公开(公告)号：US11001768B2

公开(公告)日：2021-05-11

申请号：US15775694

申请日：2016-11-01

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, Sinopec Corp.

发明人： Tiebin Liu ,  Xinguo Geng ,  Yanbo Weng ,  Hongguang Li

IPC分类号： C10G65/08 ,  C10G65/14 ,  C10G65/00 ,  C10G45/72

摘要： A heavy oil hydrotreating system has a prehydrotreating reaction zone, a transition reaction zone, and a hydrotreating reaction zone that are connected in series successively, sensor units, and a control unit. In the initial reaction stage, the prehydrotreating reaction zone includes at least two prehydrotreating reactors connected in parallel, and the transition reaction zone includes or doesn't include prehydrotreating reactors; in the reaction process, the control unit controls material feeding to and material discharging from each prehydrotreating reactor in the prehydrotreating reaction zone according to pressure drop signals of the sensor units, so that when the pressure drop in any of the prehydrotreating reactors in the prehydrotreating reaction zone reaches a predetermined value, the prehydrotreating reactor in which the pressure drop reaches the predetermined value is switched from the prehydrotreating reaction zone to the transition reaction zone.

公开(公告)号：US10525452B2

公开(公告)日：2020-01-07

申请号：US16272148

申请日：2019-02-11

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Chang Liu ,  Fenglai Wang ,  Minghua Guan ,  Yanze Du ,  Wei Huang ,  Hong Zhao

IPC分类号： B01J29/08 ,  C01B39/24 ,  C07C4/06 ,  C10G47/20 ,  B01J29/16 ,  B01J35/10 ,  B01J29/10 ,  B01J35/02 ,  C01B39/46

摘要： Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 μm, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.

公开(公告)号：US10392318B2

公开(公告)日：2019-08-27

申请号：US15347166

申请日：2016-11-09

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Huiqing Xu ,  Quanjie Liu ,  Liming Jia ,  Wei Wang

IPC分类号： B01J29/06 ,  C07C5/27 ,  B01J29/78 ,  B01J29/74 ,  B01J29/70 ,  B01J35/00 ,  B01J35/10 ,  B01J37/10 ,  B01J37/02 ,  B01J29/80 ,  C10G45/64

摘要： The present invention provides a modified composite molecular sieve, and a preparation method and an application of the modified composite molecular sieve. The modified composite molecular sieve comprises SiO2 and a composite molecular sieve that comprises molecular sieve MCM-22 and crystalline molecular sieve selected from at least one of ZSM-22, ZSM-23 and ZSM-48, wherein, the molecular sieve MCM-22 covers around the crystalline molecular sieve. The present invention further provides a catalyst and an application of the catalyst. The catalyst comprises a carrier and a noble metal loaded on the carrier, wherein, the carrier comprises a modified composite molecular sieve that is the modified composite molecular sieve provided in the present invention or the modified composite molecular sieve obtained with the method provided in the present invention. The catalyst that utilizes the composite molecular sieve as a carrier not only can decrease the solidifying point of waxy raw oil, but also can improve the yield of liquid product, is especially applicable to the isomerization dewaxing process of lube distillate, and has an advantage of remarkably improving the viscosity index of lube base oil.

公开(公告)号：US20190168193A1

公开(公告)日：2019-06-06

申请号：US16272148

申请日：2019-02-11

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Chang LIU ,  Fenglai WANG ,  Minghua GUAN ,  Yanze DU ,  Wei HUANG ,  Hong ZHAO

IPC分类号： B01J29/16 ,  B01J35/10 ,  B01J35/02 ,  B01J29/10 ,  C01B39/46 ,  B01J29/08

摘要： Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 μm, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.

公开(公告)号：US10005002B2

公开(公告)日：2018-06-26

申请号：US15031377

申请日：2014-10-21

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Jingshan Gao ,  Xiuna Yang ,  Dechen Bo ,  Shengzhong Zhang ,  Changjian Liao

IPC分类号： B01D3/14 ,  B01D3/00

CPC分类号： B01D3/141 ,  B01D3/008

摘要： A dividing wall column (10), comprising: a partition plate (11) arranged along an axial direction of the dividing wall column (10); a first shaft (22) arranged along a radial direction of the dividing wall column (10), and a first splitter plate (23) with an end connected to the first shaft (22), which are both placed beneath the partition plate (11), wherein the first splitter plate (23) is configured to be pivotable around the first shaft (22), so as to control distribution of a stream from below the first splitter plate (23) into spaces formed at two sides of the partition plate (11); and a second shaft (13) arranged along the radial direction of the dividing wall column (10), and a second splitter plate (20) with an end connected to the second shaft (13), which are both placed above the partition plate (11), wherein the second splitter plate (20) is configured to be pivotable around the second shaft (13), so as to control the stream from above the second liquid splitter plate (20) into the spaces formed at two sides of the partition plate (11).

公开(公告)号：US09719005B2

公开(公告)日：2017-08-01

申请号：US14970000

申请日：2015-12-15

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Chao Yang ,  Zhizhi Zhang ,  Xiaolei Sun ,  Jiao Lu ,  Zequn Yin ,  Quanjie Liu

IPC分类号： C09K8/035 ,  C08F220/56 ,  C08F220/34

CPC分类号： C09K8/035 ,  C08F220/34 ,  C08F220/56 ,  C08F2220/387 ,  C08F212/14

摘要： Disclosed are an associated copolymer, a method for preparation of a polymer and a polymer prepared with the method, a use of the associated copolymer and/or the polymer in drilling fluids, and a drilling fluid containing the associated copolymer and/or the polymer. The associated copolymer comprises acrylamide structural units, zwitter-ionic structural units, and cationic polyamine structural units at a specific proportion, and the cationic polyamine structural units have specific kinematic viscosity and cationic degree; thus, when the associated copolymer is used as a viscosity improver for drilling fluids, the obtained drilling fluid not only has favorable apparent viscosity after it is aged at a high temperature, but also has high dynamic shear force, and is resistant to high temperature up to 200° C. or above, resistant to NaCl up to saturated concentration, and resistant to CaCl2 up to 20 wt % concentration.

公开(公告)号：US11034932B2

公开(公告)日：2021-06-15

申请号：US15822280

申请日：2017-11-27

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Huijie Gao ,  Danfeng Sun ,  Zhihua Guo ,  Mingxiang Chen

IPC分类号： C12N1/20 ,  C02F3/30 ,  C12N1/38 ,  C02F101/16

摘要： The present invention relates to the field of biotechnology, and discloses a composition capable of promoting the growth of denitrifying microorganisms and uses thereof. The composition contains a glycolipid, an alditol, and a salt of organic acid, wherein the glycolipid is at least one of trehalose glycolipid, sophorolipid and rhamnolipid. The composition provided in the present invention can promote the growth of denitrifying microorganisms, and thereby improve the denitrification activity of the denitrifying microorganisms, promote a smooth denitrification process, and shorten the processing time.

公开(公告)号：US20200262769A1

公开(公告)日：2020-08-20

申请号：US16464405

申请日：2017-11-30

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Guoquan SUN ,  Xiangchen FANG ,  Hongfei FAN ,  Chunlei YAO ,  Hui QUAN

IPC分类号： C07C5/10

摘要： A method for preparing hexadecahydropyrene includes the step of carrying out the hydrogenation reaction to hydrocarbon oil containing pyrene compounds in the presence of a hydrogenation catalyst. The pyrene compounds are selected from at least one of pyrene and unsaturated hydrogenation products thereof. The hydrogenation catalyst contains a carrier and an active metal component loaded on the carrier. The active metal component is Pt and/or Pd and the carrier contains a small crystal size Y zeolite, alumina and amorphous silica-alumina. The small crystal size Y zeolite has an average grain diameter of 200-700 nm, a molar ratio of SiO2 to Al2O3 of 40-120, a relative crystallinity of ≥95%, and a specific surface area of 900-1,200 m2/g. The pore volume of secondary pores in 1.7-10 nm diameter is more than 50% of the total pore volume.

公开(公告)号：US10669168B2

公开(公告)日：2020-06-02

申请号：US15807252

申请日：2017-11-08

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Huijie Gao ,  Danfeng Sun ,  Zhihua Guo ,  Mingxiang Chen

IPC分类号： C02F1/44 ,  C02F1/58 ,  C02F5/00 ,  C02F9/00 ,  C02F1/469 ,  C02F1/72 ,  C02F1/52 ,  C02F101/12 ,  C02F103/36 ,  C02F3/34 ,  C02F1/04 ,  C02F3/12 ,  C02F1/22

摘要： The present invention relates to a method for zero-release treatment of brine waste water, comprising: (1) pretreatment; (2) reverse osmosis treatment; (3) advanced oxidation treatment; (4) biochemical treatment; (5) electrodialysis concentration; (6) circulating crystallization. Compared with the prior art, the method for zero-release treatment of brine waste water provided in the present invention realizes zero release or near zero release of waste water, improves salt recovery efficiency, can recover high-quality sodium sulfate, mirabilite and sodium chloride, and turns crystalline salts into a resource; the membrane treatment unit can operates stably in the process for a long operation period at a low cost, and the entire process has high economic efficiency.

公开(公告)号：US10265687B2

公开(公告)日：2019-04-23

申请号：US14946527

申请日：2015-11-19

申请人： China Petroleum & Chemical Corporation ,  Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC CORP.

发明人： Chang Liu ,  Fenglai Wang ,  Minghua Guan ,  Yanze Du ,  Wei Huang ,  Hong Zhao

IPC分类号： C01B39/46 ,  B01J29/16 ,  B01J35/10 ,  B01J29/08 ,  B01J29/10 ,  B01J35/02

摘要： Provided is a Na—Y molecular sieve and a method for preparing the Na—Y molecular sieve, an H—Y molecular sieve and a method for preparing the H—Y molecular sieve, a hydrocracking catalyst, and a hydrocracking method. The average grain diameter of the Na—Y molecular sieve is 2-5 μm, and the sum of pore volumes of pores in 1-10 nm diameter accounts for 70-90% of the total pore volume of the Na—Y molecular sieve. The H—Y molecular sieve obtained from the large-grain Na—Y molecular sieve can be used as an acidic component in the hydrocracking catalyst. When the hydrocracking catalyst containing the H—Y molecular sieve is applied in the hydrocracking reaction of heavy oils that contain macromolecules, it can provide better cracking activity and product selectivity in the hydrocracking reaction.