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1.发明授权Nano-linked heteronuclear metallocene catalyst compositions and their polymer products 有权纳米连接的异核茂金属催化剂组合物及其聚合物产物公开(公告)号：US08426536B2
公开(公告)日：2013-04-23
申请号：US13398142
申请日：2012-02-16
IPC分类号： C08F4/642 , C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： The present invention provides polymerization catalyst compositions employing novel heterodinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins are also provided.
摘要翻译： 本发明提供了采用新型异二核茂金属化合物的聚合催化剂组合物。 还提供了制备这些新的双核金属茂化合物和在催化剂组合物中用于烯烃聚合的方法。
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2.发明申请NANO-LINKED HETERONUCLEAR METALLOCENE CATALYST COMPOSITIONS AND THEIR POLYMER PRODUCTS 有权纳米链烷基金属催化剂组合物及其聚合物产品公开(公告)号：US20120149854A1
公开(公告)日：2012-06-14
申请号：US13398142
申请日：2012-02-16
CPC分类号： C07F17/00 , Y10S526/943
摘要： The present invention provides polymerization catalyst compositions employing novel heterodinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins are also provided.
摘要翻译： 本发明提供了采用新型异二核茂金属化合物的聚合催化剂组合物。 还提供了制备这些新的双核金属茂化合物和在催化剂组合物中用于烯烃聚合的方法。
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3.发明授权Nano-linked heteronuclear metallocene catalyst compositions and their polymer products 有权纳米连接的异核茂金属催化剂组合物及其聚合物产物公开(公告)号：US08143430B2
公开(公告)日：2012-03-27
申请号：US13034036
申请日：2011-02-24
IPC分类号： C08F4/64 , C08F4/642 , C08F4/6592 , B01J31/22
CPC分类号： C07F17/00 , Y10S526/943
摘要： The present invention provides polymerization catalyst compositions employing novel heterodinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins are also provided.
摘要翻译： 本发明提供了采用新型异二核茂金属化合物的聚合催化剂组合物。 还提供了制备这些新的双核金属茂化合物和在催化剂组合物中用于烯烃聚合的方法。
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公开(公告)号：US6153716A
公开(公告)日：2000-11-28
申请号：US204635
申请日：1998-12-02
申请人： M. Bruce Welch , Helmut G. Alt , Bernd Peifer , Syriac J. Palackal , Gary L. Glass , Ted M. Pettijohn , Gil R. Hawley , Darryl R. Fahey
发明人： M. Bruce Welch , Helmut G. Alt , Bernd Peifer , Syriac J. Palackal , Gary L. Glass , Ted M. Pettijohn , Gil R. Hawley , Darryl R. Fahey
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/02 , C08F110/02 , C08F210/16 , C08J5/18
CPC分类号： C08J5/18 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08J2323/04 , Y10S526/943
摘要： The present invention provides polymers of ethylene having ethyl branches, a narrow molecular weight distribution, no substantial amount of branches longer than any comonomer employed in the polymerization, and an unusually low branching to density ratio. In one embodiment the polyethylenes are substantially free of any branches having more than 2 carbon atoms, i.e. ethyl branches, and the molar percent of ethyl branches is substantially the same for molecular fractions across the molecular weight distribution. In another embodiment the polyethylenes have other branches having 3 or more carbons and the molar percent of the ethyl branches is substantially the same for molecular fractions across the molecular weight distribution.
摘要翻译： 本发明提供具有乙基支链的乙烯聚合物，窄分子量分布，没有比聚合中使用的任何共聚单体长得多的分支，以及非常低的支链与密度比。 在一个实施方案中，聚乙烯基本上不含具有多于2个碳原子的任何分支，即乙基支链，并且乙基支链的摩尔百分数对于分子量分布上的分子级分基本相同。 在另一个实施方案中，聚乙烯具有具有3个或更多个碳的其它分支，并且分子量分布中的分子级分的乙基支链的摩尔百分比基本相同。
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5.发明申请USE OF HYDROGEN SCAVENGING CATALYSTS TO CONTROL POLYMER MOLECULAR WEIGHT AND HYDROGEN LEVELS IN A POLYMERIZATION REACTOR 有权氢化催化剂在聚合反应器中控制聚合物分子量和氢含量的应用公开(公告)号：US20120238712A1
公开(公告)日：2012-09-20
申请号：US13488578
申请日：2012-06-05
申请人： Rex E. MURRAY , William B. BEAULIEU , Qing YANG , Errun DING , Gary L. GLASS , Alan L. SOLENBERGER , Steve J. SECORA
发明人： Rex E. MURRAY , William B. BEAULIEU , Qing YANG , Errun DING , Gary L. GLASS , Alan L. SOLENBERGER , Steve J. SECORA
IPC分类号： C08F4/6592 , C08F4/52 , C08F2/01
CPC分类号： C08F210/14 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/08 , C08F210/16 , C08F2410/03 , C08F2420/00 , C08F2420/02 , Y10S526/943 , C08F4/65925 , C08F4/65927 , C08F2/38 , C08F2500/12 , C08F2500/01 , C08F2500/08 , C08F4/70 , C08F4/545
摘要： The present invention provides dual catalyst systems containing a metallocene catalyst and a hydrogen scavenging catalyst, and polymerization processes employing these dual catalyst systems. Due to a reduction in hydrogen levels in the polymerization processes, olefin polymers produced from these polymerization processes may have a higher molecular weight, a lower melt index, and higher levels of unsaturation.
摘要翻译： 本发明提供了含有茂金属催化剂和除氢催化剂的双重催化剂体系，以及采用这些双重催化剂体系的聚合方法。 由于聚合过程中氢含量的降低，由这些聚合方法制备的烯烃聚合物可能具有较高的分子量，较低的熔体指数和更高的不饱和度。
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6.发明授权Use of hydrogen scavenging catalysts to control polymer molecular weight and hydrogen levels in a polymerization reactor 有权使用清除氢的催化剂来控制聚合反应器中的聚合物分子量和氢含量公开(公告)号：US08207280B2
公开(公告)日：2012-06-26
申请号：US12824491
申请日：2010-06-28
申请人： Rex E. Murray , William B. Beaulieu , Qing Yang , Errun Ding , Gary L. Glass , Alan L. Solenberger , Steven J. Secora
发明人： Rex E. Murray , William B. Beaulieu , Qing Yang , Errun Ding , Gary L. Glass , Alan L. Solenberger , Steven J. Secora
IPC分类号： C08F4/642 , C08F4/643 , C08F4/6592 , B01J31/22
CPC分类号： C08F210/14 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/08 , C08F210/16 , C08F2410/03 , C08F2420/00 , C08F2420/02 , Y10S526/943 , C08F4/65925 , C08F4/65927 , C08F2/38 , C08F2500/12 , C08F2500/01 , C08F2500/08 , C08F4/70 , C08F4/545
摘要： The present invention provides dual catalyst systems containing a metallocene catalyst and a hydrogen scavenging catalyst, and polymerization processes employing these dual catalyst systems. Due to a reduction in hydrogen levels in the polymerization processes, olefin polymers produced from these polymerization processes may have a higher molecular weight, a lower melt index, and higher levels of unsaturation.
摘要翻译： 本发明提供了含有茂金属催化剂和除氢催化剂的双重催化剂体系，以及采用这些双重催化剂体系的聚合方法。 由于聚合过程中氢含量的降低，由这些聚合方法制备的烯烃聚合物可能具有较高的分子量，较低的熔体指数和更高的不饱和度。
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7.发明授权Nano-linked heteronuclear metallocene catalyst compositions and their polymer products 有权纳米连接的异核茂金属催化剂组合物及其聚合物产物公开(公告)号：US07919639B2
公开(公告)日：2011-04-05
申请号：US12489630
申请日：2009-06-23
IPC分类号： C08F4/64 , C08F4/642 , C08F4/6592 , B01J31/22
CPC分类号： C07F17/00 , Y10S526/943
摘要： The present invention provides polymerization catalyst compositions employing novel heterodinuclear metallocene compounds. Methods for making these new dinuclear metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins are also provided.
摘要翻译： 本发明提供了采用新型异二核茂金属化合物的聚合催化剂组合物。 还提供了制备这些新的双核金属茂化合物和在催化剂组合物中用于烯烃聚合的方法。
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8.发明申请USE OF HYDROGEN SCAVENGING CATALYSTS TO CONTROL POLYMER MOLECULAR WEIGHT AND HYDROGEN LEVELS IN A POLYMERIZATION REACTOR 有权氢化催化剂在聚合反应器中控制聚合物分子量和氢含量的应用公开(公告)号：US20100331501A1
公开(公告)日：2010-12-30
申请号：US12824491
申请日：2010-06-28
申请人： Rex E. Murray , William B. Beaulieu , Qing Yang , Errun Ding , Gary L. Glass , Alan L. Solenberger , Steve J. Secora
发明人： Rex E. Murray , William B. Beaulieu , Qing Yang , Errun Ding , Gary L. Glass , Alan L. Solenberger , Steve J. Secora
CPC分类号： C08F210/14 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/08 , C08F210/16 , C08F2410/03 , C08F2420/00 , C08F2420/02 , Y10S526/943 , C08F4/65925 , C08F4/65927 , C08F2/38 , C08F2500/12 , C08F2500/01 , C08F2500/08 , C08F4/70 , C08F4/545
摘要： The present invention provides dual catalyst systems containing a metallocene catalyst and a hydrogen scavenging catalyst, and polymerization processes employing these dual catalyst systems. Due to a reduction in hydrogen levels in the polymerization processes, olefin polymers produced from these polymerization processes may have a higher molecular weight, a lower melt index, and higher levels of unsaturation.
摘要翻译： 本发明提供了含有茂金属催化剂和除氢催化剂的双重催化剂体系，以及采用这些双重催化剂体系的聚合方法。 由于聚合过程中氢含量的降低，由这些聚合方法制备的烯烃聚合物可能具有较高的分子量，较低的熔体指数和更高的不饱和度。
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公开(公告)号：US06852660B2
公开(公告)日：2005-02-08
申请号：US10348555
申请日：2003-01-21
申请人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
发明人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
IPC分类号： C08F2/00 , C08F4/06 , C08F4/42 , C08F4/649 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F110/02 , B01J31/16
CPC分类号： C08F110/02 , C08F4/6492 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/904 , Y10S526/943
摘要： A solid metallocene-containing catalyst system of an organoaluminoxane, at least one metallocene having at least one olefinically unsaturated substituent and a polyolefin is disclosed. The polyolefin is formed from at least one olefin polymerized in the presence of a combination of a solution of the organoluminoxane in an aromatic liquid, the at least one metallocene, and an aliphatic liquid. The solid metallocene-containing catalyst system may also include one or more the particulate solids.
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公开(公告)号：US06534609B2
公开(公告)日：2003-03-18
申请号：US09805277
申请日：2001-03-13
申请人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
发明人： Kent E. Mitchell , Gary L. Glass , L. Matthew Kirchman , Robert K. Provence , Leigh A. Ford , Randall S. Muninger
IPC分类号： C08F442
CPC分类号： C08F110/02 , C08F4/6492 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/904 , Y10S526/943
摘要： Methods are disclosed for preparing a highly active solid metallocene-containing catalyst system and its use in the polymerization of olefins. The catalyst system is prepared by creating a catalyst system solution by combining an aluminoxane with a metallocene having a substituent which has olefinic unsaturation in an aliphatic liquid to form a liquid catalyst system, conducting prepolymerization of an olefin in the liquid catalyst system, preferably in multiple stages, and separating the resulting solid metallocene-containing catalyst system from the reaction mixture. Also polymerization of olefins using the inventive solid catalyst system is disclosed.
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