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    Pentacoordinate silicon complexes, the process for their preparation and their application to the preparation of organosilanes
    2.
    发明授权
    Pentacoordinate silicon complexes, the process for their preparation and their application to the preparation of organosilanes 失效
    五配位硅复合物，其制备方法及其在制备有机硅烷中的应用

    公开(公告)号：US4617413A

    公开(公告)日：1986-10-14

    申请号：US813740

    申请日：1985-12-24

    申请人： Robert J. Corriu ,  Genevieve E. Cerveau ,  Claude G. Chuit ,  Catherine Reye

    发明人： Robert J. Corriu ,  Genevieve E. Cerveau ,  Claude G. Chuit ,  Catherine Reye

    IPC分类号： C07F7/08 ,  C07F7/18

    CPC分类号： C07F7/1868 ,  C07F7/0809 ,  C07F7/0827 ,  C07F7/0836 ,  C07F7/0896

    摘要： The present invention relates to new pentacoordinate silicon complexes, the process for their preparation and their application to the preparation of organosilanes.The pentacoordinate silicon complexes according to the invention correspond to the general formula I: ##STR1## in which: R denotes an alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, aralkynyl or alkylaryl radical in which the aliphatic fragments are linear, branched or cyclic and contain from 1 to 20 carbon atoms,A represents an alkali metal or alkaline earth metal, with the proviso however that A represents neither sodium nor potassium when R is a phenyl radical, andn=1 or 2.

    摘要翻译： 本发明涉及新的五配位硅配合物，其制备方法及其在制备有机硅烷中的应用。 根据本发明的五配位硅配合物对应于通式I：其中：R表示烷基，烯基，炔基，芳基，芳烷基，芳烯基，芳炔基或烷基芳基，其中脂族片段是线性的 支链或环状且含有1至20个碳原子，A表示碱金属或碱土金属，但条件是当R为苯基时，A不表示钠或钾，n = 1或2。