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    Mesoporous organic-inorganic hybrid materials for separating gases
    3.
    发明授权
    Mesoporous organic-inorganic hybrid materials for separating gases 有权
    用于分离气体的介孔有机 - 无机杂化材料

    公开(公告)号：US07452845B2

    公开(公告)日：2008-11-18

    申请号：US10472301

    申请日：2002-03-21

    申请人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stéphane Brandes ,  Chloé Thieuleux

    发明人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stéphane Brandes ,  Chloé Thieuleux

    IPC分类号： B01J20/00

    CPC分类号： C07F1/005

    摘要： The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality comprising hydrolysis and condensation polymerization of a compound of formula (I): Z-R1—Si(OR)(OR′)(OR″), with an alkaline or alkaline-earth silicate in a mol ratio of (I)/(silicate)=1:9, in the presence of a non-ionic surfactant, to form a mesoporous silica represented by Z-R1—SiO1.5 9 SiO2, whereon is then anchored an organic compound, represented by (Δ)N—H, comprising a —NH— group capable of reacting with Z, to form a functionalized mesoporous silica represented by (Δ)N—R—SiO1.5 9 SiO2, which is optionally complexed with a metallic cation to form an organometallic complex. The invention also concerns the use of these materials to separate gases.

    摘要翻译： 本发明涉及一种制备具有受控孔隙率和功能性的有机 - 无机杂化材料的方法，包括式（I）化合物的水解和缩聚：ZR 1 -Si（OR）（OR'）（OR'） OR“），在非离子表面活性剂的存在下，以（I）/（硅酸盐）= 1:9的摩尔比的碱土金属或碱土金属硅酸盐形成由ZR

    Mesoporous organic-inorganic hybrid materials for separating gases
    5.
    发明授权
    Mesoporous organic-inorganic hybrid materials for separating gases 有权
    用于分离气体的介孔有机 - 无机杂化材料

    公开(公告)号：US07517512B2

    公开(公告)日：2009-04-14

    申请号：US12043486

    申请日：2008-03-06

    申请人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stéphane Brandes ,  Chloé Thieuleux

    发明人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stéphane Brandes ,  Chloé Thieuleux

    IPC分类号： B01D53/86

    CPC分类号： C07F1/005

    摘要： The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality comprising hydrolysis and condensation polymerization of a compound of formula (I): Z-R1—Si(OR)(OR′)(OR″), with an alkaline or alkaline-earth silicate in a mol ratio of (I)/(silicate)=1:9, in the presence of a non-ionic surfactant, to form a mesoporous silica represented by Z-R1—SiO1.5 9 SiO2, whereon is then anchored an organic compound, represented by (Δ)N—H, comprising a —NH— group capable of reacting with Z, to form a functionalized mesoporous silica represented by (Δ)N—R—SiO1.5 9 SiO2, which is optionally complexed with a metallic cation to form an organometallic complex. The invention also concerns the use of these materials to separate gases.

    摘要翻译： 本发明涉及一种制备具有受控孔隙率和功能性的有机 - 无机杂化材料的方法，包括式（I）化合物：Z-R1-Si（OR）（OR'）（OR“）与水解和缩聚 在非离子表面活性剂存在下，以（I）/（硅酸盐）= 1:9的摩尔比计的碱土金属或碱土金属硅酸盐，形成由Z-R1-SiO1.59SiO 2表示的介孔二氧化硅 然后将其固定在由（Δ）NH表示的有机化合物中，该化合物包含能与Z反应的-NH-基团，形成由（Delta）NR-SiO 1.59SiO 2表示的官能化介孔二氧化硅， 与金属阳离子络合形成有机金属络合物。 本发明还涉及使用这些材料来分离气体。

    MESOPOROUS ORGANIC-INORGANIC HYBRID MATERIALS FOR SEPARATING GASES
    6.
    发明申请
    MESOPOROUS ORGANIC-INORGANIC HYBRID MATERIALS FOR SEPARATING GASES 有权
    用于分离气体的多孔有机无机混合材料

    公开(公告)号：US20080152561A1

    公开(公告)日：2008-06-26

    申请号：US12043486

    申请日：2008-03-06

    申请人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stephane Brandes ,  Chloe Thieuleux

    发明人： Robert Corriu ,  Ahmad Mehdi ,  Catherine Reye ,  Henry Ledon ,  Roger Guilard ,  Stephane Brandes ,  Chloe Thieuleux

    IPC分类号： B01D53/46 ,  B01D53/38 ,  C01B13/02 ,  C07F7/02

    CPC分类号： C07F1/005

    摘要： The invention concerns a method for preparing organic-inorganic hybrid materials with controlled porosity and functionality comprising hydrolysis and condensation polymerization of a compound of formula (I): Z-R1—Si(OR)(OR′)(OR″), with an alkaline or alkaline-earth silicate in a mol ratio of (I)/(silicate)=1:9, in the presence of a non-ionic surfactant, to form a mesoporous silica represented by Z-R1—SiO1.5 9 SiO2, whereon is then anchored an organic compound, represented by (Δ)N—H, comprising a —NH— group capable of reacting with Z, to form a functionalized mesoporous silica represented by (Δ)N—R—SiO1.5 9 SiO2, which is optionally complexed with a metallic cation to form an organometallic complex. The invention also concerns the use of these materials to separate gases.

    摘要翻译： 本发明涉及一种制备具有受控孔隙率和功能性的有机 - 无机杂化材料的方法，包括式（I）化合物的水解和缩聚：ZR 1 -Si（OR）（OR'）（OR'） OR“），在非离子表面活性剂的存在下，以（I）/（硅酸盐）= 1:9的摩尔比的碱土金属或碱土金属硅酸盐形成由ZR

    Pentacoordinate silicon complexes, the process for their preparation and their application to the preparation of organosilanes
    7.
    发明授权
    Pentacoordinate silicon complexes, the process for their preparation and their application to the preparation of organosilanes 失效
    五配位硅复合物，其制备方法及其在制备有机硅烷中的应用

    公开(公告)号：US4617413A

    公开(公告)日：1986-10-14

    申请号：US813740

    申请日：1985-12-24

    申请人： Robert J. Corriu ,  Genevieve E. Cerveau ,  Claude G. Chuit ,  Catherine Reye

    发明人： Robert J. Corriu ,  Genevieve E. Cerveau ,  Claude G. Chuit ,  Catherine Reye

    IPC分类号： C07F7/08 ,  C07F7/18

    CPC分类号： C07F7/1868 ,  C07F7/0809 ,  C07F7/0827 ,  C07F7/0836 ,  C07F7/0896

    摘要： The present invention relates to new pentacoordinate silicon complexes, the process for their preparation and their application to the preparation of organosilanes.The pentacoordinate silicon complexes according to the invention correspond to the general formula I: ##STR1## in which: R denotes an alkyl, alkenyl, alkynyl, aryl, aralkyl, aralkenyl, aralkynyl or alkylaryl radical in which the aliphatic fragments are linear, branched or cyclic and contain from 1 to 20 carbon atoms,A represents an alkali metal or alkaline earth metal, with the proviso however that A represents neither sodium nor potassium when R is a phenyl radical, andn=1 or 2.

    摘要翻译： 本发明涉及新的五配位硅配合物，其制备方法及其在制备有机硅烷中的应用。 根据本发明的五配位硅配合物对应于通式I：其中：R表示烷基，烯基，炔基，芳基，芳烷基，芳烯基，芳炔基或烷基芳基，其中脂族片段是线性的 支链或环状且含有1至20个碳原子，A表示碱金属或碱土金属，但条件是当R为苯基时，A不表示钠或钾，n = 1或2。

    New organomagnesium complexes in solid form, process for their preparation, and their use
    9.
    发明授权
    New organomagnesium complexes in solid form, process for their preparation, and their use 失效
    固体形式的新的有机镁络合物，其制备方法及其用途

    公开(公告)号：US4835316A

    公开(公告)日：1989-05-30

    申请号：US103642

    申请日：1987-10-02

    申请人： Robert Corriu ,  Genevieve Cerveau ,  Claude Chuit ,  Catherine Reye ,  Alain Boudin

    发明人： Robert Corriu ,  Genevieve Cerveau ,  Claude Chuit ,  Catherine Reye ,  Alain Boudin

    IPC分类号： C07C45/00 ,  C07F3/02

    CPC分类号： C07C45/004 ,  C07F3/02

    摘要： Organgomagnesium complexes which correspond to the formula (I): ps(RMgX).sub.m /N[--CHR.sub.1 --CHR.sub.2 --O--(CHR.sub.3 --CHR.sub.4 --O).sub.n --R.sub.5 ].sub.3 (I)wherein:m is 1, 2, or 3;R denotes a substituted or unsubstituted group which is:linear or branched alkyl containing from 1 to 18 carbon atoms,alkenyl or alkynyl containing from 2 to 18 carbon atoms,cycloalkyl or cycloalkenyl containing from 3 to 12 carbon atoms,alkoxyalkyl, dialkoxyalkyl or alkylthiocarbonyl, aryl (which aryl may particularly be position-substituted by at least a halogen or an alkoxy, trifluoroemethyl, trifluoromethoxy or trifluromethoylthio group), oralkoxyaryl or alkylthioaryl;X denotes a chlorine, iodine or bromine atom;n is an integer ranging from 0 to about 10;R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which are identical or di fferent, denote a hydrogen atom or an alkyl or cycloalkyl radical containing from 1 to 4 carbon atoms; andR.sub.5, which is identical or different in each of the three [--CHR.sub.1 --CHR.sub.2 --O--(CHR.sub.3 --CHR.sub.4 --O) hd n--R.sub.5 ] chains, denotes an alkyl or cycloalkyl radical containing 1 to 12 carbon atoms, a phenyl radical or a radical of formula --C.sub.p H.sub.2p --.phi. or C.sub.p H.sub.(2p+1) --.phi.--, wherein p ranges from 1 to about 12.

    摘要翻译： 对应于式（I）的络联络合物：ps（RMgX）m / N [-CHR1-CHR2-O-（CHR3-CHR4-O）n-R5] 3（I）其中：m为1,2或 3; R表示取代或未取代的基团，其为：含有1至18个碳原子的直链或支链烷基，含有2至18个碳原子的烯基或炔基，含有3至12个碳原子的环烷基或环烯基，烷氧基烷基，二烷氧基烷基或烷硫基羰基， 芳基（该芳基可以特别被至少一个卤素或烷氧基，三氟甲基，三氟甲氧基或三氟甲硫基）位置取代）或烷氧基芳基或烷硫基芳基; X表示氯，碘或溴原子; n为0〜10的整数; 相同或不同的R 1，R 2，R 3和R 4表示氢原子或含有1至4个碳原子的烷基或环烷基; 和每个三个[-CHR1-CHR2-O-（CHR3-CHR4-O）hd n-R5]链相同或不同的R5表示含有1至12个碳原子的烷基或环烷基，苯基 基团或式-CpH2p-phi或CpH（2p + 1） - phi - 的基团，其中p为1至约12。