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    Spirobifluorene derivatives, their preparation and uses thereof
    1.
    发明授权
    Spirobifluorene derivatives, their preparation and uses thereof 有权
    螺二芴衍生物，其制备和用途

    公开(公告)号：US07557249B2

    公开(公告)日：2009-07-07

    申请号：US10523101

    申请日：2003-07-31

    申请人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    发明人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    IPC分类号： C07C49/00 ,  H01L51/54

    CPC分类号： C07D333/22 ,  C07C45/46 ,  C07C49/792 ,  C07C49/813 ,  C07C49/84 ,  C07D307/46 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1011 ,  C09K2211/1425 ,  C25B3/04 ,  H01L51/0058 ,  H01L51/5012 ,  Y10S428/917

    摘要： The invention concerns Spirobifluorene derivatives having the general formula (II) and the corresponding, radical anions that can be represented via the general formula (II): in which K, L, M and N, the same or different from each other, are independently: H or A-C═O, with the proviso that it is never K=L=M=N=H, wherein A is an aromatic group, possibly substituted with at least an R′ group selected in the group of the substituents commonly used in organic chemistry and/or at least one R group where R=aliphatic radical. The invention also concerns the method for preparing said derivatives and radical anions. Said compounds are applied in the field of components for molecular electronics, in particular systems for electroluminescence, molecular-based computational systems, OLEDs, molecular switching components, components for non-linear optics, field-effect transistors and semiconductors with negative differential resistance.

    摘要翻译： 本发明涉及具有通式（II）和可以通过通式（II）表示的相应的自由基阴离子的螺二芴衍生物：其中彼此相同或不同的K，L，M和N独立地为 ：H或ACO，条件是从不K = L = M = N = H，其中A是芳族基团，可能被至少一个选自在有机化学中通常使用的取代基中选择的R'基团取代 和/或至少一个R基团，其中R =脂族基团。 本发明还涉及制备所述衍生物和自由基阴离子的方法。 所述化合物应用于分子电子学的组件领域，特别是用于电致发光，基于分子的计算系统，OLED，分子开关组件，非线性光学元件，场效应晶体管和具有负微分电阻的半导体的系统领域。

    Spirobifluorene derivatives, their preparation and uses thereof
    2.
    发明申请
    Spirobifluorene derivatives, their preparation and uses thereof 有权
    螺二芴衍生物，其制备和用途

    公开(公告)号：US20060006365A1

    公开(公告)日：2006-01-12

    申请号：US10523101

    申请日：2003-07-31

    申请人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    发明人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    IPC分类号： C09K11/06

    CPC分类号： C07D333/22 ,  C07C45/46 ,  C07C49/792 ,  C07C49/813 ,  C07C49/84 ,  C07D307/46 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1011 ,  C09K2211/1425 ,  C25B3/04 ,  H01L51/0058 ,  H01L51/5012 ,  Y10S428/917

    摘要： The invention concerns Spirobifluorene derivatives having the general formula (II) and the corresponding, radical anions that can be represented via the general formula (II): in which K, L, M and N, the same or different from each other, are independently: H or A-C═O, with the proviso that it is never K=L=M=N═H, wherein A is an aromatic group, possibly substituted with at least an R′ group selected in the group of the substituents commonly used in organic chemistry and/or at least one R group where R=aliphatic radical. The invention also concerns the method for preparing said derivatives and radical anions. Said compounds are applied in the field of components for molecular electronics, in particular systems for electroluminescence, molecular-based computational systems, OLEDs, molecular switching components, components for non-linear optics, field-effect transistors and semiconductors with negative differential resistance.

    摘要翻译： 本发明涉及具有通式（II）和可以通过通式（II）表示的相应的自由基阴离子的螺二芴衍生物：其中彼此相同或不同的K，L，M和N独立地为 ：H或ACO，条件是从未K = L = M = NH，其中A是芳族基团，可能被至少一个在有机化学中通常使用的取代基中选择的R'基团取代和/ 或至少一个R基团，其中R =脂族基团。 本发明还涉及制备所述衍生物和自由基阴离子的方法。 所述化合物应用于分子电子学的组件领域，特别是用于电致发光，基于分子的计算系统，OLED，分子开关组件，非线性光学元件，场效应晶体管和具有负微分电阻的半导体的系统领域。

    Spirobifluorene derivatives, their preparation and uses thereof
    3.
    发明授权
    Spirobifluorene derivatives, their preparation and uses thereof 有权
    螺二芴衍生物，其制备和用途

    公开(公告)号：US08188462B2

    公开(公告)日：2012-05-29

    申请号：US12497195

    申请日：2009-07-02

    申请人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    发明人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    IPC分类号： H01L51/00

    CPC分类号： C07D333/22 ,  C07C45/46 ,  C07C49/792 ,  C07C49/813 ,  C07C49/84 ,  C07D307/46 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1011 ,  C09K2211/1425 ,  C25B3/04 ,  H01L51/0058 ,  H01L51/5012 ,  Y10S428/917

    摘要： The invention concerns Spirobifluorene derivatives having the general formula (II) and the corresponding, radical anions that can be represented via the general formula (II): in which K, L, M and N, the same or different from each other, are independently: H or A-C═O, with the proviso that it is never K=L=M=N═H, wherein A is an aromatic group, possibly substituted with at least an R′ group selected in the group of the substituents commonly used in organic chemistry and/or at least one R group where R=aliphatic radical. The invention also concerns the method for preparing said derivatives and radical anions. Said compounds are applied in the field of components for molecular electronics, in particular systems for electroluminescence, molecular-based computational systems, OLEDs, molecular switching components, components for non-linear optics, field-effect transistors and semiconductors with negative differential resistance.

    摘要翻译： 本发明涉及具有通式（II）的螺二芴衍生物和可以通过通式（II）表示的相应的自由基阴离子：其中彼此相同或不同的K，L，M和N独立地为 ：H或AC = O，条件是从未K = L = M = N = H，其中A是芳族基团，可能被至少一个选自通常用于 有机化学和/或至少一个R基团，其中R =脂族基团。 本发明还涉及制备所述衍生物和自由基阴离子的方法。 所述化合物应用于分子电子学的组件领域，特别是用于电致发光，基于分子的计算系统，OLED，分子开关组件，非线性光学元件，场效应晶体管和具有负微分电阻的半导体的系统领域。

    Oligomeric derivatives of spirobifluorene, their preparation and use
    5.
    发明授权
    Oligomeric derivatives of spirobifluorene, their preparation and use 有权
    螺二芴的低聚衍生物，其制备和用途

    公开(公告)号：US08614357B2

    公开(公告)日：2013-12-24

    申请号：US11632337

    申请日：2005-07-15

    申请人： Liliana Bagala'Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    发明人： Liliana Bagala'Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    IPC分类号： C07C49/00 ,  C07C315/00 ,  C07C317/00 ,  C07C319/00 ,  C07C331/00 ,  C07C381/00 ,  H01L29/08 ,  H01L35/24 ,  H01L51/00

    CPC分类号： C07C13/72 ,  C07C13/62 ,  C07C2603/18 ,  C09B5/62 ,  C09B23/105 ,  C09B57/00 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1011 ,  H01L51/0058 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5048 ,  H05B33/14 ,  Y02E10/549 ,  Y10S428/917

    摘要： SBF derivatives, represented with the following formula: SBF-X wherein: with m=0, 1, 2 or 3; p=positive integer,; n=positive integer; L: is the same or different and independently represents C, PR, AsR, SbR, BiR, S, Se, Te, S═Y, Se═Y or Te═Y; Y: is the same or different and independently represents O, S, Se or Te; K: is the same or different and independently represents a chemical bond or a group selected from O, S, BR(2−p), N, NR(2−p), R(2−p)P═O, B3O3, (PR)3N3, CR(3−p), CR(3−p)(C6H4)(p+1), SiR(3−p)(C6H4)(p+1) alkyne, substituted alkyne, alkyne, substituted alkyne, aromatic or R substituted aromatic, heteroaromatic-or a combination of two, three or four of the above mentioned groups; SBF: spiro-compound of formula (I): R, A, B, C, D: is the same or different and independently represents H, deuterium, F, Cl, Br, I, CN, a linear, branched or cyclic alkyl, alkoxy or thioalkoxy chain, or a combination from two, three or four of these systems; two or more substituents R can form a further monocyclic or polycyclic aliphatic or aromatic ring system with each other.

    摘要翻译： SBF衍生物，用下式表示：SBF-X其中：m = 0,1,2或3; p =正整数 n =正整数; L：相同或不同，独立地表示C，PR，AsR，SbR，BiR，S，Se，Te，S = Y，Se = Y或Te = Y; Y：相同或不同，独立地表示O，S，Se或Te; K：相同或不同，独立地表示化学键或选自O，S，BR（2-p），N，NR（2-p），R（2-p）P = O， （PR）3N3，CR（3-p），CR（3-p）（C6H4）（p + 1），SiR（3-p）（C6H4）（p + 1）炔，取代炔，炔，取代炔 ，芳族或R取代的芳族，杂芳族或两个，三个或四个上述基团的组合; SBF：式（I）的螺 - 化合物：R，A，B，C，D：相同或不同，独立地表示H，氘，F，Cl，Br，I，CN，直链，支链或环状烷基 ，烷氧基或硫代烷氧基链，或这些系统中的两个，三个或四个的组合; 两个或更多个取代基R可以彼此形成另外的单环或多环脂族或芳环体系。

    SPIROBIFLUORENE DERIVATIVES, THEIR PREPARATION AND USES THEREOF
    6.
    发明申请
    SPIROBIFLUORENE DERIVATIVES, THEIR PREPARATION AND USES THEREOF 有权
    螺旋体衍生物，其制备及其用途

    公开(公告)号：US20090302274A1

    公开(公告)日：2009-12-10

    申请号：US12497195

    申请日：2009-07-02

    申请人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    发明人： Liliana Bagala' Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    IPC分类号： C09K11/06

    CPC分类号： C07D333/22 ,  C07C45/46 ,  C07C49/792 ,  C07C49/813 ,  C07C49/84 ,  C07D307/46 ,  C09K11/06 ,  C09K2211/1003 ,  C09K2211/1011 ,  C09K2211/1425 ,  C25B3/04 ,  H01L51/0058 ,  H01L51/5012 ,  Y10S428/917

    摘要： The invention concerns Spirobifluorene derivatives having the general formula (II) and the corresponding, radical anions that can be represented via the general formula (II): in which K, L, M and N, the same or different from each other, are independently: H or A-C═O, with the proviso that it is never K═L═M═N═H, wherein A is an aromatic group, possibly substituted with at least an R′ group selected in the group of the substituents commonly used in organic chemistry and/or at least one R group where R=aliphatic radical. The invention also concerns the method for preparing said derivatives and radical anions. Said compounds are applied in the field of components for molecular electronics, in particular systems for electroluminescence, molecular-based computational systems, OLEDs, molecular switching components, components for non-linear optics, field-effect transistors and semiconductors with negative differential resistance.

    摘要翻译： 本发明涉及具有通式（II）和可以通过通式（II）表示的相应的自由基阴离子的螺二芴衍生物：其中彼此相同或不同的K，L，M和N独立地为 ：H或ACO，条件是其永远不是KLMNH，其中A是芳族基团，可能被至少一个在有机化学中通常使用的取代基中选择的R'基团取代，和/或至少一个R基团 其中R =脂族基团。 本发明还涉及制备所述衍生物和自由基阴离子的方法。 所述化合物应用于分子电子学的组件领域，特别是用于电致发光，基于分子的计算系统，OLED，分子开关组件，非线性光学元件，场效应晶体管和具有负微分电阻的半导体的系统领域。

    Oligomeric derivatives of spirobifluorene, their preparation and use
    7.
    发明申请
    Oligomeric derivatives of spirobifluorene, their preparation and use 有权

    公开(公告)号：US20090234164A1

    公开(公告)日：2009-09-17

    申请号：US11632337

    申请日：2005-07-15

    申请人： Liliana Bagala'Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    发明人： Liliana Bagala'Rampazzo ,  Giulia Fioravanti ,  Leonardo Mattiello

    IPC分类号： C07C45/61 ,  C07C49/215

    CPC分类号： C07C13/72 ,  C07C13/62 ,  C07C2603/18 ,  C09B5/62 ,  C09B23/105 ,  C09B57/00 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1011 ,  H01L51/0058 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5048 ,  H05B33/14 ,  Y02E10/549 ,  Y10S428/917

    摘要： SBF derivatives, which can be represented with the following formula: SBF-X wherein: with m=0, 1, 2 or 3; p=positive integer, preferably 1, 2 or 3, with (p+1) being the valency of K; n=positive integer, preferably 1, 2 or 3; L: is the same or different and independently represents C, PR, AsR, SbR, BiR, S, Se, Te, S═Y, Se═Y or Te═Y; Y: is the same or different and independently represents O, S, Se or Te; K: is the same or different and independently represents a chemical bond or a group selected from O, S, BR(2−p), N, NR(2−p), R(2−p)P═O, B3O3, (PR)3N3, CR(3−p), CR(3−p)(C6H4)(p+1), SiR(3−p)(C6H4)(p+1) with (2−p) and (3−p) being a positive integer including zero; alkene, substituted alkene, alkyne, substituted alkyne, aromatic or R substituted aromatic, heteroaromatic or R substituted heteroaromatic or a group resulting from benzene and non benzene, monocyclic and polycyclic hydrocarbons, which can be bivalent, trivalent or of higher valency; or a combination of two, three or four of the above mentioned groups; SBF: spiro-compound of formula (I): R, A, B, C, D: is the same or different and independently represents H, deuterium, F, Cl, Br, I, CN, a linear, branched or cyclic alkyl, alkoxy or thioalkoxy chain with 1 to 40 carbon atoms, which can be substituted by R1 and in which one or more non-neighbouring carbon atoms can be replaced by N—R1, O, S, C═O, C═S, C═NR1, Si(R1)2, Ge(R1)2, O—CO—O, CO—O, CO—NR1, —CR1═CR1— or —C≡C— and in which one or more H-atoms can be replaced by F, Cl, Br, I or CN, or an aromatic or heteroaromatic ring system with 5 to 40 aromatic ring atoms, which can be substituted by deuterium, F, Cl, Br, I, CN or one or more substituents R1, or a combination from two, three or four of these systems; two or more substituents R can form a further monocyclic or polycyclic aliphatic or aromatic ring system with each other; R1: is the same or different and independently represents H or an aliphatic or aromatic hydrocarbon rest with 1 to 20 C-atoms.