摘要:
A catalyst has high activity and is suitable for use in producing chlorine by oxidizing hydrogen chloride with oxygen. The catalyst includes copper, an alkali metal and a rare earth and has pores of which pores having a diameter of 5 to 15 nm have a pore volume of 0.4 to 2.0 ml/g.
摘要:
There are provided a method for producing porous silica and a porous silica film having low specific dielectric constant and high mechanical strength, that are preferably applicable to optical functional materials, electronic functional materials or the like, and a method for producing an interlayer insulating film, a semiconductor material and a semiconductor apparatus and a producing apparatus, which use the porous silica film. A solution containing a hydrolysis-condensation product of alkoxysilanes and a surfactant is dried to form a composite to which are then applied in the following order an ultraviolet ray irradiation treatment and a hydrophobic treatment with the use of an organic silicon compound having an alkyl group. By forming the composite by drying the solution on a substrate, the porous silica film is obtained.
摘要:
The invention provides a chlorine production catalyst that shows excellent reaction activity in the oxidation reaction of hydrogen chloride with oxygen into chlorine, is inexpensive and can be supplied stably, and is suited for use in a fluidized-bed reactor. The invention also provides a chlorine production process using the catalyst. The chlorine production catalyst of the invention includes spherical particles containing copper element (A), an alkali metal element (B) and a lanthanoid element (C) and having an average sphericity of not less than 0.80. The lanthanoid element (C) has a bond dissociation energy with oxygen at 298 K of 100 to 185 kcal/mol. The content of the copper element (A) in the catalyst is 0.3 wt % to 4.5 wt %.
摘要:
A carriage-type conveying apparatus with a workpiece support base and an elevating drive has a passive shaft interlocked with the elevating drive and a lock to prevent descent of the workpiece support base A power source carriage capable of traveling synchronously with the conveying carriage is aside of a traveling path of the conveying carriage at a workpiece support height changing position so as to be reciprocable along the traveling path. The power source carriage has a transmission shaft driven by a power source and a separable interlock to interlock the passive shaft and a transmission shaft with each other.
摘要:
The invention provides a chlorine production catalyst that shows excellent reaction activity in the oxidation reaction of hydrogen chloride with oxygen into chlorine, is inexpensive and can be supplied stably, and is suited for use in a fluidized-bed reactor. The invention also provides a chlorine production process using the catalyst. The chlorine production catalyst of the invention includes spherical particles containing copper element (A), an alkali metal element (B) and a lanthanoid element (C) and having an average sphericity of not less than 0.80. The lanthanoid element (C) has a bond dissociation energy with oxygen at 298 K of 100 to 185 kcal/mol. The content of the copper element (A) in the catalyst is 0.3 wt % to 4.5 wt %.
摘要:
There is provided by the present invention a process for preparing a copper-based catalyst having good catalytic activity, markedly excellent durability and good reproducibility. The process for preparing a copper-based catalyst of the invention is a process for preparing a catalyst composed of metal oxides containing copper oxide as an essential component and is characterized by comprising the following steps: (1) a step of bringing an acidic metal salt solution containing copper and a precipitant solution into contact with each other to obtain a slurry solution containing a precipitate of a catalyst precursor, and (2) a step of continuously bringing the slurry solution and a wash liquid into contact with each other to wash the precipitate, with substantially keeping the suspended state.
摘要:
A hydrophobic compound having at least one each of hydrophobic group (an alkyl group having 1 to 6 carbon atoms or a —C6H5 group) and polymerizable group (a hydrogen atom, a hydroxyl group or a halogen atom) is allowed to undergo a gas-phase polymerization reaction, under reduced pressure (of not more than 30 kPa), in the presence of a raw porous silica film and to thus form a modified porous silica film wherein a hydrophobic polymer thin film is formed on the inner walls of holes present in the raw porous silica film. The resulting porous silica film has a low relative dielectric constant and a low refractive index and the silica film is likewise improved in the mechanical strength and hydrophobicity. A semiconductor device is produced using the porous silica film.
摘要翻译:具有疏水性基团(具有1〜6个碳原子的烷基或-C 6 H 5基团)和可聚合基团(氢原子,羟基或卤素原子)中的至少一种的疏水化合物被允许进行气 - 在减压(不大于30kPa)的条件下,在原料多孔二氧化硅膜的存在下进行相聚合反应,从而形成改性多孔二氧化硅膜,其中在存在于孔中的孔的内壁上形成疏水性聚合物薄膜 原料多孔二氧化硅膜。 所得到的多孔二氧化硅膜的相对介电常数低,折射率低,二氧化硅膜的机械强度和疏水性同样提高。 使用多孔二氧化硅膜制造半导体器件。
摘要:
The coating liquid for forming porous silica according to the present invention is characterized by preferably containing a partial hydrolysis-condensation product of an alkoxysilane compound, a surfactant and an organic ampholyte, and by having a metal content of not more than 50 ppb. Conventional coating liquids for forming porous silica have such a problem that porous silica films formed therefrom may have poor regularity in micropore alignment when the shelf life of the coating liquids are long. On the contrary, the coating liquid for forming porous silica of the present invention is excellent in self-life stability. Namely, the quality of porous silica formed therefrom is hardly affected by the length of self-life period of the coating liquid. Consequently, the coating liquid is expected to contribute to the stable preparation of porous silica films which cause no shift in capacitance or voltage when exposed to an electric field, have regularly aligned uniform micropores, and are preferably used as an optically functional material or an electronically functional material.
摘要:
A composite oxide catalyst represented by the general formula: Mo-V-P-X-Y (wherein X represents at least one element selected from the group consisting of Sb, Cu, Co, Bi and As; Y represents at least one element selected from the group consisting of K, Rb, Cs and Tl) and a method for preparing methacrylic acid through gas phase catalytic oxidation of methacrolein with molecular oxygen in the presence of the foregoing catalyst are herein disclosed. The catalyst exhibits excellent catalytic activity, selectivity to methacrylic acid, catalytic stability and lifetime.
摘要:
There is provided by the present invention a process for preparing a copper-based catalyst having good catalytic activity, markedly excellent durability and good reproducibility. The process for preparing a copper-based catalyst of the invention is a process for preparing a catalyst composed of metal oxides containing copper oxide as an essential component and is characterized by comprising the following steps: (1) a step of bringing an acidic metal salt solution containing copper and a precipitant solution into contact with each other to obtain a slurry solution containing a precipitate of a catalyst precursor, and (2) a step of continuously bringing the slurry solution and a wash liquid into contact with each other to wash the precipitate, with substantially keeping the suspended state.