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公开(公告)号:US06417323B1
公开(公告)日:2002-07-09
申请号:US09622592
申请日:2000-09-13
申请人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
发明人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
IPC分类号: C08G6534
CPC分类号: A61Q19/00 , A61K8/86 , A61K2800/48 , C08G65/10 , C08G65/22 , C08G65/226 , C08G65/266
摘要: The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L1, L2 and L3 are same as or different from each other and each of them represents an oxygen-binding ligand.
摘要翻译: 本发明提供了一种通过容易聚合取代的环氧化物而有效获得聚合度高的方法,所述取代环氧化物几乎不能或不能达到提供高度聚合的程度。 也就是说,通过在式(I)表示的稀土金属化合物和还原性化合物的存在下,通过包括使环氧丙烷和表卤代醇除外的至少一种取代的环氧化物开环聚合的方法获得聚醚 :其中M表示选自Sc,Y和镧系元素的稀土元素,L1,L2和L3彼此相同或不同,它们各自表示氧结合配体。
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公开(公告)号:US5853611A
公开(公告)日:1998-12-29
申请号:US894556
申请日:1997-09-11
申请人: Hiroshi Kawamukai , Katsuhiko Rindo , Takashi Oda , Masaaki Moriyama , Hideyuki Hanazawa , Yasushi Kajihara
发明人: Hiroshi Kawamukai , Katsuhiko Rindo , Takashi Oda , Masaaki Moriyama , Hideyuki Hanazawa , Yasushi Kajihara
IPC分类号: A61K8/65 , A61K8/86 , A61Q5/00 , A61Q5/02 , A61Q19/00 , A61Q19/10 , C08G65/332 , C08G65/333 , C08L71/03 , C11D9/30 , C08F283/04
CPC分类号: C08L71/03 , A61K8/65 , A61K8/86 , A61Q19/00 , C08G65/332 , C08G65/3322 , C08G65/33306 , A61Q19/10 , A61Q5/00 , A61Q5/02
摘要: The present invention relates to a polyether polymer having structural units represented by general formula (1), wherein R.sup.1 and R.sup.2 mean individually an alkyl group of 1-20 carbon atoms, which may have at least one hydroxyl group, and Y denotes an alkylene group of 1-10 carbon atoms, which may have a hydroxyl group, a preparation process thereof, and a moisturizer, a cosmetic composition and a detergent composition comprising this polymer. The cosmetic composition and detergent composition are excellent in moisture retention, keep up the moisturizing effect over a long period of time and give users a pleasant feeling.
摘要翻译: PCT No.PCT / JP96 / 00291 Sec。 371日期:1997年9月11日 102(e)1997年9月11日PCT PCT 1996年2月9日PCT公布。 出版物WO96 / 26233 PCT 日期:1996年8月29日本发明涉及具有由通式(1)表示的结构单元的聚醚聚合物,其中R 1和R 2分别表示可以具有至少一个羟基的1-20个碳原子的烷基, Y表示可以具有羟基的1-10个碳原子的亚烷基,其制备方法和保湿剂,化妆品组合物和包含该聚合物的洗涤剂组合物。 化妆品组合物和洗涤剂组合物具有优异的保湿性,在长时间内保持保湿效果,并给予使用者愉快的感觉。
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公开(公告)号:US06906167B2
公开(公告)日:2005-06-14
申请号:US10883827
申请日:2004-07-06
申请人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
发明人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
CPC分类号: A61Q19/00 , A61K8/86 , A61K2800/48 , C08G65/10 , C08G65/22 , C08G65/226 , C08G65/266
摘要: The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L1, L2 and L3 are same as or different from each other and each of them represents an oxygen-binding ligand.
摘要翻译: 本发明提供了一种通过容易聚合取代的环氧化物而有效获得聚合度高的方法,所述取代环氧化物几乎不能或不能达到提供高度聚合的程度。 也就是说,通过在式(I)表示的稀土金属化合物和还原性化合物的存在下,通过包括使环氧丙烷和表卤代醇除外的至少一种取代的环氧化物开环聚合的方法获得聚醚 :其中M表示选自Sc,Y和镧系元素的稀土元素,L 1,L 2和L 3 3与SO 3, 它们彼此不同,它们各自表示氧结合配体。
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公开(公告)号:US20050004344A1
公开(公告)日:2005-01-06
申请号:US10883827
申请日:2004-07-06
申请人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
发明人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
CPC分类号: A61Q19/00 , A61K8/86 , A61K2800/48 , C08G65/10 , C08G65/22 , C08G65/226 , C08G65/266
摘要: The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L1, L2 and L3 are same as or different from each other and each of them represents an oxygen-binding ligand.
摘要翻译: 本发明提供了一种通过容易聚合取代的环氧化物而有效获得聚合度高的方法,所述取代环氧化物几乎不能或不能达到提供高度聚合的程度。 也就是说,通过在式(I)表示的稀土金属化合物和还原性化合物的存在下,通过包括使环氧丙烷和表卤代醇除外的至少一种取代的环氧化物开环聚合的方法获得聚醚 :其中M表示选自Sc,Y和镧系元素的稀土元素,L 1,L 2和L 3彼此相同或不同,它们各自表示氧结合配体。
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公开(公告)号:US06800723B2
公开(公告)日:2004-10-05
申请号:US10082059
申请日:2002-02-26
申请人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
发明人: Seiichi Miyanaga , Hiroshi Kawamukai , Takashi Oda
IPC分类号: C08G6534
CPC分类号: A61Q19/00 , A61K8/86 , A61K2800/48 , C08G65/10 , C08G65/22 , C08G65/226 , C08G65/266
摘要: The present invention provides a process for efficiently obtaining polyethers having its high degree of polymerization by easily polymerizing substituted epoxides which could hardly or could not be made so far to provide a high degree of polymerization. That is, a polyether is obtained by a process which comprises ring-opening-polymerizing at least one substituted epoxide, except for propylene oxide and epihalohydrin, in the presence of a rare earth metal compound represented by the formula (I) and a reducing compound: Wherein M represents a rare earth element selected from Sc, Y and lanthanide, and L1, L2 and L3 are same as or different from each other and each of them represents an oxygen-binding ligand.
摘要翻译: 本发明提供了一种通过容易聚合取代的环氧化物而有效获得聚合度高的方法,所述取代环氧化物几乎不能或不能达到提供高度聚合的程度。 也就是说,通过在式(I)表示的稀土金属化合物和还原性化合物的存在下,通过包括使环氧丙烷和表卤代醇除外的至少一种取代的环氧化物开环聚合的方法获得聚醚 :其中M表示选自Sc,Y和镧系元素的稀土元素,L 1,L 2和L 3彼此相同或不同,它们各自表示氧结合配体。
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公开(公告)号:US5534322A
公开(公告)日:1996-07-09
申请号:US231749
申请日:1994-04-25
申请人: Kenichi Ueyama , Hiroshi Kawamukai
发明人: Kenichi Ueyama , Hiroshi Kawamukai
CPC分类号: G11B7/2542 , G11B5/7315 , G11B11/10593 , G11B7/24 , G11B7/2534 , G11B7/2545 , Y10S428/90 , Y10T428/31663 , Y10T428/31935
摘要: A recording medium, showing sufficient resistance to contamination and having excellent reproducing characteristics, comprises a film provided on a surface thereof and this film comprises a copolymer formed by polymerizing a composition which comprises a compound A having a (meth)acryloyl group and a reactive antistatic agent B having a quaternary ammonium salt group, an alkylene glycol chain, a hydrocarbon group of which carbon number is four or more and a copolymerizable group.
摘要翻译: 显示出足够的耐污染性和具有优异的再现特性的记录介质包括在其表面上提供的膜,该膜包含通过聚合包含具有(甲基)丙烯酰基的化合物A和反应性抗静电剂的组合物形成的共聚物 具有季铵盐基团的试剂B,亚烷基二醇链,碳数为4以上的烃基和可共聚基团。
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