公开(公告)号：US07175740B2

公开(公告)日：2007-02-13

申请号：US10396155

申请日：2003-03-25

申请人： Richard James Riehle ,  Anthony J. Allen ,  Michaela Hofbauer ,  Alfred Jacques Haandrikman ,  Ronald Busink ,  Mark T. Crisp ,  John James Hoglen ,  Huai Nan Cheng ,  Francis J. Carlin, Jr. ,  John Arthur Lapre ,  Harold Jabloner

发明人： Richard James Riehle ,  Anthony J. Allen ,  Michaela Hofbauer ,  Alfred Jacques Haandrikman ,  Ronald Busink ,  Mark T. Crisp ,  John James Hoglen ,  Huai Nan Cheng ,  Francis J. Carlin, Jr. ,  John Arthur Lapre ,  Harold Jabloner

IPC分类号： D21H17/55 ,  D21H21/20 ,  C08G69/46

CPC分类号： D21H17/55 ,  C08G73/022 ,  C08G73/0286 ,  D21H17/56 ,  D21H27/08 ,  D21H27/10

摘要： Processes for rendering a polyamine-epihalohydrin resin storage stable, including processes that prepare a storage stable resin and/or processes that treat resins. A composition containing a polyamine-epihalohydrin resin which includes CPD-forming species can be treated with at least one agent under conditions to at least one of inhibit, reduce and remove the CPD-forming species to obtain a reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin when stored for 2 weeks at 50° C., and a pH of about 2.5 to 3.5 contains less than about 250 ppm dry basis of CPD. The invention is also directed to a gelation storage stable reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin, when stored at pH 1 for 24 hours at 50° C. and measured at 24 hours, produces less than about 1000 ppm dry basis of CPD. A paper product containing the storage stable polyaminopolyamide-epihalohydrin resin, when corrected for adding at about a 1 wt % addition level of the polyaminopolyamide-epihalohydrin resin, contains less than about 250 ppb of CPD. Moreover, a resin can be prepared starting from a prepolymer having a low acid number or low concentration of acid end groups. The invention is also directed to papers containing the resins.

摘要翻译： 使多胺 - 表卤代醇树脂保存稳定的方法，包括制备储存稳定树脂的方法和/或处理树脂的方法。 包含CPD形成物质的含有多胺 - 表卤醇树脂的组合物可以在至少一种抑制，减少和除去CPD形成物质的条件下用至少一种试剂处理，以获得减少的CPD形成树脂，使得 含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存2周时，pH约2.5-3.5含有低于约250ppm干基的CPD。 本发明还涉及一种凝胶储存稳定的减少CPD形成树脂，使得含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存24小时并在24小时时测量时产生 小于约1000ppm的干燥基础的CPD。 含有储存稳定的聚氨基多酰胺 - 表卤代醇树脂的纸产品在校正后加入多氨基聚酰胺 - 表卤代醇树脂的约1重量％时含有小于约250ppb的CPD。 此外，可以从具有低酸值或低浓度酸端基的预聚物开始制备树脂。 本发明还涉及含有树脂的纸张。

公开(公告)号：US06159721A

公开(公告)日：2000-12-12

申请号：US919190

申请日：1997-08-20

申请人： Huai Nan Cheng ,  Qu-Ming Gu ,  Robert G. Nickol

发明人： Huai Nan Cheng ,  Qu-Ming Gu ,  Robert G. Nickol

IPC分类号： C08B37/00 ,  C08L5/06 ,  C12N9/50 ,  C08B37/06

CPC分类号： C08B37/0045 ,  C08L5/06

摘要： Amine modified pectins wherein the amine is a water soluble amine, amino acid, etc. and process to catalyze the reaction of water soluble polymers having alkoxyester and carboxylic acid functionality, such as polysaccharides, with a primary or secondary amine in the presence of a protease and water.

摘要翻译： 胺修饰的果胶，其中胺是水溶性胺，氨基酸等，并且在蛋白酶存在下催化具有烷氧基酯和羧酸官能团的水溶性聚合物如多糖与伯胺或仲胺的反应的方法 和水。

公开(公告)号：US08841470B1

公开(公告)日：2014-09-23

申请号：US13216841

申请日：2011-08-24

申请人： Atanu Biswas ,  Kenneth M. Doll ,  Huai Nan Cheng ,  Brajendra K. Sharma

发明人： Atanu Biswas ,  Kenneth M. Doll ,  Huai Nan Cheng ,  Brajendra K. Sharma

IPC分类号： C07C227/00 ,  C07C53/00 ,  C07C229/00 ,  C10L1/222

CPC分类号： C10M133/14 ,  C07C227/06 ,  C07C229/22 ,  C10M2205/0285 ,  C10M2215/062 ,  C10N2230/06 ,  C10N2270/00

摘要： Chemically-modified fatty acids are prepared by reacting epoxidized fatty acids, their esters or triglyceride oils with amines of cyclic or aromatic hydrocarbons. The fatty acid derivatives produced are of the formula: wherein R is an H, branched or straight chain alkyl or alkenyl group, aromatic-containing group, glycerol, or glyceride, R″ is a C3 to C29 aliphatic chain comprising one or more of the derivatized methylene groups of the formula: wherein R1 and R2 are independently selected from the group consisting of H, cyclic hydrocarbons, substituted cyclic hydrocarbons, and aryl groups, with the proviso that only one of said R1 and R2 may be H. These fatty acid derivatives have utility as antiwear/antifriction additives for industrial oils and automotive applications.

摘要翻译： 化学修饰的脂肪酸通过环氧化脂肪酸，它们的酯或甘油三酯油与环状或芳族烃的胺反应来制备。 产生的脂肪酸衍生物具有下式：其中R是H，支链或直链烷基或链烯基，含芳基的基团，甘油或甘油酯，R“是C 3至C 29脂族链，其包含一个或多个 衍生的下式的亚甲基：其中R 1和R 2独立地选自H，环烃，取代的环烃和芳基，条件是所述R 1和R 2中只有一个可以是H.这些脂肪酸 衍生物可用作工业油和汽车应用的抗磨/抗磨添加剂。

公开(公告)号：US06667384B2

公开(公告)日：2003-12-23

申请号：US10032651

申请日：2001-12-27

申请人： Qu-Ming Gu ,  Armin Michel ,  Huai Nan Cheng ,  William W. Maslanka ,  Ronald R. Staib

发明人： Qu-Ming Gu ,  Armin Michel ,  Huai Nan Cheng ,  William W. Maslanka ,  Ronald R. Staib

IPC分类号： C08G7300

CPC分类号： C08G73/0286

摘要： The present invention contemplates poly(aminoamide) pre-polymers, polyamide polymers, a multi-step process for the synthesis of these pre-polymers and polymers using acrylates and at least one monomer containing at least two primary amines, and the resins resulting from the reaction of the polymers with an epihalohydrin. These resins may be used as wet strength resins and creping aids in the papermaking industry as well as surface additives for wool.

公开(公告)号：US06554961B1

公开(公告)日：2003-04-29

申请号：US09592681

申请日：2000-06-12

申请人： Richard James Riehle ,  Anthony J. Allen ,  Michaela Hofbauer ,  Alfred Jacques Haandrikman ,  Ronald Busink ,  Mark T. Crisp ,  John James Hoglen ,  Huai Nan Cheng ,  Francis J. Carlin, Jr. ,  John Arthur Lapre ,  Harold Jabloner

发明人： Richard James Riehle ,  Anthony J. Allen ,  Michaela Hofbauer ,  Alfred Jacques Haandrikman ,  Ronald Busink ,  Mark T. Crisp ,  John James Hoglen ,  Huai Nan Cheng ,  Francis J. Carlin, Jr. ,  John Arthur Lapre ,  Harold Jabloner

IPC分类号： D21H1755

CPC分类号： D21H17/55 ,  C08G73/022 ,  C08G73/0286 ,  D21H17/56 ,  D21H27/08 ,  D21H27/10

摘要： Processes for rendering a polyamine-epihalohydrin resin storage stable, including processes that prepare a storage stable resin and/or processes that treat resins. A composition containing a polyamine-epihalohydrin resin which includes CPD-forming species can be treated with at least one agent under conditions to at least one of inhibit, reduce and remove the CPD-forming species to obtain a reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin when stored for 2 weeks at 50° C., and a pH of about 2.5 to 3.5 contains less than about 250 ppm dry basis of CPD. The invention is also directed to a gelation storage stable reduced CPD-forming resin so that a composition containing the reduced CPD-forming polyamine-epihalohydrin resin, when stored at pH 1 for 24 hours at 50° C. and measured at 24 hours, produces less than about 1000 ppm dry basis of CPD. A paper product containing the storage stable polyaminopolyamide-epihalohydrin resin, when corrected for adding at about a 1 wt % addition level of the polyaminopolyamide-epihalohydrin resin, contains less than about 250 ppb of CPD. Moreover, a resin can be prepared starting from a prepolymer having a low acid number or low concentration of acid end groups. The invention is also directed to papers containing the resins.

摘要翻译： 使多胺 - 表卤代醇树脂保存稳定的方法，包括制备储存稳定树脂的方法和/或处理树脂的方法。 包含CPD形成物质的含有多胺 - 表卤醇树脂的组合物可以在至少一种抑制，减少和除去CPD形成物质的条件下用至少一种试剂处理，以获得减少的CPD形成树脂，使得 含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存2周时，pH约2.5-3.5含有低于约250ppm干基的CPD。 本发明还涉及一种凝胶储存稳定的减少CPD形成树脂，使得含有减少的形成CPD的多胺 - 表卤代醇树脂的组合物在50℃下储存24小时并在24小时时测量时产生 小于约1000ppm的干燥基础的CPD。 含有储存稳定的聚氨基多酰胺 - 表卤代醇树脂的纸产品在校正后加入多氨基聚酰胺 - 表卤代醇树脂的约1重量％时含有小于约250ppb的CPD。 此外，可以从具有低酸值或低浓度酸端基的预聚物开始制备树脂。 本发明还涉及含有树脂的纸张。