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    Stabilizer composition
    1.
    发明授权
    Stabilizer composition 失效
    稳定剂组成

    公开(公告)号：US06492442B1

    公开(公告)日：2002-12-10

    申请号：US09676985

    申请日：2000-10-02

    Applicant: Manfred Appel ,  Hubert Trauth ,  Jürgen Krockenberger ,  Alexander Aumüller

    Inventor： Manfred Appel ,  Hubert Trauth ,  Jürgen Krockenberger ,  Alexander Aumüller

    IPC: C08K51575

    CPC classification number: C08K5/10 ,  C08K5/005 ,  C08K5/1345 ,  C08L75/04 ,  C08L35/00

    Abstract: Described is a stabilizer composition comprising a 3-arylacrylic ester, a polymeric compound having a molecular weight of at least 2000 which carries, on a polymeric framework, side groups having secondary amine functions, all substituents positioned to the amine nitrogen being other than hydrogen, a chroman derivative, and an organic phosphite and/or phosphonite. The stabilizer composition is particularly suitable for stabilizing thermoplastic polyurethane against light, oxygen and heat.

    Abstract translation: 描述了一种稳定剂组合物，其包含3-芳基丙烯酸酯，分子量至少为2000的聚合化合物，其在聚合物骨架上带有具有仲胺官能团的侧基，位于胺氮以外的所有取代基不同于氢， 苯并二氢吡喃衍生物和有机亚磷酸酯和/或亚膦酸酯。 稳定剂组合物特别适合于稳定热塑性聚氨酯以抵抗光，氧和热。

    Use of isoindolinone derivatives as stabilizers for organic materials
    2.
    发明授权
    Use of isoindolinone derivatives as stabilizers for organic materials 失效
    异吲哚啉酮衍生物作为有机材料的稳定剂的使用

    公开(公告)号：US06210657B1

    公开(公告)日：2001-04-03

    申请号：US09207624

    申请日：1998-12-09

    Applicant: Thorsten Habeck ,  Sylke Haremza ,  Hubert Trauth ,  Volker Schehlmann ,  Horst Westenfelder

    Inventor： Thorsten Habeck ,  Sylke Haremza ,  Hubert Trauth ,  Volker Schehlmann ,  Horst Westenfelder

    IPC: A61K742

    CPC classification number: A61K31/4035 ,  C08K5/3417 ,  C09D7/48 ,  C09K15/30 ,  Y10S514/844 ,  Y10S514/97 ,  Y10S514/972

    Abstract: Isoindolinone derivatives of the formula I, in which the variables have the following meanings: R1 is hydrogen, COOR4, COR4, CONR4R5, CN, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, aryl or heteroaryl, substituted or unsubstituted; R1 and R2 together are C7-C10-bicycloalkyl or C7-C10-bicycloalkenyl; R3 is hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl or heteroaryl, substituted or unsubstituted, substituents which confer solubility in water, selected from the group consisting of carboxylate, sulfonate or ammonium radicals; R4 and R5 independently of one another are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl; aryl or heteroaryl, substituted or unsubstituted; are used as stabilizers for organic materials.

    Abstract translation: 式I的异吲哚啉酮衍生物，其中变量具有以下含义：R1是氢，COOR4，COR4，CONR4R5，CN，C1-C20-烷基，C2-C10-烯基，C3-C10-环烷基，C3-C10- 环烯基，芳基或杂芳基，取代或未取代的; R1和R2一起是C7-C10-双环烷基或C7-C10-双环烯基; R3是氢，C1-C20-烷基，C2-C10-烯基，C3-C10-环烷基，C3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20 - 烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基或杂芳基，取代或未取代的赋予水溶性的取代基， 羧酸酯，磺酸酯或铵基; R 4和R 5彼此独立地是氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 3 -C 10 - 环烯基; 芳基或杂芳基，取代或未取代的;被用作有机材料的稳定剂。

    N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives
    5.
    发明授权
    N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine derivatives 失效
    N-（β-羰基 - 和β-氰基乙烯基）-2,2,6,6-四甲基 - 哌啶衍生物

    公开(公告)号：US5434202A

    公开(公告)日：1995-07-18

    申请号：US244209

    申请日：1994-06-03

    Applicant: Alfred Krause ,  Alexander Aumueller ,  Hubert Trauth

    Inventor： Alfred Krause ,  Alexander Aumueller ,  Hubert Trauth

    IPC: C07D211/46 ,  C07D211/54 ,  C07D211/58 ,  C07D401/04 ,  C07D405/06 ,  C07D409/06 ,  C08K5/3432 ,  C08K5/3435

    CPC classification number: C07D211/58 ,  C07D211/46 ,  C08K5/3435

    Abstract: N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.

    Abstract translation: PCT No.PCT / EP92 / 02733 Sec。 371日期：1994年6月3日 102（e）日期1994年6月3日PCT提交1992年11月27日PCT公布。 出版物WO93 / 11109 日期：6月10日，1993.N-（β-羰基 - 和β-氰基乙酰基）-2,2,6,6-四甲基哌啶衍生物，其中R1是COOR3，COR4，CONR4R5或CN，R2 具有R 1的意义或是C 1 -C 12 - 烷基或氢，R 3是氢，C 1 -C 8 - 烷基，C 5 -C 8 - 环烷基，C 3 -C 5 - 烯基或苯基，其可以被C1-C4- 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基，R 4和R 5各自为氢，C 1 -C 12烷基，C 5 -C 8环烷基或苯基， - 被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷氧基羰基，卤素，羟基，苯氧基，苯基，甲苯基或二甲苯基三取代，n为1-4，各个n的X和A定义 在规范中。

    Heterocyclic amidine derivatives
    6.
    发明授权
    Heterocyclic amidine derivatives 失效
    杂环脒衍生物

    公开(公告)号：US5047539A

    公开(公告)日：1991-09-10

    申请号：US511302

    申请日：1990-04-19

    Applicant: Peter Spang ,  Peter Neumann ,  Hubert Trauth

    Inventor： Peter Spang ,  Peter Neumann ,  Hubert Trauth

    IPC: C07D209/08 ,  C07D209/86 ,  C07D215/06 ,  C07D215/18 ,  C07D215/20 ,  C07D215/26 ,  C07D219/02 ,  C08K5/3417 ,  C08K5/3437

    CPC classification number: C08K5/3417 ,  C07D209/08 ,  C07D209/86 ,  C07D215/06 ,  C07D215/18 ,  C07D215/20 ,  C07D215/26 ,  C07D219/02 ,  C08K5/3437

    Abstract: Heterocyclic amidine derivatives of the general formula I ##STR1## in which the variables R.sup.1 are the same or different and denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, hydroxyl or chlorine,R.sup.2 to R.sup.5 denote hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.3 and R.sup.4 can together form a five-membered or six-membered ring,R.sup.6 denotes hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.7 denotes cyano or --COOR.sup.8, --COR.sup.8, --CONHR.sup.8 or --CONR.sup.8.sub.2, in whichR.sup.8 is a straight-chain or branched-chain C.sub.1 -C.sub.12 -alkyl group which may be interrupted by oxygen atoms, a cyclopentyl or cyclohexyl group or a phenylalkyl group having from 1 to 3 carbon atoms in the alkyl moiety,A is a chemical bond or a methylene group which may additionally carry one or two C.sub.1 -C.sub.4 -alkyl radicals, andm and n are each 1 or 2.The said heterocyclic amidine derivatives I serve as UV stabilizers for organic materials.

    Abstract translation: 其中变量R1相同或不同并表示氢，C1-C4-烷基，C1-C4-烷氧基，羟基或氯的通式I（I）的杂环脒衍生物，R2至R5表示氢或 C 1 -C 4烷基和R 3和R 4可以一起形成五元或六元环，R 6表示氢或C 1 -C 8 - 烷基，R 7表示氰基或-COOR 8，-COR 8，-CONHR 8或-CONR 82，其中 R8是可以被氧原子间隔的直链或支链C 1 -C 12烷基，在烷基部分具有1至3个碳原子的环戊基或环己基或苯基烷基，A是化学键 或可以另外携带一个或两个C 1 -C 4 - 烷基的亚甲基，m和n各自为1或2.所述杂环脒衍生物I用作有机材料的UV稳定剂。

    Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials
    7.
    发明授权
    Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials 失效
    双酚（3.3.1）壬烷衍生物，用于稳定有机物质

    公开(公告)号：US4943391A

    公开(公告)日：1990-07-24

    申请号：US286295

    申请日：1988-12-10

    Applicant: Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

    Inventor： Alexander Aumueller ,  Peter Neumann ,  Hubert Trauth

    IPC: C07D471/08 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3442 ,  C09D7/12 ,  C09K15/18

    CPC classification number: C07D471/08

    Abstract: Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.

    Abstract translation: 双环[3.3.1]通式（I）的壬烷衍生物其中n是1至70的整数，R 1是氢，R 2是氢或羟基，或者基团R 3和R 4 各自独立地为其它苯基或1-或2-萘基，该苯基或萘基各自可被1,2或3个C 1 -C 12烷基，C 1 -C 12烷氧基，氯，溴，氟，三氟甲基或氰基取代 在2或3个取代基的情况下，这些取代基相同或不同，A和B各自独立地为化学键，C 1 -C 22 - 亚烷基，亚环烷基，其中m和o分别为 1至20，R 10为氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 7 -C 18 - 苯基烷基，苯基或C 2 -C 22 - 氰基烷基，M为式 A不仅通过氮原子而且通过碳原子，并且R 11，R 12，R 13和R 14各自独立地为C 1 -C 4 - 烷基，或者R 11和R 12和/或R 13和R 14分别为四甲基 烯或五亚甲基，R 5是氢，氰基，羟基，R 15是氢，C 1 -C 22 - 烷基，C 5 -C 12 - 环烷基，C 5 -C 16 - 苯基烷基或5-或6-元杂环 或者当n为1时，-MB-R 5为式（VI）的基团，其中R 16为C 1 -C 4 - 烷基，R 17为氢，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基 和R18是氢或C1-C12烷基，在塑料方面具有非常好的稳定性，是无色的，与有机聚合物高度相容并且对热分解是稳定的。

    Stabilizers
    8.
    发明授权
    Stabilizers 失效
    稳定剂

    公开(公告)号：US4680327A

    公开(公告)日：1987-07-14

    申请号：US823744

    申请日：1986-01-29

    Applicant: Albert Hettche ,  Stefan Weiss ,  Hubert Trauth ,  Peter Lechtken ,  Michael Horner

    Inventor： Albert Hettche ,  Stefan Weiss ,  Hubert Trauth ,  Peter Lechtken ,  Michael Horner

    IPC: C08K5/11 ,  C08K5/00 ,  C08K5/10 ,  C08K5/103 ,  C08K5/1545 ,  C08L101/00 ,  C08K5/15

    CPC classification number: C08K5/1545 ,  C08K5/103

    Abstract: Stabilizers consisting of (a) 2,5,7,8-tetramethyl-2-(2'-stearyloxyethyl)-chroman and (b) glyceryl stearate, glyceryl hydroxystearate, partial esters of stearic acid with condensates of glycerol and trimethylolpropane, triglyceryl stearate and/or tetraglyceryl stearate, with or without further conventional additives, the weight ratio of (a) to (b) being from 10:1 to 1:10, give improved stabilization to discoloration and superior stability during processing when used in plastics such as polyethylene or polypropylene.

    Abstract translation: 稳定剂由（a）2,5,7,8-四甲基-2-（2'-硬脂酰氧基乙基） - 苯并二氢吡喃和（b）硬脂酸甘油酯，羟基硬脂酸甘油酯，硬脂酸与甘油和三羟甲基丙烷缩合物的偏酯，硬脂酸甘油三酯 和/或四甘油硬脂酸酯，使用或不含其它常规添加剂时，（a）至（b）的重量比为10:1至1:10，当在塑料中使用时，提供改进的变色稳定性和加工过程中优异的稳定性 聚乙烯或聚丙烯。

    4-formylamino-N-methylpiperidine derivatives, the use thereof as stabilizers and organic material stabilized therewith
    9.
    发明授权
    4-formylamino-N-methylpiperidine derivatives, the use thereof as stabilizers and organic material stabilized therewith 有权
    4-甲酰氨基-N-甲基哌啶衍生物，其作为稳定剂的用途和用其稳定的有机物质

    公开(公告)号：US06737527B2

    公开(公告)日：2004-05-18

    申请号：US10239213

    申请日：2002-09-27

    Applicant: Sylke Haremza ,  Jürgen Krockenberger ,  Manfred Appel ,  Hubert Trauth ,  Alexander Aumüller

    Inventor： Sylke Haremza ,  Jürgen Krockenberger ,  Manfred Appel ,  Hubert Trauth ,  Alexander Aumüller

    IPC: C07D21158

    CPC classification number: C07D211/58 ,  C08K5/3435 ,  C09D7/48

    Abstract: The present invention relates to 4-formylamino-N-methylpiperidine derivatives of the formula (I) where the variables are as defined in the Description, to a process for preparing these piperidine derivatives, to the use of these piperidine derivatives of the invention, or prepared according to the invention, for stabilizing organic material, in particular for stabilizing plastics or coating materials, and also to the use of these piperidine derivatives of the invention, or prepared according to the invention, as light stabilizers or stabilizers for wood surfaces. The present invention further relates to stabilized organic material which comprises these piperidine derivatives of the invention or prepared according to the invention.

    Abstract translation: 本发明涉及式（I）的4-甲酰基氨基-N-甲基哌啶衍生物，其中变量如说明书中所定义，涉及制备这些哌啶衍生物的方法，使用本发明的这些哌啶衍生物，或 根据本发明制备的，用于稳定有机材料，特别是用于稳定塑料或涂层材料，以及本发明的这些哌啶衍生物或根据本发明制备的用作木材表面的光稳定剂或稳定剂的用途。 本发明还涉及包含本发明的或根据本发明制备的这些哌啶衍生物的稳定的有机材料。

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