公开(公告)号：US4680327A

公开(公告)日：1987-07-14

申请号：US823744

申请日：1986-01-29

申请人： Albert Hettche ,  Stefan Weiss ,  Hubert Trauth ,  Peter Lechtken ,  Michael Horner

发明人： Albert Hettche ,  Stefan Weiss ,  Hubert Trauth ,  Peter Lechtken ,  Michael Horner

IPC分类号： C08K5/11 ,  C08K5/00 ,  C08K5/10 ,  C08K5/103 ,  C08K5/1545 ,  C08L101/00 ,  C08K5/15

CPC分类号： C08K5/1545 ,  C08K5/103

摘要： Stabilizers consisting of (a) 2,5,7,8-tetramethyl-2-(2'-stearyloxyethyl)-chroman and (b) glyceryl stearate, glyceryl hydroxystearate, partial esters of stearic acid with condensates of glycerol and trimethylolpropane, triglyceryl stearate and/or tetraglyceryl stearate, with or without further conventional additives, the weight ratio of (a) to (b) being from 10:1 to 1:10, give improved stabilization to discoloration and superior stability during processing when used in plastics such as polyethylene or polypropylene.

摘要翻译： 稳定剂由（a）2,5,7,8-四甲基-2-（2'-硬脂酰氧基乙基） - 苯并二氢吡喃和（b）硬脂酸甘油酯，羟基硬脂酸甘油酯，硬脂酸与甘油和三羟甲基丙烷缩合物的偏酯，硬脂酸甘油三酯 和/或四甘油硬脂酸酯，使用或不含其它常规添加剂时，（a）至（b）的重量比为10:1至1:10，当在塑料中使用时，提供改进的变色稳定性和加工过程中优异的稳定性 聚乙烯或聚丙烯。

公开(公告)号：US4621109A

公开(公告)日：1986-11-04

申请号：US743682

申请日：1985-06-11

申请人： Peter Lechtken ,  Hubert Trauth ,  Stefan Weiss ,  Albert Hettche

发明人： Peter Lechtken ,  Hubert Trauth ,  Stefan Weiss ,  Albert Hettche

IPC分类号： A23K1/16 ,  A23L3/34 ,  A23L3/3544 ,  A61K8/49 ,  A61K47/22 ,  C07D327/06 ,  C09K15/12 ,  C08K5/46

CPC分类号： C09K15/12 ,  C07D327/06

摘要： 2,3-Dihydrobenz-4-oxa-1-thiins of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, methyl or methoxy, and R.sup.2 and R.sup.3 together may furthermore be a fused benzene ring, R.sup.4 is hydrogen or an m-valent aliphatic hydrocarbon radical which may be interrupted by sulfur and /or carry thiol groups as substituents, or is halogen when n is zero, X is --O--, --S-- or --O--CO--, m is 1 or 2 and n is zero or 1, are useful as antioxidants for organic materials.

摘要翻译： 通式I的2,3-二氢苯并-4-氧杂-1-硫杂，其中R 1，R 2和R 3各自为氢，甲基或甲氧基，R 2和R 3一起还可以为稠合苯环，R 4 是氢或可被硫中断和/或携带硫醇基团作为取代基的m价脂肪族烃基，或当n为0时为卤素，X为-O - ， - S-或-O-CO-，m 为1或2，n为0或1，可用作有机材料的抗氧化剂。

公开(公告)号：US4806580A

公开(公告)日：1989-02-21

申请号：US107461

申请日：1987-10-09

申请人： Gustav Bock ,  Hubert Trauth ,  Wilhelm Weber ,  Peter Lechtken

发明人： Gustav Bock ,  Hubert Trauth ,  Wilhelm Weber ,  Peter Lechtken

IPC分类号： C09K15/08 ,  C08K5/1545 ,  C08K5/378 ,  C08K5/524 ,  C08K5/53 ,  C08K5/5393 ,  C08L101/00 ,  C09K15/14 ,  C09K15/32 ,  C08K5/52 ,  C08K5/15

CPC分类号： C08K5/524 ,  C08K5/1545 ,  C08K5/378 ,  C08K5/5393

摘要： Stabilizer mixtures for stabilizing plastics comprising one part by weight of a chroman derivative (I) of the general formula ##STR1## where R= ##STR2## where Z=C.sub.7 -C.sub.30 -alkyl, --CH.sub.2 CH.sub.2 --S--[C.sub.1 -C.sub.30 -alkyl] or ##STR3## and from 5 to 14 parts by weight of an organic phosphite of the general formula (II) ##STR4## where R.sup.1, R.sup.2 and R.sup.3 are identical of different alkyl and/or aryl or of an organic phosphonite of the formula (III) ##STR5## where +is C(CH.sub.3).sub.3, a mixing ratio (a):(b) of from 1:6 to 1:10 being preferred.

摘要翻译： 用于稳定塑料的稳定剂混合物，其包含1重量份的通式为其中R = C 1 -C 30 - 烷基，-CH 2 CH 2 -S- [C 1 -C 30 - 烷基]或[IMAGE]和5至14重量份的通式（II）的有机亚磷酸酯其中R 1，R 2和R 3与不同的烷基和/或芳基相同，或 的式（III）的有机亚膦酸盐其中+是C（CH 3）3，混合比（a）：（b）为1:6至1:10是优选的。

公开(公告)号：US4966734A

公开(公告)日：1990-10-30

申请号：US324044

申请日：1989-03-16

申请人： Ulrich Hoercher ,  Peter Lechtken

发明人： Ulrich Hoercher ,  Peter Lechtken

IPC分类号： C11C1/08 ,  A61K31/23 ,  C11B3/02

CPC分类号： C11B3/02 ,  A61K31/23

摘要： Undesirable odors are removed from fatty ester mixtures which, in addition to other components, contain the esters of highly unsaturated fatty acids, in particular of highly unsaturated 3-fatty acids, such as eicosapentaenoic acid or docosahexaenoic acid, by a process in which the fatty ester mixture is treated with a complex hydride, in particular with sodium borohydride solution. The process is particularly suitable for removing undesirable odors from fatty ester mixtures obtained from fish oil, for example by transesterification with an alkanol of 1 to 3 carbon atoms.

摘要翻译： 从脂肪酯混合物中除去不希望的气味，除脂肪酯混合物外，除了其它成分外还含有高度不饱和脂肪酸的酯，特别是高度不饱和的3-脂肪酸的酯，如二十碳五烯酸或二十二碳六烯酸， 酯混合物用复合氢化物，特别是用硼氢化钠溶液处理。 该方法特别适用于从由鱼油获得的脂肪酯混合物中除去不需要的气味，例如通过与1至3个碳原子的链烷醇进行酯交换。

公开(公告)号：US4510146A

公开(公告)日：1985-04-09

申请号：US376586

申请日：1982-05-10

申请人： Peter Lechtken ,  Axel Nuerrenbach ,  Juergen Schole

发明人： Peter Lechtken ,  Axel Nuerrenbach ,  Juergen Schole

IPC分类号： A23K1/16 ,  A23K1/18 ,  C07D215/60 ,  A61K31/47

CPC分类号： C07D215/60 ,  A23K20/132 ,  A23K50/30

摘要： Animal feeds and drinks containing small amounts of compounds of the formula Ia or Ib ##STR1## where R.sup.1 is hydrogen, low molecular weight alkyl or alkoxy, or halogen, R.sup.2 is hydrogen or low molecular weight alkyl and R.sup.3 and R.sup.4 are hydrogen or a low molecular weight aliphatic or araliphatic radical. The compounds of the formulae Ia and Ib promote growth without exerting an antibiotic action.

摘要翻译： 含有少量式Ia或Ib化合物的动物饲料和饮料，其中R 1是氢，低分子量烷基或烷氧基或卤素，R 2是氢或低分子量烷基，R 3和R 4 是氢或低分子量脂族或芳脂族基。 式Ia和Ib的化合物促进生长而不施加抗生素作用。

公开(公告)号：US4710523A

公开(公告)日：1987-12-01

申请号：US571794

申请日：1984-01-18

申请人： Peter Lechtken ,  Ingolf Buethe ,  Manfred Jacobi ,  Werner Trimborn

发明人： Peter Lechtken ,  Ingolf Buethe ,  Manfred Jacobi ,  Werner Trimborn

IPC分类号： C07F9/32 ,  C07F9/40 ,  C07F9/46 ,  C07F9/48 ,  C07F9/53 ,  C08F2/50 ,  C08F4/00 ,  C08F4/32 ,  G03F7/029 ,  C08L63/10

CPC分类号： C07F9/4065 ,  C07F9/3252 ,  C07F9/46 ,  C07F9/48 ,  C07F9/4841 ,  C07F9/5337 ,  G03F7/029

摘要： Acylphosphine oxide compounds of the general formula ##STR1## where R.sup.1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical,R.sup.2 has one of the meanings of R.sup.1 (but R.sup.1 and R.sup.2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R.sup.1 and R.sup.2 together form a ring andR.sup.3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkylthio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R.sup.3 is .alpha.-naphthyl substituted by A and B at least in the 2- and 8-positions or is .beta.-naphthyl substituted by A and B at least in the 1- and 3-positions, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula ##STR2## where X is chlorine or bromine, and a phosphine of the general formula ##STR3## and the use of these acylphosphine oxide compounds as photoinitiators in photopolymerizable surface coatings, finishes and printing inks.

摘要翻译： 其中R1是烷基，环己基，环戊基，未被取代或被卤素，烷基或烷氧基取代的芳基，或含S或N的五元或六元杂环基的酰基氧化膦化合物 ，R 2具有R 1的含义（但R 1和R 2可以相同或不同）或者是烷氧基，芳氧基或芳烷氧基，或者R 1和R 2一起形成环，R 3是至少二取代的苯基，吡啶基，呋喃基或噻吩基 至少在与羰基的连接点相邻的两个碳原子上具有可以相同或不同的取代基A和B的基团，并且各自为1-6个碳原子的烷基，烷氧基或烷硫基 5至7个碳原子的环烷基，苯基或卤素，或R3是至少在2-和8-位被A和B取代的α-萘基，或至少在1-位上由A和B取代的β-萘基， 和3-位，这些酰基氧化物的制备方法 e化合物，其中X为氯或溴的通式为“IMAGE”的酰卤，以及通式为“IMAGE”的膦，以及这些酰基氧化膦化合物作为可光聚合表面涂料，表面处理剂和印刷油墨中的光引发剂的用途。

公开(公告)号：US4515982A

公开(公告)日：1985-05-07

申请号：US450097

申请日：1982-12-15

申请人： Peter Lechtken ,  Gerhard Mueller ,  Klaus Schmieder

发明人： Peter Lechtken ,  Gerhard Mueller ,  Klaus Schmieder

IPC分类号： C09K15/20 ,  A23L3/34 ,  A23L3/3526 ,  C07C67/00 ,  C07C213/00 ,  C07C225/20 ,  C07C227/00 ,  C07C229/14 ,  C07D265/36 ,  C09K15/30 ,  C07C101/12

CPC分类号： C07D265/36 ,  C09K15/30

摘要： Organic materials which contain from 0.001 to 10% by weight of an aminoreductone I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are H, methyl or ethyl and R.sup.4 is the radical of a naturally occurring .alpha.- or .beta.-aminoacid or of a C.sub.1 -C.sub.10 -alkyl ester thereof or, in the case of an .alpha.-aminoacid, a lactone having a 2--OH group in the cyclohexenone ring, or R.sup.4 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by --OH, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -acyloxy, or is --(CH.sub.2 --CH.sub.2 --O).sub.n H, which may be etherified with a C.sub.1 -C.sub.4 -alkanol or esterified with a C.sub.1 -C.sub.4 -fatty acid, and where n is from 2 to 10, or a mineral salt thereof.Novel compounds Ia differ from I in having the radical R.sup.4a, where R.sup.4a is R.sup.4 with the exception of methyl. Compounds I are prepared by reacting the corresponding 2,3-dihydroxycyclohex-2-en-1-one with an amine HN(R.sup.3)R.sup.4 or a mineral acid salt thereof.

摘要翻译： 含有0.001至10重量％的氨基还原酮I的有机材料，其中R 1，R 2和R 3是H，甲基或乙基，R 4是天然存在的α-或β-氨基酸或C1 -C 10 - 烷基酯，或在α-氨基酸的情况下，在环己烯酮环中具有2-OH基团的内酯，或R4是未被取代或被-OH取代的C1-C20烷基，C1-C4 - 烷氧基或C 1 -C 4 - 酰氧基，或是 - （CH 2 -CH 2 -O）n H，其可以用C 1 -C 4烷醇醚化或用C 1 -C 4脂肪酸酯化，并且其中n为2至 10或其矿物盐。 新颖的化合物Ia与具有自由基R4a的不同之处在于，R4a除了甲基以外是R4a。 化合物I通过使相应的2,3-二羟基环己-2-烯-1-酮与胺HN（R3）R4或其无机酸盐反应来制备。

公开(公告)号：US4298738A

公开(公告)日：1981-11-03

申请号：US148665

申请日：1980-05-12

申请人： Peter Lechtken ,  Ingolf Buethe ,  Manfred Jacobi ,  Werner Trimborn

发明人： Peter Lechtken ,  Ingolf Buethe ,  Manfred Jacobi ,  Werner Trimborn

IPC分类号： C07F9/32 ,  C07F9/40 ,  C07F9/46 ,  C07F9/48 ,  C07F9/53 ,  C08F2/50 ,  C08F4/00 ,  C08F4/32 ,  G03F7/029

CPC分类号： C07F9/4065 ,  C07F9/3252 ,  C07F9/46 ,  C07F9/48 ,  C07F9/4841 ,  C07F9/5337 ,  G03F7/029

摘要： Acylphosphine oxide compounds of the general formula ##STR1## where R.sup.1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical,R.sup.2 has one of the meanings of R.sup.1 (but R.sup.1 and R.sup.2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R.sup.1 and R.sup.2 together form a ring andR.sup.3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkythio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R.sup.3 is .alpha.-naphthyl substituted by A and B at least in the 2- and 8-positions or is .beta.-naphthyl substituted by A and B at least in the 1- and 3-positions, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula ##STR2## where X is chlorine or bromine, and a phosphine of the general formula ##STR3## and the use of these acylphosphine oxide compounds as photoinitiators in photopolymerizable surface coatings, finishes and printing inks.

摘要翻译： 其中R1是烷基，环己基，环戊基，未被取代或被卤素，烷基或烷氧基取代的芳基，或含S或N的五元或六元杂环基的酰基氧化膦化合物 ，R 2具有R 1的含义（但R 1和R 2可以相同或不同）或者是烷氧基，芳氧基或芳烷氧基，或者R 1和R 2一起形成环，R 3是至少二取代的苯基，吡啶基，呋喃基或噻吩基 至少在与羰基的连接点相邻的两个碳原子上具有可以相同或不同的取代基A和B的基团，并且各自为1至6个碳原子的烷基，烷氧基或链烯基 5至7个碳原子的环烷基，苯基或卤素，或R3是至少在2-和8-位被A和B取代的α-萘基，或至少在1-位上由A和B取代的β-萘基， 和3-位，这些酰基氧化膦的制备方法 其中X是氯或溴的通式为“IMAGE”的酰卤，以及通式为“IMAGE”的膦，以及这些酰基氧化膦化合物作为可光聚合表面涂料，表面处理剂和印刷油墨中的光引发剂的用途。

公开(公告)号：US4929249A

公开(公告)日：1990-05-29

申请号：US347223

申请日：1989-05-04

申请人： Peter Lechtken ,  Peter Kutschera

发明人： Peter Lechtken ,  Peter Kutschera

IPC分类号： D06P5/12 ,  D06P1/642 ,  D06P5/13 ,  D06P5/15

CPC分类号： D06P5/15 ,  D06P1/642 ,  Y10S8/921 ,  Y10S8/922 ,  Y10S8/924

摘要： Textile materials made of polyester, triacetate, acetate or polyamide or mixtures thereof are printed by the discharge printing or discharge resist printing technique by using as discharging agent for disperse dyes a 3-aminoreductone of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and each is hydrogen, methyl or ethyl and R.sup.4 is linear or branched alkyl or alkenyl of from 1 to 20 carbon atoms, which may be monosubstituted or polysubstituted by hydroxyl, alkoxy of from 1 to 3 carbon atoms in the alkyl or acetoxy, or is a radical --(CH.sub.2 --CH.sub.2 --O).sub.n H where n is from 1 to 10 and which may be etherified with alkyl of from 1 to 3 carbon atoms or esterified with acetyl, or R.sup.4 together with the N-atom is the radical of an aliphatic .alpha.- or .beta.-amino acid of from 2 to 15 carbon atoms, in which case the carboxyl group may be present in neutralized form as an alkali metal, alkaline earth metal or ammonium salt or in esterified form as a C.sub.1 -c.sub.10 -alkyl ester, or a mineral acid salt thereof.

摘要翻译： 使用聚酯，三乙酸酯，乙酸酯或聚酰胺或其混合物制成的纺织材料通过使用分散染料作为分散染料的分散剂通过放电印刷或放电抗蚀剂印刷技术印制，其中R1，R2和R3的3-氨基三烯酮 相同或不同，各自为氢，甲基或乙基，R4为具有1至20个碳原子的直链或支链烷基或链烯基，其可被羟基取代或多取代，烷基中有1至3个碳原子的烷氧基或 乙酰氧基，或是其中n为1至10并且可以与1至3个碳原子的烷基醚化或与乙酰基或R4一起与N-原子酯化的基团 - （CH 2 -CH 2 -O）n H 2至15个碳原子的脂族α-或β-氨基酸的基团，在这种情况下，羧基可以中和形式存在，作为碱金属，碱土金属或铵盐，或以酯化形式存在为C1 -10-烷基酯或无机酸 的盐。

公开(公告)号：US4925960A

公开(公告)日：1990-05-15

申请号：US337840

申请日：1989-04-13

申请人： Peter Lechtken ,  Ulrich Hoercher ,  Barbara Jessel

发明人： Peter Lechtken ,  Ulrich Hoercher ,  Barbara Jessel

IPC分类号： C07D311/72

CPC分类号： C07D311/72

摘要： d-.alpha.-Tocopherol is prepared from a mixture obtained from natural intermediates and containing .alpha.-, .beta.-, .gamma.- and .delta.-tocopherols, by methylation at the aromatic ring of the tocopherols by reaction with formaldehyde or with a compound which donates formaldehyde under the reaction conditions, and subsequent catalytic hydrogenation, by a process in which the reaction with formaldehyde or with the formaldehyde donor is carried out at from 150.degree. to 200.degree. C. in the presence of an alkyl ester of phosphoric or phosphorous acid.

摘要翻译： d-α-生育酚由天然中间体获得并含有α-，β-，γ-和δ-生育酚的混合物通过与甲醛或与向甲醛施用的化合物在生育酚的芳环上甲基化而制备 反应条件和随后的催化氢化，其中在甲酸或甲醛供体的反应在150℃至200℃下在磷酸或亚磷酸的烷基酯存在下进行。