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公开(公告)号：US06656595B2
公开(公告)日：2003-12-02
申请号：US09975197
申请日：2001-10-12
申请人： Yoshio Nakajima , Yoshiyuki Yukawa , Isao Kamimori
发明人： Yoshio Nakajima , Yoshiyuki Yukawa , Isao Kamimori
IPC分类号： B32B2738
CPC分类号： C08F265/04 , C08F257/02 , C08F265/06 , C08F290/06 , C08L51/003 , C09D151/003 , Y10T428/31511 , Y10T428/31938
摘要： This invention relates to use of copolymers which are obtained through copolymerization, in the presence of a radical-polymerization initiator, of monomeric mixtures comprising: macromonomers obtained by (co)polymerizing, in the presence of a metal complex which is a catalytic chain transfer agent or an addition-cleavage-type chain transfer agent, and optionally a radical-polymerization initiator, at least one polymerizable monomer selected from methacrylic acid esters and styrene and if necessary methacrylic acid, or the macromonomers into which polymerizable unsaturated groups are further introduced; polymerizable unsaturated monomers containing at least one ionic functional group selected from amino, quaternary ammonium salt and sulfonic acid groups; polyoxyalkylene chain-containing nonionic polymerizable unsaturated monomers; and other ethylenically unsaturated monomers (D); and also such copolymers into which long chain alkyl groups are further introduced, as pigment-dispersing resins to be used in water-based paints.
摘要翻译： 本发明涉及在自由基聚合引发剂的存在下，通过共聚单体混合物共聚获得的共聚物的用途，所述单体混合物包含：通过（共）聚合得到的大分子单体，所述金属配合物是催化链转移剂 或加成裂解型链转移剂和任选的自由基聚合引发剂，至少一种选自甲基丙烯酸酯和苯乙烯以及如果需要的可聚合单体的甲基丙烯酸或其中引入可聚合不饱和基团的大分子单体;可聚合的单体 含有至少一个选自氨基，季铵盐和磺酸基的离子官能团的不饱和单体;含聚氧化烯链的非离子可聚合不饱和单体; 和其它烯属不饱和单体（D）; 以及进一步引入长链烷基的这种共聚物作为用于水性涂料的颜料分散树脂。
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公开(公告)号：US20050252418A1
公开(公告)日：2005-11-17
申请号：US11168539
申请日：2005-06-29
IPC分类号： C08F220/28 , C08F220/34 , C08F246/00 , C09D11/00 , G03C1/492
CPC分类号： C09D11/326 , C08F220/28 , C08F220/34 , C08F246/00
摘要： This invention provides both a pigment dispersing resin which is a copolymer of (A) polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of tertiary amino group, quaternary ammonium salt and sulfonic acid group; (B) nonionic polymerizable unsaturated monomer having polyoxyalkylene chain; (C) ultraviolet-absorbing polymerizable unsaturated monomer and/or an ultraviolet-stabilizing polymerizable unsaturated monomer; and (D) other ethylenically unsaturated monomer, and water-based pigment dispersion which comprises said pigment dispersing resin, pigment, aqueous medium and, as circumstances may demand, dispersing agent as well.
摘要翻译： 本发明提供了一种颜料分散树脂，它是（A）含有选自叔氨基，季铵盐和磺酸基团中的至少一种离子官能团的可聚合不饱和单体的共聚物; （B）具有聚氧化烯链的非离子可聚合不饱和单体; （C）紫外线吸收性聚合性不饱和单体和/或紫外线稳定化聚合性不饱和单体; 和（D）其它烯属不饱和单体，以及包含所述颜料分散树脂，颜料，水性介质以及根据需要的分散剂的水性颜料分散体。
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3.发明授权Pigment dispersing resin and water-based pigment dispersion which contains the same 失效颜料分散树脂和含有相同颜料的水性颜料分散体公开(公告)号：US06852817B2
公开(公告)日：2005-02-08
申请号：US10400439
申请日：2003-03-28
申请人： Yoshiyuki Yukawa , Yuko Hoshida , Isao Kamimori
发明人： Yoshiyuki Yukawa , Yuko Hoshida , Isao Kamimori
IPC分类号： C08F220/28 , C09B67/46 , C09D7/45 , C09D17/00 , C08F222/24
CPC分类号： C09B67/0089 , C08F220/28 , C09D7/45 , C09D17/001
摘要： This invention provides a pigment dispersing resin which is a copolymer of: (A) sulfonic group-containing polymerizable unsaturated monomer, (B) polyoxyalkylene chain-containing nonionic polymerizable unsaturated monomer, (C) (C-1) (meth)acrylic acid ester type polymerizable monomer having two tertiary alkyl groups per molecule and/or (C-2) (meth)acrylic acid ester type polymerizable monomer having one tertiary alkyl group and one secondary hydroxyl group per molecule, and (D) other ethylenically unsaturated monomer; and also provides water-based pigment dispersion which comprises said pigment dispersing resin, pigment, aqueous medium and, as circumstances may demand, basic neutralizer and/or dispersing agent as well.
摘要翻译： 本发明提供一种颜料分散树脂，它是以下共聚物：（A）含磺酸基的可聚合不饱和单体，（B）含聚氧化烯链的非离子聚合性不饱和单体，（C）（C-1）（甲基）丙烯酸酯 （C-2）（甲基）丙烯酸酯型聚合性单体，（D）其它烯键式不饱和单体;（D）其它烯键式不饱和单体， 并且还提供包含所述颜料分散树脂，颜料，水性介质以及根据需要的碱性中和剂和/或分散剂的水性颜料分散体。
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公开(公告)号：US06548174B2
公开(公告)日：2003-04-15
申请号：US09893564
申请日：2001-06-29
申请人： Yoshio Nakajima , Yoshiyuki Yukawa , Isao Kamimori
发明人： Yoshio Nakajima , Yoshiyuki Yukawa , Isao Kamimori
IPC分类号： B32B2738
CPC分类号： C08F8/14 , C08F290/04 , C08F2810/20 , C08F2810/30 , C09D151/00 , Y10T428/31511 , Y10T428/31938
摘要： This invention relates to use of a copolymer of a high acid value macromonomer which is obtained through copolymerization of specific monomeric components including methacrylic acid in the presence of a metal complex which is a catalytic chain transfer agent or an addition cleavage-type chain transfer agent, and optionally a radical-polymerization initiator, or this macromonomer into which a polymerizable unsaturated group is further introduced, with an ethylenically unsaturated monomer; and said copolymer into which further a long chain alkyl group is introduced; as pigment-dispersing resins to be used in water-based paint.
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公开(公告)号：US08071170B2
公开(公告)日：2011-12-06
申请号：US11655228
申请日：2007-01-19
申请人： Isao Kamimori , Ikumi Ono , Takashi Kawasaki
发明人： Isao Kamimori , Ikumi Ono , Takashi Kawasaki
摘要： The present invention provides methods of forming multi-layered patterned coating films comprising the steps of (1) applying a first colored base coating composition to a substrate, (2) applying a second colored base coating composition over the uncured coating film of the first colored base coating composition in such a manner that the first colored base coating film is partially exposed, the second colored base coating composition being able to form a coating film of different color and/or visual texture from that of the first colored base coating composition, and having, 30 seconds after application, 30 to 60 mass % of the solids content of the base coating composition, and (3) applying a top clear coating composition over the cured or uncured first and second colored base coating compositions, and curing the uncured composition(s).
摘要翻译： 本发明提供了形成多层图案化涂膜的方法，包括以下步骤：（1）将第一着色底涂层组合物施加到基底上，（2）将第二着色底涂层组合物涂覆在第一着色 所述第一着色基底涂膜部分地露出，所述第二着色底涂层组合物能够形成与所述第一着色底涂层组合物不同颜色和/或视觉质地的涂膜，以及 在涂布后30秒，30〜60质量％的基础涂料组合物的固体成分，和（3）在固化或未固化的第一和第二着色底涂层组合物上施加顶部透明涂料组合物，并固化未固化组合物 （s）。
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公开(公告)号：US07026392B2
公开(公告)日：2006-04-11
申请号：US10149676
申请日：2001-10-12
CPC分类号： C09D11/326 , B41M5/5245 , C08F290/06 , C08F290/061 , C08F290/062 , C08F290/14 , C09B67/0089 , C09D5/027 , C09D7/45 , C09D17/001
摘要： This invention relates to the use of a copolymer of polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of quaternary ammonium salt group and sulfonic acid group, nonionic polymerizable unsaturated monomer having polyoxyalkylene chain, and other ethylenically unsaturated monomer, as a pigment dispersing resin for water-based paint or water-based ink.
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公开(公告)号：US20060052514A1
公开(公告)日：2006-03-09
申请号：US11246097
申请日：2005-10-11
IPC分类号： C08F8/30
CPC分类号： C09D11/326 , B41M5/5245 , C08F290/06 , C08F290/061 , C08F290/062 , C08F290/14 , C09B67/0089 , C09D5/027 , C09D7/45 , C09D17/001
摘要： This invention relates to the use of a copolymer of polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of quaternary ammonium salt group and sulfonic acid group, nonionic polymerizable unsaturated monomer having polyoxyalkylene chain, and other ethylenically unsaturated monomer, as a pigment dispersing resin for water-based paint or water-based ink.
摘要翻译： 本发明涉及含有选自季铵盐基和磺酸基的至少一种离子官能团的聚合性不饱和单体的共聚物，具有聚氧化烯链的非离子可聚合不饱和单体和其它烯属不饱和单体 ，作为水性涂料或水性油墨的颜料分散树脂。
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公开(公告)号：US06994745B2
公开(公告)日：2006-02-07
申请号：US10116104
申请日：2002-04-05
CPC分类号： C09D11/326 , C08F220/28 , C08F220/34 , C08F246/00
摘要： This invention provides both a pigment dispersing resin which is a copolymer of: (A) polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of tertiary amino group, quaternary ammonium salt and sulfonic acid group; (B) nonionic polymerizable unsaturated monomer having polyoxyalkylene chain; (C) ultraviolet-absorbing polymerizable unsaturated monomer and/or an ultraviolet-stabilizing polymerizable unsaturated monomer; and (D) other ethylenically unsaturated monomer, and water-based pigment dispersion which comprises said pigment dispersing resin, pigment, aqueous medium and, as circumstances may demand, dispersing agent as well.
摘要翻译： 本发明提供作为共聚物的颜料分散树脂
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公开(公告)号：US07271213B2
公开(公告)日：2007-09-18
申请号：US11168539
申请日：2005-06-29
CPC分类号： C09D11/326 , C08F220/28 , C08F220/34 , C08F246/00
摘要： This invention provides both a pigment dispersing resin which is a copolymer of: (A) polymerizable unsaturated monomer containing at least one kind of ionic functional group selected from the group consisting of tertiary amino group, quaternary ammonium salt and sulfonic acid group; (B) nonionic polymerizable unsaturated monomer having polyoxyalkylene chain; (C) ultraviolet-absorbing polymerizable unsaturated monomer and/or an ultraviolet-stabilizing polymerizable unsaturated monomer; and (D) other ethylenically unsaturated monomer, and water-based pigment dispersion which comprises said pigment dispersing resin, pigment, aqueous medium and, as circumstances may demand, dispersing agent as well.
摘要翻译： 本发明提供了一种颜料分散树脂，它是以下物质的共聚物：（A）含有选自叔氨基，季铵盐和磺酸基团中的至少一种离子官能团的可聚合不饱和单体; （B）具有聚氧化烯链的非离子可聚合不饱和单体; （C）紫外线吸收性聚合性不饱和单体和/或紫外线稳定化聚合性不饱和单体; 和（D）其它烯属不饱和单体，以及包含所述颜料分散树脂，颜料，水性介质以及根据需要的分散剂的水性颜料分散体。
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公开(公告)号：US20070172692A1
公开(公告)日：2007-07-26
申请号：US11655228
申请日：2007-01-19
申请人： Isao Kamimori , Ikumi Ono , Takashi Kawasaki
发明人： Isao Kamimori , Ikumi Ono , Takashi Kawasaki
摘要： The present invention provides methods of forming multi-layered patterned coating films comprising the steps of (1) applying a first colored base coating composition to a substrate, (2) applying a second colored base coating composition over the uncured coating film of the first colored base coating composition in such a manner that the first colored base coating film is partially exposed, the second colored base coating composition being able to form a coating film of different color and/or visual texture from that of the first colored base coating composition, and having, 30 seconds after application, 30 to 60 mass % of the solids content of the base coating composition, and (3) applying a top clear coating composition over the cured or uncured first and second colored base coating compositions, and curing the uncured composition(s).
摘要翻译： 本发明提供了形成多层图案化涂膜的方法，包括以下步骤：（1）将第一着色底涂层组合物施加到基底上，（2）将第二着色底涂层组合物涂覆在第一着色 所述第一着色基底涂膜部分地露出，所述第二着色底涂层组合物能够形成与所述第一着色底涂层组合物不同颜色和/或视觉质地的涂膜，以及 在涂布后30秒，30〜60质量％的基础涂料组合物的固体成分，和（3）在固化或未固化的第一和第二着色底涂层组合物上施加顶部透明涂料组合物，并固化未固化组合物 （s）。
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