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    Alkylation process
    1.
    发明授权
    Alkylation process 失效
    烷基化方法

    公开(公告)号：US4225737A

    公开(公告)日：1980-09-30

    申请号：US32613

    申请日：1979-04-23

    申请人： Michael Z. Mikulicz ,  James F. Himes

    发明人： Michael Z. Mikulicz ,  James F. Himes

    IPC分类号： C07C2/70 ,  C07C2/66

    CPC分类号： C07C2/70 ,  C07C2527/1206

    摘要： A process is disclosed for the alkylation of an aromatic hydrocarbon with an olefin-acting alkylating agent. The aromatic hydrocarbon is commingled with a first portion of said alkylating agent in a first alkylation reaction zone at alkylation reaction conditions in contact with a hydrofluoric acid catalyst. The acid phase of the effluent from the first alkylation reaction zone is separated, and the hydrocarbon phase, comprising alkylate and unreacted aromatic hydrocarbon is commingled with a second portion of said alkylating agent at alkylation reaction conditions in a second alkylation reaction zone in contact with a hydrofluoric acid catalyst separately charged thereto, the hydrofluoric acid catalyst being that separated from the effluent of the first alkylation reaction zone. The acid phase is separated from the effluent from the second alkylation reaction zone and recycled to the first alkylation reaction zone, and the alkylate product is recovered from the hydrocarbon phase.

    摘要翻译： 公开了用烯烃作用烷基化剂烷基化芳族烃的方法。 在与氢氟酸催化剂接触的烷基化反应条件下，芳烃与第一烷基化剂的第一部分在第一烷基化反应区中混合。 分离出来自第一烷基化反应区的流出物的酸相，包括烷基化物和未反应的芳烃的烃相与烷基化试剂的第二部分在烷基化反应条件下与第二烷基化反应区接触的烷基化反应区 氢氟酸催化剂分开加入，氢氟酸催化剂与第一烷基化反应区的流出物分离。 将酸相与来自第二烷基化反应区的流出物分离并再循环至第一烷基化反应区，并从烃相中回收烷基化产物。

    Plural stages of hydrofluoric acid alkylation utilizing separated acid phase as catalyst in the subsequent stage
    2.
    发明授权
    Plural stages of hydrofluoric acid alkylation utilizing separated acid phase as catalyst in the subsequent stage 失效
    在后续阶段利用分离的酸相作为催化剂的多级氢氟酸烷基化

    公开(公告)号：US4220806A

    公开(公告)日：1980-09-02

    申请号：US32611

    申请日：1979-04-23

    申请人： Michael Z. Mikulicz ,  James F. Himes

    发明人： Michael Z. Mikulicz ,  James F. Himes

    IPC分类号： C07C2/62 ,  C07C3/54

    CPC分类号： C07C2/62 ,  C07C2527/1206

    摘要： A process is disclosed for the alkylation of an isoparaffinic hydrocarbon with an olefin-acting alkylating agent. The isoparaffinic hydrocarbon is commingled with a first portion of said alkylating agent in a first alkylation reaction zone at alkylation reaction conditions in contact with a hydrofluoric acid catalyst. The acid phase of the effluent from the first alkylation reaction zone is separated, and the hydrocarbon phase, comprising alkylate and unreacted isoparaffin, is commingled with a second portion of said alkylating agent at alkylation reaction conditions in a second alkylation reaction zone in contact with a hydrofluoric acid catalyst separately charged thereto, the hydrofluoric acid catalyst being that separated from the effluent of the first alkylation reaction zone. The acid phase is separated from the effluent from the second alkylation reaction zone and recycled to the first alkylation reaction zone, and the alkylate product is recovered from the hydrocarbon phase.

    摘要翻译： 公开了用烯烃作用烷基化剂烷基化异链烷烃的方法。 在与氢氟酸催化剂接触的烷基化反应条件下，在第一烷基化反应区中将异链烷烃与第一部分所述烷基化剂混合。 分离来自第一烷基化反应区的流出物的酸相，并且包含烷基化物和未反应的异链烷烃的烃相与烷基化剂的第二部分在烷基化反应条件下与第二烷基化反应区接触的烷基化反应区 氢氟酸催化剂分开加入，氢氟酸催化剂与第一烷基化反应区的流出物分离。 将酸相与来自第二烷基化反应区的流出物分离并再循环至第一烷基化反应区，并从烃相中回收烷基化产物。

    HF regeneration in aromatic hydrocarbon alkylation process
    5.
    发明授权
    HF regeneration in aromatic hydrocarbon alkylation process 失效
    芳香烃烷基化过程中的HF再生

    公开(公告)号：US4503277A

    公开(公告)日：1985-03-05

    申请号：US556755

    申请日：1983-11-30

    申请人： James F. Himes

    发明人： James F. Himes

    IPC分类号： B01J27/00 ,  B01J27/12 ,  B01J27/32 ,  C07B61/00 ,  C07C1/00 ,  C07C2/70 ,  C07C15/107 ,  C07C67/00 ,  C07C2/64

    CPC分类号： B01J27/32 ,  C07C2/70 ,  C07C2527/1206 ,  Y02P20/584

    摘要： A process is disclosed for the production of alkylaromatic hydrocarbons by the HF-catalyzed reaction of an aromatic hydrocarbon with a C.sub.8 -plus acyclic olefin. The production of linear alkylbenzenes is preferred. The HF is regenerated in a regeneration column in which high boiling compounds are removed from the HF fed to the column. The main stream of HF enters an upper intermediate point in the regeneration column. A second portion of the HF is fed to the top of the regeneration column as reflux. This second portion of HF is withdrawn from the reaction zone rather than from the overhead receiver of the HF regeneration column as in the prior art regeneration method.

    摘要翻译： 公开了通过芳族烃与C 8加无环烯烃的HF催化反应生产烷基芳族烃的方法。 直链烷基苯的制备是优选的。 在再生塔中再生HF，其中高沸点化合物从供给塔的HF除去。 HF的主流进入再生塔的上部中间点。 HF的第二部分作为回流进料到再生塔的顶部。 如现有技术的再生方法那样，HF的第二部分从反应区而不是从HF再生塔的塔顶接收器排出。