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    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process
    5.
    发明授权
    Activator solid support for metallocene catalysts in the polymerization of olefins, a process for preparing such a support, and the corresponding catalytic system and polymerization process 有权
    在烯烃聚合中的茂金属催化剂的活化剂固体载体，制备这种载体的方法以及相应的催化体系和聚合方法

    公开(公告)号：US06605561B1

    公开(公告)日：2003-08-12

    申请号：US09822840

    申请日：2001-04-02

    Applicant: Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    Inventor： Thierry Saudemont ,  Roger Spitz ,  Jean-Pierre Broyer ,  Jean Malinge ,  Nathalie Verdel

    IPC: B01J3116

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65922 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F4/025 ,  C08F4/65916

    Abstract: Activator solid support for metallocenes as catalysts in the polymerization of olefins, characterized in that it consists of a group of support particles for a solid catalytic component, which are formed from at least one porous mineral oxide, the said particles having been modified in order to carry, on the surface, aluminium and/or magnesium Lewis-acid sites of formula: or —Mg—F, the groups coming from a functionalization agent having reacted with —OH radicals carried by the base particles of the support, the functionalization reaction having been followed by a fluorination reaction. The catalytic system according to the invention comprises (a) a metallocene catalyst, which has, if required, been subjected to a prealkylation treatment; (b) a cocatalyst; and (c) an activator solid support for metallocene, as defined above, it being possible for the cocatalyst (b) to be absent if the metallocene catalyst (a) has been prealkylated.

    Abstract translation: 在烯烃聚合中作为催化剂的金属茂的活化剂固体支持物，其特征在于它由一组由至少一种多孔矿物氧化物形成的固体催化组分的载体颗粒组成，所述颗粒已被修饰以便 在表面上携带式：或-Mg-F的铝和/或镁路易斯酸位点，来自与由载体的基础颗粒携带的-OH自由基反应的官能化试剂的基团，官能化反应已经 随后进行氟化反应。 根据本发明的催化体系包括（a）茂金属催化剂，如果需要，其进行预烷基化处理; （b）助催化剂; 如上所述，如果茂金属催化剂（a）已经被烷基化，则助催化剂（b）可能不存在，而且（c）金属茂的活化剂固体载体。

    Synthesis and application of vapor grafted porous materials
    10.
    发明授权
    Synthesis and application of vapor grafted porous materials 失效
    蒸气接枝多孔材料的合成与应用

    公开(公告)号：US06489258B1

    公开(公告)日：2002-12-03

    申请号：US09419365

    申请日：1999-10-15

    Applicant: Jackie Y. Ying ,  Christian P. Mehnert

    Inventor： Jackie Y. Ying ,  Christian P. Mehnert

    IPC: B01J3116

    CPC classification number: B01J29/0341 ,  B01J29/0308 ,  B01J29/0316 ,  B01J29/0325 ,  B01J29/0333 ,  B01J29/041 ,  B01J35/0053 ,  B01J35/006 ,  B01J37/0238 ,  B01J2229/18 ,  B01J2229/32 ,  B01J2229/34 ,  C07B37/04 ,  Y02P20/588

    Abstract: This invention provides an article, compositions, methods of making and uses of vapor-deposited metal compounds immobilized on porous substrates. The substrate is a porous substrate having an average pore size of at least about 8 Å and a surface area of at least about 10 m2/g. The methods describe the vapor-deposition of an inorganic compound onto the substrate where the deposition is accomplished with a relatively small amount of ligand loss. The substrate can be pre-treated to achieve a uniformly dispersed metal compound deposited on the substrate. The inorganic compound can decompose into a metal compound. The article can also function as a catalyst for carbon-heteroatom coupling reactions such as carbon-carbon coupling reactions, most notably, the Heck reaction.

    Abstract translation: 本发明提供一种制备和使用固定在多孔基材上的气相沉积金属化合物的制品，组合物，方法。 基材是平均孔径至少约为8，表面积至少约10m 2 / g的多孔基材。 该方法描述了无机化合物在基底上的蒸镀，其中以相对少量的配体损失完成沉积。 可以对基底进行预处理，以实现沉积在基底上的均匀分散的金属化合物。 无机化合物可分解成金属化合物。 该文章还可以用作碳 - 杂原子偶联反应的催化剂，如碳 - 碳偶联反应，最着名的是Heck反应。

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