Recharge catalyst with thin film low corrosion coating, metal-air
electrode including said catalyst and methods for making said catalyst
and electrode
    2.
    发明授权
    Recharge catalyst with thin film low corrosion coating, metal-air electrode including said catalyst and methods for making said catalyst and electrode 失效
    具有薄膜低腐蚀涂层的充电催化剂,包括所述催化剂的金属空气电极和制备所述催化剂和电极的方法

    公开(公告)号:US6127060A

    公开(公告)日:2000-10-03

    申请号:US98786

    申请日:1998-06-17

    申请人: Jeffrey A. Read

    发明人: Jeffrey A. Read

    IPC分类号: H01M4/86 H01M4/90 H01M12/08

    摘要: A catalyst composition for use in a rechargeable metal-air electrochemical cell comprises an oxygen evolution catalyst coated with a thin film deposition of a binder and an electrically conductive particulate material which is not corroded during charge. This catalyst is useful to make an air electrode which has greater corrosion protection than an air electrode having an oxygen evolution catalyst without the thin film deposition.

    摘要翻译: 用于可充电金属 - 空气电化学电池的催化剂组合物包括涂覆有粘合剂的薄膜沉积物和在电荷期间不被腐蚀的导电颗粒材料的析氧催化剂。 该催化剂可用于制造具有比没有薄膜沉积的具有析氧催化剂的空气电极具有更大腐蚀保护性的空气电极。

    Electrolyte for metal-oxygen battery and method for its preparation
    3.
    发明授权
    Electrolyte for metal-oxygen battery and method for its preparation 有权
    金属氧电池用电解液及其制备方法

    公开(公告)号:US07585579B1

    公开(公告)日:2009-09-08

    申请号:US10628424

    申请日:2003-07-29

    申请人: Jeffrey A. Read

    发明人: Jeffrey A. Read

    IPC分类号: H01M4/00

    CPC分类号: H01M12/06

    摘要: An electrolyte for a metal-oxygen battery includes a non-aqueous solvent which is characterized in that the solubility of oxygen therein is at least 0.1150 cc O2/cc of solvent at STP. The electrolyte also includes an electrolyte salt dissolved in the solvent. The solvent may comprise a mixture of materials in which at least 50%, on a weight basis, of the materials have an oxygen solubility of at least 0.1760 cc O2/cc at STP. Also disclosed is a method for optimizing the composition of an electrolyte for a metal-oxygen battery by selecting the solvent for the electrolyte from those materials which will dissolve the electrolyte salt and which have a solubility for oxygen which is at least 0.1150 cc O2/cc at STP.

    摘要翻译: 用于金属 - 氧电池的电解质包括非水溶剂,其特征在于其中的氧的溶解度在STP下至少为0.1150cc O 2 / cc溶剂。 电解质还包括溶解在溶剂中的电解质盐。 溶剂可以包括材料的混合物,其中至少50%的材料在STP下具有至少0.1760cc O2 / cc的氧溶解度。 还公开了一种用于优化金属 - 氧气电池的电解质的组成的方法,该方法是从那些将溶解电解质盐并且具有至少为0.1150cc O2 / cc的氧的溶解度的那些材料中选择用于电解质的溶剂 在STP。

    Cathode for metal-oxygen battery
    4.
    发明授权
    Cathode for metal-oxygen battery 失效
    金属氧气阴极

    公开(公告)号:US07147967B1

    公开(公告)日:2006-12-12

    申请号:US10628435

    申请日:2003-07-29

    申请人: Jeffrey A. Read

    发明人: Jeffrey A. Read

    摘要: Disclosed is a cathode material for a metal-oxygen battery such as a lithium-oxygen battery. The material comprises, on a weight basis, a first component which is an oxide or a sulfide of a metal. The first component is capable of intercalating lithium, and is present in an amount which is greater than 20% and up to 80% of the material. The material includes a second component which comprises carbon. The carbon is an electroactive catalyst which is capable of reducing oxygen, and comprises 10–80% of the material. The material further includes a binder, such as a fluoropolymer binder, which is present in an amount of 5–40%. Also disclosed is a battery which incorporates the cathode material.

    摘要翻译: 公开了一种用于诸如锂 - 氧电池的金属 - 氧电池的阴极材料。 该材料以重量计包含作为金属的氧化物或硫化物的第一成分。 第一组分能够插入锂,并且以大于材料的20%和高达80%的量存在。 该材料包括包含碳的第二组分。 碳是能够还原氧的电活性催化剂,并且包含10-80%的材料。 该材料还包括以5-40%的量存在的粘合剂,例如氟聚合物粘合剂。 还公开了并入阴极材料的电池。

    Mechanochemical Synthesis of Carbon Fluorides and an Electrochemical Cell using the Synthesized Carbon Fluorides
    6.
    发明申请
    Mechanochemical Synthesis of Carbon Fluorides and an Electrochemical Cell using the Synthesized Carbon Fluorides 审中-公开
    使用合成碳氟化合物的碳氟化合物和电化学电池的机械化学合成

    公开(公告)号:US20110091370A1

    公开(公告)日:2011-04-21

    申请号:US12877153

    申请日:2010-09-08

    IPC分类号: C01B31/00

    CPC分类号: C01B32/00

    摘要: Carbon fluoride is synthesized by reactively or high intensity/energy milling at ambient room temperature carbon-containing material (such as graphite, carbon black, coke, or other carbon-based material) with an inorganic fluoride agent (such as cobalt trifluoride) other than fluorine gas. The following chemical reaction occurs: xC+CoF3→CxF+CoF2, wherein x equals 1 to 4. The CxF is separated from the CoF2 and the CoF3 by digesting the CxF, CoF2 and the CoF3 in hot water of at least approximately 90° C. causing the CoF2 to dissolve; and then filtering the CoF2. The CoF3 is unreacted and undergoes hydrolysis in the hot water to form Co(OH)3 or Co2O3.3H2O, which is removed by washing with sulfuric acid. Alternatively, the CxF is separated from the CoF2 and the CoF3 by digesting the CxF, CoF2 and the CoF3 in heated sulfuric acid followed by filtration and washing with sulfuric acid and then with hot water. The synthesized carbon fluoride is used to form a cathode in electrochemical cells, such as lithium batteries.

    摘要翻译: 碳氟化物通过在环境室温下含碳材料(如石墨,炭黑,焦炭或其他碳基材料)与无机氟化物(如三氟化铬)除以下进行反应或高强度/能量研磨来合成。 氟气。 发生以下化学反应:xC + CoF3→CxF + CoF2,其中x等于1至4.通过在至少约90℃的热水中消化CxF,CoF 2和CoF 3从CoF 2和CoF 3中分离CxF 使CoF2溶解; 然后过滤CoF2。 CoF 3是未反应的,并在热水中进行水解,形成Co(OH)3或Co2O3.3H2O,通过用硫酸洗涤除去。 或者,通过在加热的硫酸中消化CxF,CoF 2和CoF 3然后过滤并用硫酸洗涤,然后用热水将CxF与CoF 2和CoF 3分离。 合成的碳氟化物用于在诸如锂电池的电化学电池中形成阴极。