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公开(公告)号：US08961833B2
公开(公告)日：2015-02-24
申请号：US13206895
申请日：2011-08-10
CPC分类号： H01M4/5835 , H01M4/622 , H01M4/623 , H01M10/052 , Y02E60/122
摘要： A lithium/fluorinated carbon (Li/CFx) battery having a composite cathode including an electroactive cathode material, a non-electroactive additive, a conductive agent, and a binder. The electroactive cathode material is a single fluorinated carbon having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2. The non-electroactive additive is at least one or a mixture of two or more oxides selected from the group comprising Mg, B, Al, Si, Cu, Zn, Y, Ti, Zr, Fe, Co, or Ni. The conductive agent is selected from the group comprising carbon, metals, and mixtures thereof. Finally, the binder is an amorphous polymer selected from the group comprising fluorinated polymers, ethylene-propylene-diene (EPDM) rubbers, styrene butadiene rubbers (SBR), poly (acrylonitrile-methyl methacrylate), carboxymethyl celluloses (CMC), and polyvinyl alcohol (PVA). Also, a method of reducing the initial voltage drop of a lithium/fluorinated carbon (Li/CFx) battery by providing a composite cathode which includes an electroactive cathode material having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2, a non-electroactive additive, a conductive agent, and a binder.
摘要翻译： 具有包含电活性阴极材料，非电活性添加剂，导电剂和粘合剂的复合阴极的锂/氟化碳（Li / CF x）电池。 电活性阴极材料是具有通式CF x的单一氟化碳，其中x是约0.5至约1.2的平均值。 非电活性添加剂是选自Mg，B，Al，Si，Cu，Zn，Y，Ti，Zr，Fe，Co或Ni中的至少一种或两种以上的氧化物的混合物。 导电剂选自碳，金属及其混合物。 最后，粘合剂是选自含氟聚合物，乙烯 - 丙烯 - 二烯（EPDM）橡胶，苯乙烯丁二烯橡胶（SBR），聚（丙烯腈 - 甲基丙烯酸甲酯），羧甲基纤维素（CMC））和聚乙烯醇 （PVA）。 另外，通过提供具有通式CF x的电活性阴极材料的复合阴极来降低锂/氟化碳（Li / CF x）电池的初始电压降的方法，其中x是约0.5的平均值 至约1.2，非电活性添加剂，导电剂和粘合剂。
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2.发明授权公开(公告)号：US06316143B1
公开(公告)日：2001-11-13
申请号：US09469781
申请日：1999-12-22
IPC分类号： H01M458
CPC分类号： H01M4/13 , H01M4/58 , H01M2004/027 , Y10T29/49115
摘要： An electrode for a rechargeable lithium-ion battery is formed by mixing stanous oxide (SnO) and lithium nitride (Li3N) in a stoichiometric ratio of 2 moles of Li3N to 3 moles of SnO to form a mixture, milling the mixture to obtain a milled powder, and processing the milled powder in accordance with an electrode-forming technique. The electrode forming technique can be any one of die pressing, spraying, doctor-blading and rolling. Conductive additives, such as carbon and binders (PVDF, cellulose and Teflon), can be introduced during the processing step. Preferably, the method is carried out in a dry, inert atmosphere of argon or helium. As a result of the invention, a smaller, lighter and more efficient lithium-ion battery is produced.
摘要翻译： 通过将化学计量比为2摩尔Li 3 N至3摩尔SnO的氧化亚锡（SnO）和氮化锂（Li 3 N）混合以形成混合物形成可再充电锂离子电池用电极，研磨混合物以获得研磨 粉末，并根据电极形成技术处理研磨的粉末。 电极形成技术可以是压模，喷涂，刮刀和轧制中的任何一种。 可以在加工步骤中引入导电添加剂，例如碳和粘合剂（PVDF，纤维素和特氟隆）。 优选地，该方法在干燥的惰性气氛氩气或氦气中进行。 作为本发明的结果，生产了更小，更轻和更有效的锂离子电池。
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公开(公告)号：US4670363A
公开(公告)日：1987-06-02
申请号：US910694
申请日：1986-09-22
IPC分类号： H01M6/16 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M10/36 , H01M6/14
CPC分类号： H01M10/0569 , H01M10/052 , H01M10/0567 , H01M6/164 , H01M6/168
摘要： An improved nonaqueous electrolyte and electrochemical cell containing same, wherein the electrolyte is comprised of a salt complexed by a tertiary amine and an aromatic organic solvent, the improvement being the addition of a solvent having a dielectric constant greater than 20 which provides an electrolyte having a conductivity sufficient to support current densities greater than 1 mA/cm.sub.2.
摘要翻译： 一种改进的非水电解质和包含其的电化学电池，其中电解质由与叔胺和芳族有机溶剂络合的盐组成，改进之处在于加入介电常数大于20的溶剂，其提供电解质，其具有 电导率足以支持大于1mA / cm2的电流密度。
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4.发明授权
公开(公告)号：US4812375A
公开(公告)日：1989-03-14
申请号：US213031
申请日：1988-06-27
申请人： Donald L. Foster
发明人： Donald L. Foster
CPC分类号： H01M2/1686 , H01M10/4235 , H01M2/16 , H01M2/1653 , H01M2300/002 , H01M2300/0025
摘要： A multilayer separator is provided for insertion between the cathode and de in lithium secondary or primary batteries, the separator including porous membrane and an electroactive polymeric material contained within the separator layers wherein the polymer is one that will react with any lithium dendrite that could penetrate the separator thus preventing an internal short circuit of the cell.
摘要翻译： 提供了一种用于在锂二次电池或一次电池中插入阴极和阳极之间的多层隔板，分离器包括多孔膜和包含在隔板层内的电活性聚合物材料，其中聚合物是能与任何锂枝晶反应的聚合材料， 分离器，从而防止电池的内部短路。
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公开(公告)号：US20130137001A1
公开(公告)日：2013-05-30
申请号：US13304784
申请日：2011-11-28
IPC分类号： H01M10/056 , H01M8/22
摘要： A lithium/oxygen battery includes a lithium anode, an air cathode, and a non-aqueous electrolyte soaked in a microporous separator membrane, wherein non-aqueous electrolyte comprises a lithium salt with a general molecular formula of LiBF3X (X═F, Cl, or Br, respectively) and a non-aqueous solvent mixture.
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6.发明申请公开(公告)号：US20120088164A1
公开(公告)日：2012-04-12
申请号：US13253142
申请日：2011-10-05
IPC分类号： H01M12/06
摘要： A lithium carbon monofluoride-oxygen battery is provided that includes a lithium metal-containing electroactive anode; an electroactive cathode formed of a carbon monofluoride compound; an electrolyte solution formed of an organic solvent and a lithium salt; a casing surrounding the anode, the cathode, and the electrolyte solution; and a port bored through the casing wherein the port selectively allows the flow of gas into the casing. In addition, a method of using an electrochemical battery is provided that includes providing a lithium carbon monofluoride-oxygen battery; closing the valve of the electrochemical battery to block the flow of gas into the battery; discharging the electrochemical battery after closing the valve of the battery; opening the valve of the electrochemical battery after discharging the electrochemical battery to expose the cathode to the flow of oxygen containing gas; and discharging the electrochemical battery after opening the valve of the electrochemical battery.
摘要翻译： 提供了一种含有锂金属的电活性阳极的单氟碳酸锂电池， 由单氟化碳化合物形成的电活性阴极; 由有机溶剂和锂盐形成的电解液; 围绕阳极，阴极和电解质溶液的壳体; 以及通过所述壳体钻孔的端口，其中所述端口选择性地允许气体流入所述壳体。 此外，提供一种使用电化学电池的方法，其包括提供锂一氟一氧化碳电池; 关闭电化学电池的阀门以阻止气体进入电池; 关闭电池阀门后，放电电池; 在放电电化学电池之后打开电化学电池的阀门，将阴极暴露于含氧气体流中; 并在打开电化学电池的阀之后排出电化学电池。
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公开(公告)号：USH1076H
公开(公告)日：1992-07-07
申请号：US625181
申请日：1990-12-10
申请人： Steven M. Slane , Donald L. Foster
发明人： Steven M. Slane , Donald L. Foster
IPC分类号： H01M4/52 , H01M4/525 , H01M4/58 , H01M4/587 , H01M10/0525 , H01M10/0569 , H01M10/36
CPC分类号： H01M4/525 , H01M4/587 , H01M10/0525 , H01M10/0569
摘要： A lithium ion rechargeable intercallation cell is provided including a liated graphite anode, a lithiated oxide cathode, and a solution of a lithium salt in a solvent that cycles both the lithiated graphite anode and the lithiated oxide cathode as the electrolyte.
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公开(公告)号：US4513067A
公开(公告)日：1985-04-23
申请号：US509691
申请日：1983-06-30
CPC分类号： H01M10/0563 , H01M4/661 , H01M4/663 , H01M4/96 , H01M6/14
摘要： A novel inorganic non-aqueous electrochemical cell having an alkali or alkaline earth metal anode, an inorganic electrolyte comprised of an SO.sub.2 solvent with an alkali or alkaline earth metal halide salt of aluminum, tantalum niobium or antimony, dissolved in the SO.sub.2 and a cathode comprised of a carbonaceous material having an apparent bulk density in excess of 5 lb/ft.sup.3 (80 gm/l). Lower bulk density carbonaceous material may, however, be used in electrolytes having high salt concentrations. Ketjenblack EC (furnace black) carbonaceous material may be admixed with a solid cathode active material which is substantially insoluble in the SO.sub.2 electrolyte to provide a high primary cell capacity and an effectively rechargeable cell. There is no SO.sub.2 per se discharge in the cell.
摘要翻译： 一种具有碱金属或碱土金属阳极的新型无机非水电化学电池，由SO 2溶剂与溶解在SO 2中的铝，钽铌或锑的碱金属或碱土金属卤化物盐组成的无机电解质和阴极， 的表观堆积密度超过5lb / ft 3（80gm / l）的碳质材料。 然而，较低堆积密度的碳质材料可用于具有高盐浓度的电解质中。 可以将Ketjenblack EC（炉黑）碳质材料与基本上不溶于SO 2电解质的固体正极活性材料混合以提供高的初级电池容量和有效的可充电电池。 电池中没有SO2本身放电。
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公开(公告)号：US20120126182A1
公开(公告)日：2012-05-24
申请号：US13206895
申请日：2011-08-10
CPC分类号： H01M4/5835 , H01M4/622 , H01M4/623 , H01M10/052 , Y02E60/122
摘要： A lithium/fluorinated carbon (Li/CFx) battery having a composite cathode including an electroactive cathode material, a non-electroactive additive, a conductive agent, and a binder. The electroactive cathode material is a single fluorinated carbon having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2. The non-electroactive additive is at least one or a mixture of two or more oxides selected from the group comprising Mg, B, Al, Si, Cu, Zn, Y, Ti, Zr, Fe, Co, or Ni. The conductive agent is selected from the group comprising carbon, metals, and mixtures thereof. Finally, the binder is an amorphous polymer selected from the group comprising fluorinated polymers, ethylene-propylene-diene (EPDM) rubbers, styrene butadiene rubbers (SBR), poly (acrylonitrile-methyl methacrylate), carboxymethyl celluloses (CMC), and polyvinyl alcohol (PVA). Also, a method of reducing the initial voltage drop of a lithium/fluorinated carbon (Li/CFx) battery by providing a composite cathode which includes an electroactive cathode material having a general formula of CFx, whereby x is an averaged value ranging from about 0.5 to about 1.2, a non-electroactive additive, a conductive agent, and a binder.
摘要翻译： 具有包含电活性阴极材料，非电活性添加剂，导电剂和粘合剂的复合阴极的锂/氟化碳（Li / CF x）电池。 电活性阴极材料是具有通式CF x的单一氟化碳，其中x是约0.5至约1.2的平均值。 非电活性添加剂是选自Mg，B，Al，Si，Cu，Zn，Y，Ti，Zr，Fe，Co或Ni中的至少一种或两种以上的氧化物的混合物。 导电剂选自碳，金属及其混合物。 最后，粘合剂是选自含氟聚合物，乙烯 - 丙烯 - 二烯（EPDM）橡胶，苯乙烯丁二烯橡胶（SBR），聚（丙烯腈 - 甲基丙烯酸甲酯），羧甲基纤维素（CMC））和聚乙烯醇 （PVA）。 另外，通过提供具有通式CF x的电活性阴极材料的复合阴极来降低锂/氟化碳（Li / CF x）电池的初始电压降的方法，其中x是约0.5的平均值 至约1.2，非电活性添加剂，导电剂和粘合剂。
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公开(公告)号：US09653729B2
公开(公告)日：2017-05-16
申请号：US13253142
申请日：2011-10-05
摘要： A lithium carbon monofluoride-oxygen battery is provided that includes a lithium metal-containing electroactive anode; an electroactive cathode formed of a carbon monofluoride compound; an electrolyte solution formed of an organic solvent and a lithium salt; a casing surrounding the anode, the cathode, and the electrolyte solution; and a port bored through the casing wherein the port selectively allows the flow of gas into the casing. In addition, a method of using an electrochemical battery is provided that includes providing a lithium carbon monofluoride-oxygen battery; closing the valve of the electrochemical battery to block the flow of gas into the battery; discharging the electrochemical battery after closing the valve of the battery; opening the valve of the electrochemical battery after discharging the electrochemical battery to expose the cathode to the flow of oxygen containing gas; and discharging the electrochemical battery after opening the valve of the electrochemical battery.
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