公开(公告)号：US5262014A

公开(公告)日：1993-11-16

申请号：US898771

申请日：1992-06-12

申请人： Jeremy B. Cooper ,  John Dixon-Hall ,  Stephen J. Smith

发明人： Jeremy B. Cooper ,  John Dixon-Hall ,  Stephen J. Smith

IPC分类号： C07C7/04 ,  C07C17/38 ,  C07C19/07 ,  C07C45/80 ,  C07C45/83 ,  C07C49/08 ,  C07C51/573 ,  C07C67/54 ,  C07C69/14 ,  B01D3/34

CPC分类号： C07C51/573 ,  C07C17/38 ,  C07C17/383 ,  C07C45/80 ,  C07C45/83 ,  C07C67/54 ,  Y10S203/20 ,  Y10S203/22

摘要： A process for removing acetone from an acetone/methyl acetate/methyl iodide mixture utilizing extractive distillation with water being introduced to the distillation zone above the point of introduction of the mixture and acetic acid being introduced at or above the point of introduction of the mixture. In a preferred embodiment the mixture is subjected to an initial extraction with an aqueous extractant to remove most of the methyl iodide.The process is particularly applicable to removing acetone by-product in carbonylation processes for the production of acetic anhydride.

公开(公告)号：US5362850A

公开(公告)日：1994-11-08

申请号：US119204

申请日：1993-09-22

申请人： Jeremy B. Cooper ,  Andrew R. Lucy ,  Kevin G. Smith

发明人： Jeremy B. Cooper ,  Andrew R. Lucy ,  Kevin G. Smith

IPC分类号： C08G67/00 ,  C08G67/02

CPC分类号： C08G67/02

摘要： A process is disclosed for removing palladium from a contaminated polyketone containing palladium which comprises contacting the contaminated polyketone with an olefin in the substantial absence of carbon monoxide at a temperature above the temperature at which the polyketone was formed and in a solvent in which the contaminated polyketone is insoluble. The process is preferably carried out in the presence of an acid. The temperature at which the process is carried out is preferably at least 20.degree. C. greater than the polymerization temperature.

摘要翻译： PCT No.PCT / GB93 / 00366 Sec。 371日期：1993年9月22日 102（e）1993年9月22日PCT 1993年2月22日PCT公布。 公开号WO93 / 17061 日本公报1993年9月2日公开了一种从含有污染的含钯的钯中除去钯的方法，其中包括在高于形成聚酮的温度的温度下，将污染的聚酮与基本上不存在一氧化碳的烯烃接触， 其中污染的聚酮不溶解的溶剂。 该方法优选在酸存在下进行。 进行该方法的温度优选比聚合温度高至少20℃。

公开(公告)号：US5545787A

公开(公告)日：1996-08-13

申请号：US252051

申请日：1994-05-31

申请人： Jeremy B. Cooper ,  Jonathon C. Frost ,  Stephen R. Partington

发明人： Jeremy B. Cooper ,  Jonathon C. Frost ,  Stephen R. Partington

IPC分类号： B01J23/66 ,  B01J23/96 ,  B01J37/03 ,  C07B61/00 ,  C07C1/24 ,  C07C5/32 ,  C07C5/333 ,  C07C5/42 ,  C07C11/02 ,  C07C11/04 ,  C07C45/00

CPC分类号： C07C45/002 ,  B01J23/66 ,  B01J23/96 ,  C07C5/324 ,  C07C5/3335 ,  C07C5/42 ,  B01J37/03 ,  C07C2523/10 ,  C07C2523/52 ,  C07C2523/66 ,  Y02P20/52 ,  Y02P20/584

摘要： A continuous process for the dehydrogenation of a hydrocarbon and/or oxygenated hydrocarbon feed, comprising contacting the hydrocarbon and/or oxygenated hydrocarbon feed with a dehydrogenation catalyst at elevated temperature in a reaction zone characterized in that the catalyst is capable of retaining hydrogen and (a) is contacted with a feed to form a dehydrogenated product and hydrogen, at least some of the hydrogen formed being adsorbed by the catalyst and/or reacting therewith to reduce at least part of the catalyst; (b) the dehydrogenated product and any unadsorbed/unreacted hydrogen is removed from the reaction zone; (c) at least some of the adsorbed hydrogen is removed from the catalyst and/or at least some of the reduced catalyst is oxidized; and (d) reusing the catalyst from step (c) in step (a).

摘要翻译： 一种用于烃和/或含氧烃进料脱氢的连续方法，包括使烃和/或含氧烃进料与脱氢催化剂在升高的温度下在反应区中接触，其特征在于催化剂能够保持氢和（a ）与进料接触以形成脱氢产物和氢，形成的至少一些形成的氢被催化剂吸附和/或与其反应以减少至少部分催化剂; （b）脱氢产物和任何未吸附的/未反应的氢从反应区除去; （c）从催化剂中除去至少一些吸附的氢气，和/或至少一些还原的催化剂被氧化; 和（d）在步骤（a）中重新使用来自步骤（c）的催化剂。

公开(公告)号：US5416237A

公开(公告)日：1995-05-16

申请号：US276873

申请日：1994-07-18

申请人： Simon D. Aubigne ,  Jeremy B. Cooper ,  Bruce L. Williams ,  Derrick J. Watson

发明人： Simon D. Aubigne ,  Jeremy B. Cooper ,  Bruce L. Williams ,  Derrick J. Watson

IPC分类号： C07B61/00 ,  B01D3/06 ,  B01J39/04 ,  C07C51/12 ,  C07C51/44 ,  C07C53/08

CPC分类号： C07C51/12 ,  C07C51/44

摘要： In a process for the production of acetic acid by carbonylation of methanol in the presence of a rhodium carbonylation catalyst, methyl iodide and an iodide salt stabiliser the improvement resides in maintaining a finite concentration of water of up to about 10% by weight and a methyl acetate concentration of at least 2% by weight in the liquid reaction composition and recovering the acetic acid product by passing the liquid reaction composition through a flash zone to produce a vapour fraction which is passed to a single distillation column from which an acetic acid product is removed.

摘要翻译： 在甲酸铑羰化反应催化剂存在下通过羰基化生产乙酸的方法中，甲基碘和碘化物盐稳定剂的改进在于维持高达约10重量％的有限浓度的水和甲基 乙酸盐浓度在液体反应组合物中至少为2重量％，并通过使液体反应组合物通过闪蒸区域回收乙酸产物，以产生蒸气馏分，该蒸气馏分通过乙酸产物为单一蒸馏塔 删除。

公开(公告)号：US5227520A

公开(公告)日：1993-07-13

申请号：US945720

申请日：1992-09-16

申请人： Jeremy B. Cooper

发明人： Jeremy B. Cooper

IPC分类号： B01J31/20 ,  B01D3/06 ,  C07B61/00 ,  C07C51/12 ,  C07C51/14 ,  C07C51/42 ,  C07C51/44 ,  C07C51/573 ,  C07C53/08 ,  C07C53/12 ,  C07C53/122 ,  C07C53/124

CPC分类号： C07C51/573 ,  C07C51/44

摘要： A process for purifying an iodide-contaminated carboxylic acid and/or anhydride fraction obtained by liquid phase carbonylation using a carbonylation catalyst, an iodine-containing promoter and optional iodine-containing copromoter comprises vaporizing the fraction after it has been freed of catalyst, feedstock and promoter components to produce a vapor acid and/or anhydride fraction having reduced iodide contamination.