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1.发明授权公开(公告)号：US08334021B2
公开(公告)日：2012-12-18
申请号：US12228348
申请日：2008-08-12
CPC分类号： C14C11/003 , B05D3/107 , B05D7/12
摘要： The present invention provides methods for reducing the level of free aldehydes in coatings for flexible substrates, such as tanned leather, and substantially aldehyde free substrates. The methods comprise applying to the substrate a composition of one or more aqueous emulsion or suspension composition of an acrylic polymer or silicon containing polymer that is made from, or contains one or more lower alkyl alcohol or degrades on storage or in use to form such an alcohol, and one or more water-insoluble to slightly water soluble aldehyde scavenger compound, followed by drying or curing the applied composition to form a coating. In addition, the methods provide enhanced aldehyde scrubbing, especially for acetaldehyde, by applying to a substrate an aqueous acrylic polymer or silicon containing polymer emulsion or suspension comprising a aldehyde scavenger compound that is substantially deprotonated, i.e. by raising the pH composition to 5.5 or higher. The present invention also provides treated and coated substrates made by the inventive methods.
摘要翻译： 本发明提供了用于降低柔性基材例如鞣革和基本上无醛底物的涂料中游离醛水平的方法。 所述方法包括向基材施用一种或多种丙烯酸聚合物或含硅聚合物的水性乳液或悬浮液组合物的组合物，所述聚合物由含有一种或多种低级烷基醇或含有一种或多种低级烷基醇或在存储或使用中形成这样的 醇和一种或多种水不溶性至微水溶性醛清除剂化合物，然后干燥或固化所施加的组合物以形成涂层。 此外，该方法通过向基材施加含水丙烯酸聚合物或含硅聚合物乳液或包含基本上去质子化的醛清除剂化合物的悬浮液，即通过将pH组合物提高至5.5或更高而提供增强的醛洗涤，特别是乙醛。 。 本发明还提供了通过本发明方法制备的经处理和涂覆的基材。
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公开(公告)号：US09212402B2
公开(公告)日：2015-12-15
申请号：US12584760
申请日：2009-09-11
IPC分类号： C14C11/00 , C08F220/06 , C08K5/31 , C09D133/08
CPC分类号： C14C11/003 , C08F220/06 , C08K5/31 , C09D133/08
摘要： The present invention provides aqueous flesh coating compositions comprising one or more aqueous acid-functional acrylic or vinyl copolymer and from 0.03 and up to 1.0 equivalent, based on equivalents of carboxylic acid in the polymer, of one or more active compound chosen from an aminoguanidine, semicarbazide, dihydrazide, guanamine, hydrazine and a salt thereof. Further, the invention provides methods of applying the coating composition to leather crust or to tanned leather, and to the flesh coated leather or coated leather crust produced thereby. The leather crust and tanned leather produced by the invention, for example fleshcoated or finished leather, will emit greatly reduced levels of aldehydes over time and especially valuable in scrubbing aldehydes from perforated leather for automotive use.
摘要翻译： 本发明提供包含一种或多种酸性官能的丙烯酸或乙烯基共聚物水溶液的含水肉皮组合物，和基于聚合物中羧酸当量的0.03和至多1.0当量的一种或多种活性化合物，所述活性化合物选自氨基胍， 氨基脲，二酰肼，胍胺，肼及其盐。 此外，本发明提供了将涂料组合物施用于皮革皮革或鞣制的皮革以及由其制备的肉皮涂层皮革或涂覆的皮革外皮的方法。 由本发明生产的皮革外壳和鞣制皮革，例如肉皮或成品皮革，随着时间的推移，将大大降低醛的含量，特别是在从用于汽车用途的穿孔皮革洗涤醛时尤其有价值。
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3.发明申请公开(公告)号：US20100037399A1
公开(公告)日：2010-02-18
申请号：US12228348
申请日：2008-08-12
CPC分类号： C14C11/003 , B05D3/107 , B05D7/12
摘要： The present invention provides methods for reducing the level of free aldehydes in coatings for flexible substrates, such as tanned leather, and substantially aldehyde free substrates. The methods comprise applying to the substrate a composition of one or more aqueous emulsion or suspension composition of an acrylic polymer or silicon containing polymer that is made from, or contains one or more lower alkyl alcohol or degrades on storage or in use to form such an alcohol, and one or more water-insoluble to slightly water soluble aldehyde scavenger compound, followed by drying or curing the applied composition to form a coating. In addition, the methods provide enhanced aldehyde scrubbing, especially for acetaldehyde, by applying to a substrate an aqueous acrylic polymer or silicon containing polymer emulsion or suspension comprising a aldehyde scavenger compound that is substantially deprotonated, i.e. by raising the pH composition to 5.5 or higher. The present invention also provides treated and coated substrates made by the inventive methods.
摘要翻译： 本发明提供了用于降低柔性基材例如鞣革和基本上无醛底物的涂料中游离醛水平的方法。 所述方法包括向基材施用一种或多种丙烯酸聚合物或含硅聚合物的水性乳液或悬浮液组合物的组合物，所述聚合物由含有一种或多种低级烷基醇或含有一种或多种低级烷基醇或在存储或使用中形成这样的 醇和一种或多种水不溶性至微水溶性醛清除剂化合物，然后干燥或固化所施加的组合物以形成涂层。 此外，该方法通过向基材施加含水丙烯酸聚合物或含硅聚合物乳液或包含基本上去质子化的醛清除剂化合物的悬浮液，即通过将pH组合物提高至5.5或更高而提供增强的醛洗涤，特别是乙醛。 。 本发明还提供了通过本发明方法制备的经处理和涂覆的基材。
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公开(公告)号：US06433099B1
公开(公告)日：2002-08-13
申请号：US09628066
申请日：2000-07-28
IPC分类号： C08G5942
CPC分类号： C09D5/032 , C08G59/42 , C08G59/4238 , C08G59/686 , C09D133/068 , C09D163/00 , Y10S525/934 , C08L2666/36
摘要： Thermosetting powder coating composition adapted to provide a uniform, fine textured finish onto heat sensitive substrates, without damaging the substrate while curing the coating. The composition comprises a glycidyl methacrylate resin, 1,3,5-tris-(2-carboxyethyl)isocyanurate, a catalyst and, optionally, a second curing agent selected from the group consisting of difunctional and trifunctional carboxylic acids. The composition according to the present invention provides a fine texture finish without the need to add texturizing agents. The composition may be cured at temperatures below 300° F. so as to not damage the heat sensitive substrate.
摘要翻译： 热固性粉末涂料组合物适用于在热敏基材上提供均匀的精细纹理光洁度，而不会在固化涂层的同时损坏基材。 组合物包含甲基丙烯酸缩水甘油酯树脂，1,3,5-三（2-羧乙基）异氰脲酸酯，催化剂和任选的选自二官能和三官能羧酸的第二固化剂。 根据本发明的组合物提供精细的纹理整理，而不需要添加增稠剂。 组合物可以在低于300°F的温度下固化，以便不损坏热敏基材。
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公开(公告)号：US20100068541A1
公开(公告)日：2010-03-18
申请号：US12584760
申请日：2009-09-11
CPC分类号： C14C11/003 , C08F220/06 , C08K5/31 , C09D133/08
摘要： The present invention provides aqueous flesh coating compositions comprising one or more aqueous acid-functional acrylic or vinyl copolymer and from 0.03 and up to 1.0 equivalent, based on equivalents of carboxylic acid in the polymer, of one or more active compound chosen from an aminoguanidine, semicarbazide, dihydrazide, guanamine, hydrazine and a salt thereof. Further, the invention provides methods of applying the coating composition to leather crust or to tanned leather, and to the flesh coated leather or coated leather crust produced thereby. The leather crust and tanned leather produced by the invention, for example fleshcoated or finished leather, will emit greatly reduced levels of aldehydes over time and especially valuable in scrubbing aldehydes from perforated leather for automotive use.
摘要翻译： 本发明提供包含一种或多种酸性官能的丙烯酸或乙烯基共聚物水溶液的含水肉皮组合物，和基于聚合物中羧酸当量的0.03和至多1.0当量的一种或多种活性化合物，所述活性化合物选自氨基胍， 氨基脲，二酰肼，胍胺，肼及其盐。 此外，本发明提供了将涂料组合物施用于皮革皮革或鞣制的皮革以及由其制备的肉皮涂层皮革或涂覆的皮革外皮的方法。 由本发明生产的皮革外壳和鞣制皮革，例如肉皮或成品皮革，随着时间的推移，将大大降低醛的含量，特别是在从用于汽车用途的穿孔皮革洗涤醛时尤其有价值。
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