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公开(公告)号:US08729140B2
公开(公告)日:2014-05-20
申请号:US13333409
申请日:2011-12-21
CPC分类号: B01J23/94 , B01J21/063 , B01J23/8892 , B01J37/0009 , B01J38/10 , B01J38/12 , B01J38/66 , C10G2/332 , C10G2300/70
摘要: A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle(s), comprising the steps of: (i) oxidizing the catalyst particle(s) at a temperature between 20 and 400° C.; (ii) treating the catalyst particle(s) for more than 5 minutes, (iii) drying the catalyst particle(s); and (iv) optionally reducing the catalyst particle(s) with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s). The treatment is performed using carbon dioxide and a liquid comprising ammonia.
摘要翻译: 一种用于再生一种或多种包含费 - 托催化剂颗粒的失活的钴的方法,包括以下步骤:(i)在20-400℃的温度下氧化催化剂颗粒; (ii)处理催化剂颗粒超过5分钟,(iii)干燥催化剂颗粒; 和(iv)任选地用氢或包含气体的氢还原催化剂颗粒。 此过程之前可以是从催化剂颗粒中除去费 - 托产物的步骤。 使用二氧化碳和包含氨的液体进行处理。
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公开(公告)号:US07625539B2
公开(公告)日:2009-12-01
申请号:US12092367
申请日:2006-11-02
申请人: Cornelis Petrus Johannes Maria Van Den Brand , Lydia Singoredjo , Johannes Theodorus Maria Smits
发明人: Cornelis Petrus Johannes Maria Van Den Brand , Lydia Singoredjo , Johannes Theodorus Maria Smits
CPC分类号: B01D53/8603 , B01D53/48 , B01D2257/304 , B01D2257/306 , C01B17/0404 , C01B17/0452 , C01B17/0456 , C01B17/165
摘要: A process for producing a purified gas stream from a feed gas stream comprising contaminants, the process comprising the steps of: (a) removing contaminants from the feed gas stream to obtain the purified gas stream and a sour gas stream comprising H2S and RSH; (b) separating the sour gas stream comprising H2S and RSH into a gas stream enriched in H2S and a residual gas stream comprising RSH; (c) converting H2S in the gas stream enriched in H2S to elemental sulphur in a Claus unit, thereby obtaining a first off-gas stream comprising SO2; (d) converting SO2 in the first off-gas stream comprising SO2 to H2S in a Claus off-gas treating reactor to obtain a second off-gas stream comprising H2S; (e) converting RSH from the residual gas stream comprising RSH to H2S in an RSH conversion reactor to obtain a residual gas stream comprising H2S, wherein at least one of the operating conditions of the RSH conversion reactor is different from the corresponding operating condition of the Claus off-gas treating reactor.
摘要翻译: 一种从包含污染物的进料气流产生净化气流的方法,该方法包括以下步骤:(a)从进料气流中除去污染物以获得纯化气流和包含H 2 S和RSH的酸性气流; (b)将包含H 2 S和RSH的酸性气流分离成富含H 2 S的气流和包含RSH的残余气流; (c)在克劳斯单元中将富含H 2 S的气流中的H 2 S转化为元素硫,从而获得包含SO 2的第一废气流; (d)在克劳斯废气处理反应器中将包含SO 2的第一废气流中的SO 2转化为H 2 S.以获得包含H 2 S的第二废气流; (e)在RSH转化反应器中将RSH从包括RSH的残余气流转化为H 2 S以获得包含H 2 S的残余气流,其中RSH转化反应器的至少一个操作条件不同于 克劳斯废气处理反应器。
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公开(公告)号:US20100184875A1
公开(公告)日:2010-07-22
申请号:US12638647
申请日:2009-12-15
申请人: Gerrit Leendert BEZEMER , Carolus Matthias Anna Maria MESTERS , Thomas Joris REMANS , Johannes Theodorus Maria SMITS
发明人: Gerrit Leendert BEZEMER , Carolus Matthias Anna Maria MESTERS , Thomas Joris REMANS , Johannes Theodorus Maria SMITS
IPC分类号: C07C27/00
CPC分类号: B01J35/023 , B01J8/22 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J2208/00637 , C10G2/341
摘要: The present invention pertains to a process for carrying out a high-speed stop in a Fischer-Tropsch process which comprises providing a feed to a fixed bed reactor comprising a Fischer-Tropsch catalyst, the reactor being at reaction temperature and pressure, and withdrawing an effluent from the reactor, wherein the high-speed stop is effected by blocking provision of feed to the reactor and simultaneously blocking the withdrawal of effluent from the reactor.
摘要翻译: 本发明涉及在费 - 托方法中进行高速停止的方法,该方法包括向包含费 - 托催化剂的固定床反应器提供进料,反应器处于反应温度和压力下, 来自反应器的流出物,其中高速停止通过阻止向反应器提供进料并同时阻止流出物从反应器中排出来实现。
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公开(公告)号:US20120165417A1
公开(公告)日:2012-06-28
申请号:US13333409
申请日:2011-12-21
CPC分类号: B01J23/94 , B01J21/063 , B01J23/8892 , B01J37/0009 , B01J38/10 , B01J38/12 , B01J38/66 , C10G2/332 , C10G2300/70
摘要: A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle(s), comprising the steps of: (i) oxidising the catalyst particle(s) at a temperature between 20 and 400° C.; (ii) treating the catalyst particle(s) for more than 5 minutes, (iii) drying the catalyst particle(s); and (iv) optionally reducing the catalyst particle(s) with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s). The treatment is performed using carbon dioxide and a liquid comprising ammonia.
摘要翻译: 一种用于再生一种或多种包含费 - 托催化剂颗粒的失活的钴的方法,包括以下步骤:(i)在20-400℃的温度下氧化催化剂颗粒; (ii)处理催化剂颗粒超过5分钟,(iii)干燥催化剂颗粒; 和(iv)任选地用氢或包含气体的氢还原催化剂颗粒。 此过程之前可以是从催化剂颗粒中除去费 - 托产物的步骤。 使用二氧化碳和包含氨的液体进行处理。
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公开(公告)号:US08933136B2
公开(公告)日:2015-01-13
申请号:US12638647
申请日:2009-12-15
申请人: Gerrit Leendert Bezemer , Carolus Matthias Anna Maria Mesters , Thomas Joris Remans , Johannes Theodorus Maria Smits
发明人: Gerrit Leendert Bezemer , Carolus Matthias Anna Maria Mesters , Thomas Joris Remans , Johannes Theodorus Maria Smits
IPC分类号: C07C27/00 , B01J35/02 , B01J8/22 , C10G2/00 , B01J23/75 , B01J23/847 , B01J23/889
CPC分类号: B01J35/023 , B01J8/22 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J2208/00637 , C10G2/341
摘要: The present invention pertains to a process for carrying out a high-speed stop in a Fischer-Tropsch process which comprises providing a feed to a fixed bed reactor comprising a Fischer-Tropsch catalyst, the reactor being at reaction temperature and pressure, and withdrawing an effluent from the reactor, wherein the high-speed stop is effected by blocking provision of feed to the reactor and simultaneously blocking the withdrawal of effluent from the reactor.
摘要翻译: 本发明涉及在费 - 托方法中进行高速停止的方法,该方法包括向包含费 - 托催化剂的固定床反应器提供进料,反应器处于反应温度和压力下, 来自反应器的流出物,其中高速停止通过阻止向反应器提供进料并同时阻止流出物从反应器中排出来实现。
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公开(公告)号:US20080279759A1
公开(公告)日:2008-11-13
申请号:US12092367
申请日:2006-11-02
申请人: Cornelis Petrus Johannes Maria Van Den Brand , Lydia Singoredjo , Johannes Theodorus Maria Smits
发明人: Cornelis Petrus Johannes Maria Van Den Brand , Lydia Singoredjo , Johannes Theodorus Maria Smits
CPC分类号: B01D53/8603 , B01D53/48 , B01D2257/304 , B01D2257/306 , C01B17/0404 , C01B17/0452 , C01B17/0456 , C01B17/165
摘要: A process for producing a purified gas stream from a feed gas stream comprising contaminants, the process comprising the steps of: (a) removing contaminants from the feed gas stream to obtain the purified gas stream and a sour gas stream comprising H2S and RSH; (b) separating the sour gas stream comprising H2S and RSH into a gas stream enriched in H2S and a residual gas stream comprising RSH; (c) converting H2S in the gas stream enriched in H2S to elemental sulphur in a Claus unit, thereby obtaining a first off-gas stream comprising SO2; (d) converting SO2 in the first off-gas stream comprising SO2 to H2S in a Claus off-gas treating reactor to obtain a second off-gas stream comprising H2S; (e) converting RSH from the residual gas stream comprising RSH to H2S in an RSH conversion reactor to obtain a residual gas stream comprising H2S, wherein at least one of the operating conditions of the RSH conversion reactor is different from the corresponding operating condition of the Claus off-gas treating reactor.
摘要翻译: 一种从包含污染物的进料气流产生净化气体流的方法,该方法包括以下步骤:(a)从进料气流中除去污染物以获得纯化气流和含有H 2 S和RSH; (b)将包含H 2 S和RSH的酸性气流分离成富含H 2 S的气流和包含RSH的残余气流; (c)将富含H 2 S的气流中的H 2 S转化为克劳斯单元中的元素硫,从而获得包含SO 2 SUB> (d)在克劳斯废气处理反应器中将包含SO 2的第一废气流中的SO 2 H 2转化为H 2 S, 得到包含H 2 S的第二废气流; (e)在RSH转化反应器中将RSH从包含RSH的残余气流转化为H 2 S以获得包含H 2 S的残余气流,其中至少一个 的RSH转化反应器的操作条件与克劳斯废气处理反应器的相应操作条件不同。
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