公开(公告)号：US08378039B2

公开(公告)日：2013-02-19

申请号：US13127012

申请日：2009-11-23

申请人： Jae Hoon Choe ,  Chang Houn Rhee ,  Jung Hyun Seo ,  Yoo Seok Kim ,  In Hyoup Song ,  Jung Uk Choi ,  Kwang Ho Song

发明人： Jae Hoon Choe ,  Chang Houn Rhee ,  Jung Hyun Seo ,  Yoo Seok Kim ,  In Hyoup Song ,  Jung Uk Choi ,  Kwang Ho Song

IPC分类号： C08F2/01 ,  C08F12/20 ,  B01J19/00

CPC分类号： B01J19/0093 ,  B01J19/243 ,  B01J2219/00788 ,  B01J2219/00889 ,  C08J3/12 ,  C08J3/126 ,  C08J2325/06 ,  C08J2333/06

摘要： [Summary]The present invention relates to an apparatus for manufacturing polymer particles and a method for manufacturing the same. The present invention provides an apparatus and a method, by which polymer particles having excellent monodispersity and homogeneous physical properties, such as homogeneous cross-linking degree and polymerization degree, may be efficiently prepared. In the present invention, particles having excellent monodispersity with the desired particle diameter, and also having a high cross-linking degree or a core-shell or core-double shell structure may also be effectively prepared. In addition, the processes for manufacturing said polymer particles are exceptionally reproducible in the present invention. Additionally, the present invention provides an apparatus which may effectively control particle diameter, shape, cross-linking degree, polymerization degree or structure, and the concentration of solid content in a polymer solution, and the like, depending on the intended purpose, and a method thereof.

摘要翻译： 发明内容本发明涉及聚合物粒子的制造装置及其制造方法。 本发明提供一种可以有效地制备具有优异的单分散性和均匀的物理性质如均匀交联度和聚合度的聚合物颗粒的装置和方法。 在本发明中，也可以有效地制备具有所需粒径，具有高交联度或者核 - 壳或核 - 双壳结构的具有优异的单分散性的颗粒。 此外，制造所述聚合物颗粒的方法在本发明中是非常可重现的。 另外，本发明提供一种可以有效地控制聚合物溶液中的粒径，形状，交联度，聚合度或结构以及固体含量的浓度等的装置，这取决于预期目的，以及 方法。

公开(公告)号：US08013060B2

公开(公告)日：2011-09-06

申请号：US11920858

申请日：2006-05-23

申请人： Jong-suh Park ,  Sun-hyuk Choi ,  Ji-ho Yoon ,  Jung-uk Choi

发明人： Jong-suh Park ,  Sun-hyuk Choi ,  Ji-ho Yoon ,  Jung-uk Choi

IPC分类号： C08L83/06

CPC分类号： C08G77/32 ,  B01D1/225 ,  B01D3/10

摘要： The present invention relates to a method for concentrating organic silicate polymer solution, and more precisely, a method for concentrating organic silicate polymer solution by distillation which is characterized by remarkably reduced distillation time realized by the short-term continuous distillation at low temperature under low pressure, minimized physical property changes attributed to the inhibition of the heat-induced reaction by making the solution pass through the thin film evaporator shortly, concentration without cake generation, and easy manipulation with high capacity, making the method highly economical.

摘要翻译： 本发明涉及一种浓缩有机硅酸盐聚合物溶液的方法，更确切地说，是一种通过蒸馏浓缩有机硅酸盐聚合物溶液的方法，其特征在于在低压下通过短时间连续蒸馏在低压下实现的显着减少的蒸馏时间 通过使溶液快速通过薄膜蒸发器而导致热诱导反应的抑制所引起的物理特性变化最小化，不产生滤饼的浓度，容易操作，容易操作，使得该方法非常经济。

公开(公告)号：US20100130683A1

公开(公告)日：2010-05-27

申请号：US11920858

申请日：2006-05-23

申请人： Jong-suh Park ,  Sun-hyuk Choi ,  Ji-hi Yoon ,  Jung-uk Choi

发明人： Jong-suh Park ,  Sun-hyuk Choi ,  Ji-hi Yoon ,  Jung-uk Choi

IPC分类号： C08L83/06

CPC分类号： C08G77/32 ,  B01D1/225 ,  B01D3/10

摘要： The present invention relates to a method for concentrating organic silicate polymerite solution, and more precisely, a method for concentrating organic silicate polymerite solution by distillation which is characterized by remarkably reduced distillation time realized by the short-term continuous distillation at low temperature under low pressure, minimized physical property changes attributed to the inhibition of the heat-induced reaction by making the solution pass through the thin film evaporator shortly, concentration without cake generation, and easy manipulation with high capacity, making the method highly economical.

摘要翻译： 本发明涉及一种浓缩有机硅酸盐聚合物溶液的方法，更确切地说，涉及一种通过蒸馏浓缩有机硅酸盐聚合物溶液的方法，其特征在于在低温下在低压下短期连续蒸馏实现的蒸馏时间显着减少 通过使溶液快速通过薄膜蒸发器而导致热诱导反应的抑制所引起的物理特性变化最小化，不产生滤饼的浓度，容易操作，容易操作，使得该方法非常经济。

公开(公告)号：US20090311150A1

公开(公告)日：2009-12-17

申请号：US12309400

申请日：2007-07-19

申请人： Jun Yeon Cho ,  Jae Hoon Choe ,  Kwang Cheon Park ,  Gyea-Young Kwak ,  Chang Houn Rhee ,  Sun Hyuk Bae ,  Jung Uk Choi ,  Kwang Ho Song

发明人： Jun Yeon Cho ,  Jae Hoon Choe ,  Kwang Cheon Park ,  Gyea-Young Kwak ,  Chang Houn Rhee ,  Sun Hyuk Bae ,  Jung Uk Choi ,  Kwang Ho Song

IPC分类号： C01B3/38 ,  B01J10/00

CPC分类号： C01B3/34 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1217 ,  C01B2203/1235 ,  Y02P20/124

摘要： The present invention discloses to a chemical reactor with high heat efficiency and small volume, the chemical reaction of the present invention comprises a first unit for performing heat exchange of exothermic reaction products with exothermic reaction raw material fed for exothermic reaction; a second unit including a plate assembly for exothermic reactions and a plate assembly for endothermic reactions; and a third unit for performing heat exchange of endothermic reaction products with endothermic reaction raw material fed for endothermic reactions, the exothermic reaction raw material discharged from the first unit is fed into the plate assembly for exothermic reactions in the second unit and used in the exothermic reactions, the exothermic reaction products are fed into the first unit to pre-heat the exothermic reaction raw material, the endothermic reaction raw material discharged from the third unit is fed into the plate assembly for endothermic reactions in the second unit and used in the endothermic reactions, the endothermic reaction products are fed into the third unit to pre-heat the endothermic reaction raw material, and the first unit, the second unit and the third unit are laminately disposed.

摘要翻译： 本发明公开了一种热效率高，体积小的化学反应器，本发明的化学反应包括用于进行放热反应的放热反应原料与放热反应产物进行热交换的第一单元; 包括用于放热反应的板组件和用于吸热反应的板组件的第二单元; 以及第三单元，用于进行用于吸热反应的吸热反应原料的吸热反应产物的热交换，从第一单元排出的放热反应原料在第二单元中进料到用于放热反应的板组件中，并用于放热 反应中，将放热反应产物进料到第一单元中以预热放热反应原料，将从第三单元排出的吸热反应原料供入第二单元中用于吸热反应的板组件中并用于吸热 反应中，将吸热反应产物进料到第三单元中以预热吸热反应原料，并且第一单元，第二单元和第三单元层叠。

公开(公告)号：US20070299226A1

公开(公告)日：2007-12-27

申请号：US11666280

申请日：2006-06-01

申请人： Jong-suh Park ,  Sun-hyuk Choi ,  Jung-uk Choi

发明人： Jong-suh Park ,  Sun-hyuk Choi ,  Jung-uk Choi

IPC分类号： C08F2/02 ,  C08F120/18 ,  C08F20/10 ,  C08F4/04 ,  C08F4/28

CPC分类号： C09J133/06 ,  C08F2/02

摘要： The present invention relates to a method for preparing an acrylic ester polymer syrup by bulk polymerization, and more particularly, to a method for preparing an acrylic ester polymer syrup, which comprises the steps of: supplying a monomer solution and an initiator solution to a monomer solution reservoir and an initiator solution reservoir, respectively; supplying the monomer solution and the initiator solution to a complete-mixing type continuous reactor, while maintaining the dissolved oxygen in the monomer solution reservoir and the initiator solution reservoir at 0.0001 to 3 ppm, separately or after mixing prior to the supply; and performing bulk polymerization continuously while maintaining the solution mixture supplied to the continuous reactor at 70 to 150 ° C. and 1 to 10 atm, with a mean residence time of 30 to 240 minutes. In accordance with the present invention, an acrylic ester polymer syrup can be obtained with a degree of polymerization of 20 to 70% at a low polymerization temperature, even with a small amount of initiator. Productivity can be improved by reducing reaction time with the use of an initiator having a short half-life and polymerization can be performed very stably and continuously without gelation.

摘要翻译： 本发明涉及通过本体聚合制备丙烯酸酯聚合物浆料的方法，更具体地说，涉及一种制备丙烯酸酯聚合物浆料的方法，其包括以下步骤：将单体溶液和引发剂溶液供应到单体 溶液储层和引发剂溶液储层; 将单体溶液和引发剂溶液供应到完全混合型连续反应器，同时将单体溶液储存器和引发剂溶液储存器中的溶解氧分别维持在0.0001至3ppm，或在供给之前混合; 并连续进行本体聚合，同时将提供给连续反应器的溶液混合物保持在70至150℃和1至10大气压，平均停留时间为30至240分钟。 根据本发明，即使使用少量的引发剂，也可以在低聚合温度下聚合度为20〜70％的丙烯酸酯聚合物糖浆。 通过使用半衰期短的引发剂减少反应时间可以提高生产率，聚合可以非常稳定和连续地进行而没有凝胶化。

公开(公告)号：US07202312B2

公开(公告)日：2007-04-10

申请号：US11050833

申请日：2005-01-27

申请人： Chul-Hwan Choi ,  Sung-Yeon Kim ,  Jung-Uk Choi

发明人： Chul-Hwan Choi ,  Sung-Yeon Kim ,  Jung-Uk Choi

IPC分类号： C08F132/00

CPC分类号： C08F232/08

摘要： A method for preparing a cyclic olefin polymer is described. The method includes polymerizing cyclic olefin monomers or a cyclic olefin monomer with ethylene to prepare a cyclic olefin polymer solution; slowly adding a non-solvent drop wise to the cyclic olefin polymer solution to precipitate a cyclic olefin polymer; and filtering and drying the precipitated cyclic olefin polymer. In addition, the cyclic olefin polymer prepared using this method is described. According to the present invention, a spherical cyclic olefin polymer having a high bulk density can be easily separated from the cyclic olefin polymer solution by precipitation.

摘要翻译： 描述了制备环烯烃聚合物的方法。 该方法包括使环烯烃单体或环烯烃单体与乙烯聚合以制备环烯烃聚合物溶液; 缓慢地向环状烯烃聚合物溶液中滴加非溶剂以沉淀环烯烃聚合物; 并过滤并干燥沉淀的环烯烃聚合物。 此外，描述了使用该方法制备的环烯烃聚合物。 根据本发明，通过沉淀可以容易地从环烯烃聚合物溶液中分离出具有高堆积密度的球形环烯烃聚合物。

公开(公告)号：US07988936B2

公开(公告)日：2011-08-02

申请号：US12309400

申请日：2007-07-19

申请人： Jun Yeon Cho ,  Jae Hoon Choe ,  Kwang Cheon Park ,  Gyea-Young Kwak ,  Chang Houn Rhee ,  Sun Hvuk Bae ,  Jung Uk Choi ,  Kwang Ho Song

发明人： Jun Yeon Cho ,  Jae Hoon Choe ,  Kwang Cheon Park ,  Gyea-Young Kwak ,  Chang Houn Rhee ,  Sun Hvuk Bae ,  Jung Uk Choi ,  Kwang Ho Song

IPC分类号： B01J8/00 ,  B01J10/00 ,  B01J8/04 ,  B01J19/00

CPC分类号： C01B3/34 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0811 ,  C01B2203/1041 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1076 ,  C01B2203/1217 ,  C01B2203/1235 ,  Y02P20/124

摘要： The present invention discloses to a chemical reactor with high heat efficiency and small volume, the chemical reaction of the present invention comprises a first unit for performing heat exchange of exothermic reaction products with exothermic reaction raw material fed for exothermic reaction; a second unit including a plate assembly for exothermic reactions and a plate assembly for endothermic reactions; and a third unit for performing heat exchange of endothermic reaction products with endothermic reaction raw material fed for endothermic reactions.

摘要翻译： 本发明公开了一种热效率高，体积小的化学反应器，本发明的化学反应包括用于进行放热反应的放热反应原料与放热反应产物进行热交换的第一单元; 包括用于放热反应的板组件和用于吸热反应的板组件的第二单元; 以及用于进行吸热反应的吸热反应原料进行吸热反应产物的热交换的第三单元。

公开(公告)号：US07510688B2

公开(公告)日：2009-03-31

申请号：US11526723

申请日：2006-09-26

申请人： Jae Hoon Choe ,  Jung Uk Choi ,  Young Woon Kwon ,  Kwang Cheon Park ,  Jung Hyun Seo ,  Jun Yeon Cho ,  Yoo Seok Kim ,  Kwang Ho Song

发明人： Jae Hoon Choe ,  Jung Uk Choi ,  Young Woon Kwon ,  Kwang Cheon Park ,  Jung Hyun Seo ,  Jun Yeon Cho ,  Yoo Seok Kim ,  Kwang Ho Song

IPC分类号： B01J8/02 ,  B01J8/04 ,  B01F5/06 ,  B01F13/00

CPC分类号： B01F13/0059 ,  B01F5/0641 ,  B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00835 ,  B01J2219/00889 ,  B01J2219/00984

摘要： A stack type reactor that can adjust a length of channel (reaction time) to react raw substances with each other for a sufficient time and mix completely raw substances to maximize the reaction efficiency. The stack type reactor comprises an upper block with at least two inlets that introduce different kinds of raw substances and a lower channel fluidly connected to the inlets and formed at a lower surface thereof; a unit block including an upper channel corresponding to the lower channel of the upper block and formed on an upper surface thereof, the unit block including a lower channel formed at a lower surface thereof and fluidly connected with the upper channel via a connecting flow passage. The upper block and unit block form a flow path for the raw substances by connecting to the lower channel of the upper block to the upper channel of the unit block.

摘要翻译： 一种可以调节通道长度（反应时间）以使原料彼此反应足够的时间并将完整的原料混合以使反应效率最大化的堆叠式反应器。 堆叠式反应器包括具有至少两个引入不同种类的原料的入口的上部块和与入口流体连接并形成在其下表面的下部通道; 单元块，包括与上块的下通道对应的上通道，并形成在其上表面上，该单元块包括形成在其下表面处的下通道，并且经由连接流道与上通道流体连接。 上部块和单位块通过连接到上部块的下部通道到单元块的上部通道而形成用于原料的流动路径。

公开(公告)号：US20050171258A1

公开(公告)日：2005-08-04

申请号：US11050833

申请日：2005-01-27

申请人： Chul-Hwan Choi ,  Sung-Yeon Kim ,  Jung-Uk Choi

发明人： Chul-Hwan Choi ,  Sung-Yeon Kim ,  Jung-Uk Choi

IPC分类号： C08F32/08 ,  C08F6/12 ,  C08F32/00 ,  C08F232/08 ,  C08L1/00

CPC分类号： C08F232/08

摘要： A method for preparing a cyclic olefin polymer is described. The method includes polymerizing cyclic olefin monomers or a cyclic olefin monomer with ethylene to prepare a cyclic olefin polymer solution; slowly adding a non-solvent drop wise to the cyclic olefin polymer solution to precipitate a cyclic olefin polymer; and filtering and drying the precipitated cyclic olefin polymer. In addition, the cyclic olefin polymer prepared using this method is described. According to the present invention, a spherical cyclic olefin polymer having a high bulk density can be easily separated from the cyclic olefin polymer solution by precipitation.

摘要翻译： 描述了制备环烯烃聚合物的方法。 该方法包括使环烯烃单体或环烯烃单体与乙烯聚合以制备环烯烃聚合物溶液; 缓慢地向环状烯烃聚合物溶液中滴加非溶剂以沉淀环烯烃聚合物; 并过滤并干燥沉淀的环烯烃聚合物。 此外，描述了使用该方法制备的环烯烃聚合物。 根据本发明，通过沉淀可以容易地从环烯烃聚合物溶液中分离出具有高堆积密度的球形环烯烃聚合物。

公开(公告)号：US08052939B2

公开(公告)日：2011-11-08

申请号：US12227685

申请日：2007-05-29

申请人： Jun Yeon Cho ,  Jung Uk Choi ,  Jae Hoon Choe ,  Kwang Cheon Park ,  Chang Houn Rhee ,  Sun Hyuk Bae ,  Kwang Ho Song

发明人： Jun Yeon Cho ,  Jung Uk Choi ,  Jae Hoon Choe ,  Kwang Cheon Park ,  Chang Houn Rhee ,  Sun Hyuk Bae ,  Kwang Ho Song

IPC分类号： B01J19/00 ,  B01J8/00 ,  B01J10/00 ,  B01J8/04

CPC分类号： C01B3/16 ,  B01J19/0093 ,  B01J2219/00783 ,  B01J2219/00804 ,  B01J2219/00835 ,  B01J2219/00873 ,  C01B2203/0283 ,  C01B2203/066 ,  C01B2203/0894 ,  C01B2203/1035

摘要： The present invention discloses to a channel reactor system having a first channel plate assembly in which an exothermic reaction is performed and a second channel plate assembly provided for heat-exchanging and constituted integrally with the first channel plate assembly so as to remove effectively heat, the channel reactor system comprising at least two channel units into which reaction gas and cooling fluid are separately introduced, each channel unit comprising a reaction channel plate assembly into which reaction gas is introduced and a heat-exchanging channel plate assembly into which cooling fluid is introduced; and at least one intermediate plate disposed between the upper and lower channel units, the intermediate plate supplying reaction gas and cooling fluid inflowed from the upper channel unit with new reactant and cooling fluid and supplying reaction gas and cooling fluid to the reaction channel plate assembly and the heat-exchanging channel plate assembly of the lower channel unit, respectively.

摘要翻译： 本发明公开了一种通道反应器系统，其具有其中进行放热反应的第一通道板组件和设置用于热交换并与第一通道板组件一体构成的第二通道板组件，以便有效地除去热量， 通道反应器系统包括至少两个通道单元，反应气体和冷却流体被单独引入到该通道单元中，每个通道单元包括反应通道板组件，反应气体被引入到其中;以及热交换通道板组件，其中引入冷却流体; 以及设置在上通道单元和下通道单元之间的至少一个中间板，中间板供应来自上通道单元的反应气体和冷却流体，其具有新的反应物和冷却流体，并将反应气体和冷却流体供应到反应通道板组件， 下通道单元的热交换通道板组件。