LITHIUM ION SECONDARY BATTERY
    2.
    发明申请
    LITHIUM ION SECONDARY BATTERY 审中-公开
    锂离子二次电池

    公开(公告)号:US20130078522A1

    公开(公告)日:2013-03-28

    申请号:US13613458

    申请日:2012-09-13

    摘要: There is provided is a lithium ion secondary battery. The lithium ion secondary battery includes: a positive electrode having a positive electrode active material layer containing a positive electrode active material containing a vanadium-based compound; and a negative electrode having a negative electrode active material layer containing a negative electrode active material into which lithium ions can be inserted/deinserted reversibly. A vanadium-based compound is dispersed in the negative electrode active material layer. As a result, a vanadium-based compound, corresponding to the vanadium-based compound contained in the positive electrode active material is dispersed in the negative electrode active material layer.

    摘要翻译: 提供了锂离子二次电池。 锂离子二次电池包括:正极,具有含有含有钒系化合物的正极活性物质的正极活性物质层; 以及具有负极活性物质层的负极,所述负极活性物质层含有能够可逆地插入/脱嵌的锂离子的负极活性物质。 钒基化合物分散在负极活性物质层中。 结果,对应于正极活性物质中含有的钒系化合物的钒系化合物分散在负极活性物质层中。

    Process for producing lithium vanadium phosphate-carbon composite
    3.
    发明授权
    Process for producing lithium vanadium phosphate-carbon composite 有权
    生产锂钒磷酸盐 - 碳复合材料的方法

    公开(公告)号:US09437866B2

    公开(公告)日:2016-09-06

    申请号:US13823612

    申请日:2011-09-22

    摘要: A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.

    摘要翻译: 一种制备锂钒磷酸盐 - 碳复合材料的方法包括第一步骤,其包括在水性溶剂中将锂源,四价或五价钒化合物,磷源和通过热解产生碳的导电碳材料源混合至 制备原料混合物,第二步骤包括加热原料混合物进行沉淀反应以获得包含沉淀物的反应混合物,第三步骤包括使用介质对含有沉淀物的反应混合物进行湿磨研磨 研磨以获得包括研磨颗粒的浆料,第四步骤包括喷雾干燥包含研磨颗粒的浆料以获得反应前体,第五步包括在600至1300℃下煅烧反应前体, 惰性气体气氛或还原气氛。 通过该方法生产的锂钒磷酸铁复合物可以提供当用作阴极活性材料时具有优异的电池性能(例如,高放电容量)的锂二次电池。

    Positive electrode material
    4.
    发明授权
    Positive electrode material 有权
    正极材料

    公开(公告)号:US08802293B2

    公开(公告)日:2014-08-12

    申请号:US13606654

    申请日:2012-09-07

    IPC分类号: H01M4/00

    摘要: A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 μm to 2.6 μm and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.

    摘要翻译: 正极材料包括平均一次粒径为0.3μm至2.6μm,微晶尺寸为24nm至33nm的磷酸钒锂颗粒。 相对于总的磷酸钒锂粒子,以0.5质量%〜2.4质量%的范围的导电性碳覆盖磷酸钒锂颗粒。

    NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
    5.
    发明申请
    NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
    非水电解质二次电池

    公开(公告)号:US20130084499A1

    公开(公告)日:2013-04-04

    申请号:US13605707

    申请日:2012-09-06

    IPC分类号: H01M4/525 H01M4/54

    摘要: In a non-aqueous electrolyte secondary battery, a positive electrode active material includes a carbon-coated lithium vanadium phosphate and a lithium nickel composite oxide. A negative electrode active material includes a carbon-based active material capable of intercalating and deintercalating lithium ions. When a first charge capacity of a negative electrode per unit area is “x” (mAh/cm2), and a first charge capacity of a positive electrode per unit area is “y” (mAh/cm2), a relation of “x” and “y” satisfies 0.6≦y/x≦0.92.

    摘要翻译: 在非水电解质二次电池中,正极活性物质包括碳涂覆的磷酸钒锂和锂镍复合氧化物。 负极活性物质包括能够嵌入和脱嵌锂离子的碳系活性物质。 当单位面积的负极的第一充电容量为x(mAh / cm 2),并且每单位面积的正极的第一充电容量为y(mAh / cm 2)时,x和y的关系满足0.6≦̸ y / x≦̸ 0.92。

    NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
    6.
    发明申请
    NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 审中-公开
    非水电解质二次电池

    公开(公告)号:US20130084492A1

    公开(公告)日:2013-04-04

    申请号:US13605531

    申请日:2012-09-06

    IPC分类号: H01M4/485 H01M10/0564

    摘要: In a non-aqueous electrolyte secondary battery, a first active material of a positive electrode includes at least one of carbon-coated LiFePO4, LiMnPO4 and Li3V2(PO4)3. A second active material of the positive electrode includes lithium nickel composite oxide. An electrolytic solution includes fluorinated ethylene carbonate.

    摘要翻译: 在非水电解质二次电池中,正极的第一活性物质包括碳涂覆的LiFePO 4,LiMnPO 4和Li 3 VO 2(PO 4)3中的至少一种。 正极的第二活性物质包括锂镍复合氧化物。 电解液包括氟化碳酸亚乙酯。

    PROCESS FOR PRODUCING LITHIUM VANADIUM PHOSPHATE-CARBON COMPOSITE
    7.
    发明申请
    PROCESS FOR PRODUCING LITHIUM VANADIUM PHOSPHATE-CARBON COMPOSITE 有权
    用于生产磷酸氢钙 - 碳复合材料的方法

    公开(公告)号:US20130214462A1

    公开(公告)日:2013-08-22

    申请号:US13823612

    申请日:2011-09-22

    IPC分类号: H01M4/1397

    摘要: A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.

    摘要翻译: 一种制备锂钒磷酸盐 - 碳复合材料的方法包括第一步骤,其包括在水性溶剂中将锂源,四价或五价钒化合物,磷源和通过热解产生碳的导电碳材料源混合至 制备原料混合物,第二步骤包括加热原料混合物进行沉淀反应以获得包含沉淀物的反应混合物,第三步骤包括使用介质对含有沉淀物的反应混合物进行湿磨研磨 研磨以获得包括研磨颗粒的浆料,第四步骤包括喷雾干燥包含研磨颗粒的浆料以获得反应前体,第五步包括在600至1300℃下煅烧反应前体, 惰性气体气氛或还原气氛。 通过该方法生产的锂钒磷酸铁复合物可以提供当用作阴极活性材料时具有优异的电池性能(例如,高放电容量)的锂二次电池。