摘要:
A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 μm to 2.6 μm and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.
摘要:
There is provided is a lithium ion secondary battery. The lithium ion secondary battery includes: a positive electrode having a positive electrode active material layer containing a positive electrode active material containing a vanadium-based compound; and a negative electrode having a negative electrode active material layer containing a negative electrode active material into which lithium ions can be inserted/deinserted reversibly. A vanadium-based compound is dispersed in the negative electrode active material layer. As a result, a vanadium-based compound, corresponding to the vanadium-based compound contained in the positive electrode active material is dispersed in the negative electrode active material layer.
摘要:
A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.
摘要:
A positive-electrode material includes lithium vanadium phosphate particles having an average primary particle diameter from 0.3 μm to 2.6 μm and crystallite sizes from 24 nm to 33 nm. The lithium vanadium phosphate particles are coated with a conductive carbon of a range of 0.5 mass % to 2.4 mass % with respect to a total lithium vanadium phosphate particles.
摘要:
In a non-aqueous electrolyte secondary battery, a positive electrode active material includes a carbon-coated lithium vanadium phosphate and a lithium nickel composite oxide. A negative electrode active material includes a carbon-based active material capable of intercalating and deintercalating lithium ions. When a first charge capacity of a negative electrode per unit area is “x” (mAh/cm2), and a first charge capacity of a positive electrode per unit area is “y” (mAh/cm2), a relation of “x” and “y” satisfies 0.6≦y/x≦0.92.
摘要翻译:在非水电解质二次电池中,正极活性物质包括碳涂覆的磷酸钒锂和锂镍复合氧化物。 负极活性物质包括能够嵌入和脱嵌锂离子的碳系活性物质。 当单位面积的负极的第一充电容量为x(mAh / cm 2),并且每单位面积的正极的第一充电容量为y(mAh / cm 2)时,x和y的关系满足0.6≦̸ y / x≦̸ 0.92。
摘要:
In a non-aqueous electrolyte secondary battery, a first active material of a positive electrode includes at least one of carbon-coated LiFePO4, LiMnPO4 and Li3V2(PO4)3. A second active material of the positive electrode includes lithium nickel composite oxide. An electrolytic solution includes fluorinated ethylene carbonate.
摘要翻译:在非水电解质二次电池中,正极的第一活性物质包括碳涂覆的LiFePO 4,LiMnPO 4和Li 3 VO 2(PO 4)3中的至少一种。 正极的第二活性物质包括锂镍复合氧化物。 电解液包括氟化碳酸亚乙酯。
摘要:
A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.
摘要:
An electric storage device is provided with a positive electrode having a positive-electrode mixture layer including a positive-electrode active material. The positive-electrode active material includes a lithium-vanadium-phosphate from 8% to 70% by mass and a lithium-nickel complex oxide from 20% to 82% by mass. A coating concentration of the positive-electrode mixture layer is from 4 mg/cm2 to 20 mg/cm2. The lithium-nickel complex oxide includes a nickel element from 0.3 mol to 0.8 mol with respect to a lithium element of 1 mol.
摘要翻译:蓄电装置设置有具有包括正极活性物质的正极混合层的正极。 正极活性物质包含8〜70质量%的锂 - 磷酸钒,20〜82质量%的锂镍复合氧化物。 正极混合层的涂布浓度为4mg / cm 2〜20mg / cm 2。 锂镍复合氧化物包括相对于1摩尔锂元素为0.3摩尔至0.8摩尔的镍元素。
摘要:
Provided are a positive electrode active material, a lithium ion electric storage device using the same, and a manufacturing method thereof. The positive electrode active material contains (1) lithium nickel cobalt manganese oxide, and at least one type of a lithium ion acceptance capacity adjustment compound selected from (2a) lithium vanadium composite oxide, vanadium oxide, lithium vanadium phosphate, and lithium vanadium fluorophosphate and (2b) Nb2O5, TiO2, Li3/4Ti5/3O4, WO2, MoO2, and Fe2O3. The lithium ion electric storage device contains this positive electrode active material.