Sulfonated aromatic polyethers, process for production thereof, and electrolyte membranes
    2.
    发明申请
    Sulfonated aromatic polyethers, process for production thereof, and electrolyte membranes 审中-公开
    磺化芳族聚醚,其制备方法和电解质膜

    公开(公告)号:US20070010631A1

    公开(公告)日:2007-01-11

    申请号:US10574492

    申请日:2004-10-01

    IPC分类号: C08G65/48

    摘要: A sulfonated aromatic polyether useful for an electrolyte membrane superior in the properties such as conductivity and stability which has a principle backbone represented by the general formula (1). wherein Ar1 and Ar2 are defined C6-20 groups containing aromatic ring(s), x and y are each an integer of 0 to 3 which represent the degree of sulfonation, with the proviso that the case where both of x and y are simultaneously 0 is excluded, and n and m are each an integer of not lower than 2 which represent the degree of polymerization In the sulfonated aromatic polyether, the sites of introduction of the sulfonic acid groups are strictly specified, and the aromatic rings in the main chain has no sulfonic acid group at all, therefore, it is advantageous in that both of proton conductivity at higher than 100° C. and oxidative and hydrolytic stability are superior.

    摘要翻译: 一种用于电导率和稳定性优异的电解质膜的磺化芳族聚醚,其具有由通式(1)表示的主链。 其中Ar 1和Ar 2定义为含有芳环的C 6-20个基团,x和y各自为0的整数 3表示磺化度,条件是x和y两者同时为0的情况除外,n和m各自为不低于2的整数,表示聚合度在磺化芳族化合物中 聚醚,严格规定了磺酸基的引入位置,而且主链中的芳环根本没有磺酸基,因此有利的是,高于100℃的质子传导率和 氧化和水解稳定性优异。

    Polyimide resin, method of producing polyimide resin, and electrolyte membrane, catalyst layer, membrane/electrode assembly and device each containing polyimide resin
    4.
    发明申请
    Polyimide resin, method of producing polyimide resin, and electrolyte membrane, catalyst layer, membrane/electrode assembly and device each containing polyimide resin 审中-公开
    聚酰亚胺树脂,聚酰亚胺树脂的制造方法,电解质膜,催化剂层,膜/电极接合体以及各自含有聚酰亚胺树脂的装置

    公开(公告)号:US20070106057A1

    公开(公告)日:2007-05-10

    申请号:US10581933

    申请日:2004-12-08

    IPC分类号: C08G69/08

    摘要: A polyimide resin having a basic skeleton represented by the following general formula: (in the formula (1), each of Ar1 and Ar2 is an aromatic ring having a carbon number of 6-20, which forms an imide ring of 5 or 6 atoms with an imide group adjoining thereto. In the aromatic ring, a part of carbon atoms may be substituted with S, N, 0, SO2 or CO, or a part of hydrogen atoms may be substituted with an aliphatic group, a halogen atom or a perfluoro aliphatic group. Ar1 and Ar2 may be same or different. R is at least one of linear alkylene group and branched alkylene group having a carbon number of 1-20. Ar3 is an aromatic ring having a carbon number of 6-20 in which at least a part of hydrogen atoms is substituted with at least one of sulfoalkoxy group, carboalkoxy group and phosphoalkoxy group having a carbon number of 1-20 and a part of carbon atoms in these groups may be substituted with S, N, 0, SO2 or CO, or a part of hydrogen atoms may be substituted with an aliphatic group, a halogen atom or a perfluoro aliphatic group. n and m show a polymerization degree and are an integer of not less than 2.)

    摘要翻译: 具有由以下通式表示的基本骨架的聚酰亚胺树脂:(式(1)中,Ar 1和Ar 2各自为具有碳原子的芳香环, 数量为6〜20,与酰亚胺基相邻形成5或6个原子的酰亚胺环,在芳香环中,一部分碳原子可以被S,N,O,SO 2, 或者一部分氢原子可以被脂族基团,卤素原子或全氟脂族基团取代,Ar 1和Ar 2可以相同 或不同的,R是直链亚烷基和碳数为1-20的支链亚烷基中的至少一个,Ar 3是碳数为6〜20的芳环,其中至少 一部分氢原子被磺基烷氧基,碳烷氧基和碳数为1-20的磷酸烷氧基中的至少一个取代,这些基团中的一部分碳原子可以被S,N,O,SO 2 或CO, 或一部分氢原子可以被脂肪族基团,卤素原子或全氟脂族基团取代。 n和m表示聚合度,为不小于2的整数)