Process for the preparation of N,N-diisopropylbenzothiazyl-2-sulfenamide
    1.
    发明授权
    Process for the preparation of N,N-diisopropylbenzothiazyl-2-sulfenamide 失效
    制备N,N-二异丙基苯并噻唑-2-次磺酰胺的方法

    公开(公告)号:US4719305A

    公开(公告)日:1988-01-12

    申请号:US713066

    申请日:1985-03-18

    申请人: Kevin L. Rollick

    发明人: Kevin L. Rollick

    IPC分类号: C07D277/80

    CPC分类号: C07D277/80

    摘要: There is disclosed a process for the preparation of N,N-diisopropylbenzothiazyl-2-sulfenamide which comprises contacting an aqueous mixture of diisopropylamine and 2-mercaptobenzothiazole with an oxidizing agent in the presence of sufficient acid to neutralize the excess base, if any, in the oxidizing agent wherein the molar ratio of diisopropylamine to 2-mercaptobenzothiazole is at least 1.5 to 1.

    摘要翻译: 公开了一种制备N,N-二异丙基苯并噻唑-2-次磺酰胺的方法,该方法包括在足够的酸存在下使二异丙胺和2-巯基苯并噻唑的含水混合物与氧化剂接触以中和过量碱 其中二异丙胺与2-巯基苯并噻唑的摩尔比为至少1.5:1的氧化剂。

    Polyester modification method
    2.
    发明授权

    公开(公告)号:US10899881B1

    公开(公告)日:2021-01-26

    申请号:US16277550

    申请日:2019-02-15

    申请人: Kevin L. Rollick

    发明人: Kevin L. Rollick

    摘要: The subject invention provides a means for modifying existing polyester polymers to optimize characteristics for solid state polymerization and for utilization in a wide array of specific applications. For instance, the modification technique of this invention may be used to adjust the melting point, crystallization temperature (either from the solid or on cooling from the melt), glass transition temperature, natural stretch ratio, barrier properties, melt strength, and/or solid state polymerization characteristic of the polyester. Application of the instant invention could result in a polymer with substantially different physical properties, potentially allowing its use in heretofore high cost, specialty applications. A further advantage of the invention is that recycled polymer may be modified to broaden its potential uses into more demanding higher performance applications.

    Process for Creating An Oxygen Scavenging Particle
    4.
    发明申请
    Process for Creating An Oxygen Scavenging Particle 有权
    创建氧气清除颗粒的方法

    公开(公告)号:US20070200091A1

    公开(公告)日:2007-08-30

    申请号:US11678438

    申请日:2007-02-23

    申请人: Kevin L. Rollick

    发明人: Kevin L. Rollick

    IPC分类号: C01B3/00

    摘要: A method is disclosed for manufacturing one or more oxygen scavenging particles, wherein the particle(s) comprises an oxidizable metal particle, such as elemental iron; an acidifying electrolyte such as sodium or potassium bisulfate and optionally a water hydrolysable Lewis acid, such as aluminum chloride. The method comprises the step of coating the oxidizable particle with a first compound and then reacting the first compound with a second compound to form a third compound, wherein the third compound promotes the reaction of the oxidizable particle with oxygen.

    摘要翻译: 公开了用于制造一种或多种除氧颗粒的方法,其中颗粒包含可氧化的金属颗粒,例如元素铁; 酸化电解质如硫酸氢钠或硫酸氢钾,以及任选的水可水解路易斯酸,如氯化铝。 该方法包括用第一化合物涂覆可氧化颗粒的步骤,然后使第一化合物与第二化合物反应以形成第三化合物,其中第三化合物促进可氧化颗粒与氧的反应。

    Method of Making Vapor Deposited Oxygen-Scavenging Particles
    8.
    发明申请
    Method of Making Vapor Deposited Oxygen-Scavenging Particles 有权
    制备气相沉积氧清除颗粒的方法

    公开(公告)号:US20100068379A1

    公开(公告)日:2010-03-18

    申请号:US12623485

    申请日:2009-11-23

    申请人: Kevin L. Rollick

    发明人: Kevin L. Rollick

    IPC分类号: B05D7/14 B05D7/00

    摘要: This invention discloses a method of making an oxygen scavenging particle comprised of an activating component and an oxidizable component wherein one component is deposited upon the other component from a vapour phase and is particularly useful when the activating component is a protic solvent hydrolysable halogen compound and the oxygen scavenging particle is a reduced metal.

    摘要翻译: 本发明公开了一种由活化组分和可氧化组分组成的除氧颗粒的方法,其中一种组分从气相沉积在另一种组分上,当活化组分是质子溶剂可水解的卤素化合物时特别有用, 除氧颗粒是还原金属。

    Free radical cured rubber employing acrylate or methacrylate esters of
hydroxybenzene and hydroxynaphthalene compounds as co-curing agents
    9.
    发明授权
    Free radical cured rubber employing acrylate or methacrylate esters of hydroxybenzene and hydroxynaphthalene compounds as co-curing agents 失效
    使用羟基苯和羟基萘化合物的丙烯酸酯或甲基丙烯酸酯作为共固化剂的自由基固化橡胶

    公开(公告)号:US5310811A

    公开(公告)日:1994-05-10

    申请号:US124787

    申请日:1993-09-22

    摘要: Free radically curable rubbers are crosslinked with the aid of a free radical initiator and a co-curing agent, which is an acrylate or methacrylate ester of a hydroxybenzene or hydroxynaphthalene compound containing two or more hydroxyl groups, at least two of which are esterified. The rubbers which are used in the present invention are natural rubber and synthetic rubbers derived from a diene monomer. Preferred co-curing agents are acrylate and methacrylate esters of hydroxybenzene compounds in which the ester contains two or three acrylate or methacrylate groups per molecule. The amount of co-curing agent may be about 1-50 parts by weight per one hundred parts by weight of rubber (phr). Outstanding abrasion resistance and air oven aging are observed.

    摘要翻译: 自由基可固化橡胶借助于自由基引发剂和共固化剂,其是含有两个或多个羟基的羟基苯或羟基萘化合物的丙烯酸酯或甲基丙烯酸酯,其中至少两个被酯化。 用于本发明的橡胶是由二烯单体衍生的天然橡胶和合成橡胶。 优选的共固化剂是羟基苯化合物的丙烯酸酯和甲基丙烯酸酯,其中酯每分子含有两个或三个丙烯酸酯或甲基丙烯酸酯基团。 共固化剂的量可以为每100重量份橡胶约1-50重量份(phr)。 观察到出色的耐磨性和空气烘箱老化。