Dimensionally stable polyimide film and process for preparation thereof
    1.
    发明授权
    Dimensionally stable polyimide film and process for preparation thereof 失效
    尺寸稳定的聚酰亚胺薄膜及其制备方法

    公开(公告)号:US4725484A

    公开(公告)日:1988-02-16

    申请号:US864299

    申请日:1986-05-16

    摘要: A dimensionally stable polyimide film and processes for the preparation thereof. The polyimide film is composed of an aromatic polyimide obtained from a solution of a polymer formed by polymerization of a biphenyl-tetracarboxylic acid and a phenylene diamine, wherein the average linear expansion coefficient of the polyimide film in the temperature range of from 50.degree. C. to 300.degree. C. is 0.1.times.10.sup.-5 to 2.5.times.10.sup.-5 cm/cm..degree.C., the ratio of the linear expansion coefficient in the machine direction of the film to the linear expansion coefficient in the transverse direction of the film is in the range of from 1/5 to 4, and the thermal dimension stability expressed by the ratio of the change of the size of the film at normal temperature after the heat treatment where the temperature is elevated to 400.degree. C. from normal temperature and the film is maintained at 400.degree. C. for 2 hours is less than 0.3%.

    摘要翻译: 一种尺寸稳定的聚酰亚胺薄膜及其制备方法。 聚酰亚胺膜由通过联苯基 - 四羧酸和苯二胺的聚合形成的聚合物的溶液得到的芳香族聚酰亚胺构成,聚酰亚胺膜的平均线膨胀系数为50℃ 至300℃,为0.1×10 -5至2.5×10 -5 cm / cm。 ℃时,膜的纵向上的线膨胀系数与膜的横向的线膨胀系数之比在1/5〜4的范围内,由 在从常温升温至400℃的热处理后的常温下的膜尺寸变化率与膜在400℃保持2小时的比例小于0.3%。