Cross-linkable organometallic light emitting ligands and complexes

    公开(公告)号:US11420989B2

    公开(公告)日:2022-08-23

    申请号:US16490146

    申请日:2018-02-28

    申请人: LOMOX LIMITED

    摘要: A 1, 4 bidentate ligand comprising first and second ligand centres, wherein the first ligand centre is an sp2-hybridised carbon or a nitrogen atom; wherein the second ligand centre is a nitrogen atom in a five- or six-membered aromatic or hetero-aromatic ring, said ring having a substantially linear substituent T1 meta or para to the nitrogen atom; wherein T1 has the formula 1: —Ar1a—Y1b—Ar2—[Y2c—Ar2]d—S—B  (1) and wherein T1 is attached to the ring by X1, wherein X1 is a bond, a methylene group, a substituted methylene group, an oxygen atom or a sulphur atom, wherein each Ar1 and Ar2 are independently selected from the group of C6 to C20 aromatic and C4 to C20 heteroaromatic groups, wherein Y1 and each Y2 is independently an optionally substituted C2 or acetonitrile trans double-bond linking moiety, wherein a is 0, 1, 2 or 3, wherein b is 0, 1 or 2, wherein each c is independently 0, 1 or 2, wherein d is 0, 1, 2, 3 or 4, S is a flexible spacer, and B represents a moiety having one or more cross-linkable functionalities. Network polymers, complexes, compositions, and devices based on this ligand. Method for forming devices based on this ligand.

    Dibenzo[d,B]silole-based reactive mesogens

    公开(公告)号:US11316118B2

    公开(公告)日:2022-04-26

    申请号:US16338070

    申请日:2017-10-06

    申请人: LOMOX LIMITED

    摘要: A compound of Formula (I) D-S1-A-S2—B1,  Formula (I) wherein: A represents a conjugated chain of from 1 to 20 aromatic moieties independently selected from the group consisting of aromatic moieties, heteroaromatic moieties and E moieties, provided that A includes at least one E moiety, wherein E is selected from the group consisting of: E1 being a dibenzo[d,b]silole moiety of the structure: E2 being a moiety of the structure: and E3 being a moiety of the structure: wherein E is connected in the conjugated chain of A and optionally to S1 or to S2 through covalent bonds at Y and Z; wherein each R is independently selected from the group consisting of straight chain or branched C1-C20 alkyl and C2-C20 alkenyl, optionally wherein from 1 to 5 CH2 groups are each replaced by an oxygen, provided that no acetal, ketal, peroxide or vinyl ether is present in the R group, and optionally wherein each H bonded to a C in each R group may independently be replaced by a halogen; wherein the X moieties are the same and are selected from the group consisting of hydrogen, straight chain or branched C1-C8 alkyl, straight chain or branched C1-C8 alkoxyl and a halogen, wherein each E moiety may have the same or different X moieties, wherein W is either an oxygen or sulfur atom, D represents a moiety having one or more cross-linkable functionalities, S1 and S2 are flexible linker groups; and B1 represents a moiety having one or more cross-linkable functionalities or a hydrogen atom, with the proviso that when B1 represents a hydrogen atom, D represents a moiety having at least two cross-linkable functionalities.

    CROSS-LINKABLE ORGANOMETALLIC LIGHT EMITTING LIGANDS AND COMPLEXES

    公开(公告)号:US20200010495A1

    公开(公告)日:2020-01-09

    申请号:US16490146

    申请日:2018-02-28

    申请人: LOMOX LIMITED

    IPC分类号: C07F15/00 H01L51/00 C07F7/08

    摘要: A 1, 4 bidentate ligand comprising first and second ligand centres, wherein the first ligand centre is an sp2-hybridised carbon or a nitrogen atom; wherein the second ligand centre is a nitrogen atom in a five- or six-membered aromatic or hetero-aromatic ring, said ring having a substantially linear substituent T1 meta or para to the nitrogen atom; wherein T1 has the formula 1: —Ar1a—Y1b—Ar2—[Y2c—Ar2]d—S—B  (1) and wherein T1 is attached to the ring by X1, wherein X1 is a bond, a methylene group, a substituted methylene group, an oxygen atom or a sulphur atom, wherein each Ar1 and Ar2 are independently selected from the group of C6 to C20 aromatic and C4 to C20 heteroaromatic groups, wherein Y1 and each Y2 is independently an optionally substituted C2 or acetonitrile trans double-bond linking moiety, wherein a is 0, 1, 2 or 3, wherein b is 0, 1 or 2, wherein each c is independently 0, 1 or 2, wherein d is 0, 1, 2, 3 or 4, S is a flexible spacer, and B represents a moiety having one or more cross-linkable functionalities. Network polymers, complexes, compositions, and devices based on this ligand. Method for forming devices based on this ligand.

    ORGANIC LIGHT EMITTING DIODE STRUCTURE AND METHOD OF FORMING SAME

    公开(公告)号:US20170338445A1

    公开(公告)日:2017-11-23

    申请号:US15499251

    申请日:2017-04-27

    申请人: Lomox Limited

    摘要: There is provided organic light emitting diode (OLED) device that include an organic electroluminescent layer formed between a first electrode and a second electrode. The organic electroluminescent layer is formed of a photo-crosslinkable liquid having dichroic molecules therein, and has a grating pattern defined therein by exposure of regions of the organic electroluminescent layer to a light beam. The refractive index of the exposed regions of the organic electroluminescent layer varies across the grating pattern. A method for fabricating the OLED device is also provided that includes providing the organic electroluminescent layer and defining the grating pattern in the photo-crosslinkable liquid by illuminating regions of the organic electroluminescent layer with a light beam. The refractive index of the defined grating pattern is tuned by adjusting the dosage of light to which the photo-crosslinkable liquid is exposed.

    ORGANIC LIGHT EMITTING DIODE STRUCTURE
    5.
    发明申请
    ORGANIC LIGHT EMITTING DIODE STRUCTURE 有权
    有机发光二极管结构

    公开(公告)号:US20160126488A1

    公开(公告)日:2016-05-05

    申请号:US14894667

    申请日:2014-05-28

    申请人: LOMOX LIMITED

    IPC分类号: H01L51/52

    摘要: There is provided an organic light emitting diode (OLED) comprising an organic electroluminescent layer formed between a first electrode and a second electrode, characterised in that one of the first and second electrodes comprises a nano-meter metallic layer having a plasmonic photonic crystal structure formed thereon, and wherein the plasmonic photonic crystal structure is configured to interact with surface plasmon polaritons generated at a surface of the ne electrode thereby providing for transmission of electromagnetic radiation having a wavelength of between 350 nm to 750 nm from the OLED.

    摘要翻译: 提供了一种有机发光二极管(OLED),其包括在第一电极和第二电极之间形成的有机电致发光层,其特征在于,所述第一和第二电极中的一个包括形成有等离子体激元光子晶体结构的纳米金属层 并且其中等离子体激元光子晶体结构被配置为与在ne电极的表面处产生的表面等离子体激元极化相互作用,从而提供从OLED到具有350nm至750nm的波长的电磁辐射的透射。

    DIBENZO[D,B]SILOLE-BASED REACTIVE MESOGENS
    7.
    发明申请

    公开(公告)号:US20190280223A1

    公开(公告)日:2019-09-12

    申请号:US16338070

    申请日:2017-10-06

    申请人: LOMOX LIMITED

    摘要: A compound of Formula (I) D-S1-A-S2—B1,  Formula (I) wherein: A represents a conjugated chain of from 1 to 20 aromatic moieties independently selected from the group consisting of aromatic moieties, heteroaromatic moieties and E moieties, provided that A includes at least one E moiety, wherein E is selected from the group consisting of: E1 being a dibenzo[d,b]silole moiety of the structure: E2 being a moiety of the structure: and E3 being a moiety of the structure: wherein E is connected in the conjugated chain of A and optionally to S1 or to S2 through covalent bonds at Y and Z; wherein each R is independently selected from the group consisting of straight chain or branched C1-C20 alkyl and C2-C20 alkenyl, optionally wherein from 1 to 5 CH2 groups are each replaced by an oxygen, provided that no acetal, ketal, peroxide or vinyl ether is present in the R group, and optionally wherein each H bonded to a C in each R group may independently be replaced by a halogen; wherein the X moieties are the same and are selected from the group consisting of hydrogen, straight chain or branched C1-C8 alkyl, straight chain or branched C1-C8 alkoxyl and a halogen, wherein each E moiety may have the same or different X moieties, wherein W is either an oxygen or sulfur atom, D represents a moiety having one or more cross-linkable functionalities, S1 and S2 are flexible linker groups; and B1 represents a moiety having one or more cross-linkable functionalities or a hydrogen atom, with the proviso that when B1 represents a hydrogen atom, D represents a moiety having at least two cross-linkable functionalities.

    Organic light emitting diode structure

    公开(公告)号:US10211419B2

    公开(公告)日:2019-02-19

    申请号:US15823924

    申请日:2017-11-28

    申请人: LOMOX LIMITED

    IPC分类号: H01L51/52

    摘要: An organic light emitting diode (OLED) having an organic electroluminescent layer formed between a first electrode and a second electrode. One of the first and second electrodes is a transparent electrode having a surface through which light is emitted from the OLED to the outside. The transparent electrode has a plasmonic photonic crystal structure fabricated having an artificial lattice with a pitch in density variation intermediate in size between a metallic crystal and a photonic crystal formed in the same material as the transparent electrode, thereby operable to suppress propagation of the surface plasmon polaritons at the surface.

    Organic light emitting diode structure

    公开(公告)号:US09831458B2

    公开(公告)日:2017-11-28

    申请号:US14894667

    申请日:2014-05-28

    申请人: LOMOX LIMITED

    IPC分类号: H01L51/52

    摘要: There is provided an organic light emitting diode (OLED) comprising an organic electroluminescent layer formed between a first electrode and a second electrode, characterized in that one of the first and second electrodes comprises a nano-meter metallic layer having a plasmonic photonic crystal structure formed thereon, and wherein the plasmonic photonic crystal structure is configured to interact with surface plasmon polaritons generated at a surface of the ne electrode thereby providing for transmission of electromagnetic radiation having a wavelength of between 350 nm to 750 nm from the OLED.