摘要:
Thermoplastic molding compositions are made from a mixture of thermoplastic material (for example, polycaprolactone), a free-radically polymerizable resin (for example, a urethane diacrylate oligomer), and free-radical initiator (for example, a visible-light cure photoinitiator). The mixture is solid at 38.degree. C., has a melting or softening point that comfortably can be withstood by oral tissues, and can be imprinted with a heat-stable custom shape memory and semi-thermoplastic properties by shaping the composition to a desired shape and then causing or permitting the resin to undergo polymerization.
摘要:
A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
摘要:
A mixture of hydroxy functional polymers which can be used to form isocyanate prepolymers which are non-hairing at application temperature are disclosed. Examples of suitable mixtures of hydroxy functional polymers that can be used to form the prepolymers are:(1) linear polyester blends, comprising a first and second polyester wherein each polyester is the reaction product of a polyol and a polyacid, whereina+b or=6a+b>4 or .ltoreq.6, c+d>or=10a+b>6 or .ltoreq.8, c+d>or=12herein a is the number of methylene moieties in the polyol used to form the first polyester,b is the number of methylene moieties in the polyacid used to form the first polyester,c is the number of methylene moieties in the polyol used to form the second polyester of the blend,d is the number of methylene moieties in the polyacid used to form the second polyester of the blend; and(2) a blend of at least one non-linear polyester and one linear polyester, wherein the non-linear polyester is selected from the group consisting of polyneopentyl adipate, polypropylene adipate and polycyclohexanedimethyl adipate, and the linear polyester is selected from the group consisting of polyethylene adipate, polybutylene succinate, and polyhexamethylene sebacate, provided that when the linear polyester is polyhexamethylene sebacate, the non-linear polyester is polyneopentyl adipate or polypropylene adipate; and(3) a blend of poly .epsilon.-caprolactone and at least one linear polyester selected from the group consisting of polyethylene adipate, polyethylene succinate and polybutylene succinate.
摘要:
The present invention features ionomer compositions containing nanozirconia fillers. The compositions can be used in a variety of dental and orthodontic applications, for example, as adhesives, cements, restoratives, coatings and sealants.
摘要:
A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
摘要:
Dental crowns and bridges are made from thermoplastic molding compositions which are a mixture of thermoplastic material (for example, polycaprolactone), a free-radically polymerizable resin (for example, a urethane diacrylate oligomer), and free-radical initiator (for example, a visible-light cure photoinitiator). The mixture is solid at 38.degree. C., has a melting or softening point that comfortably can be withstood by oral tissues, and can be imprinted with a heat-stable custom shape memory and semi-thermoplastic properties by shaping the composition to a desired shape and then causing or permitting the resin to undergo polymerization.
摘要:
A blend of isocyanate-terminated polyurethane prepolymers is provided. The blend consists essentially of a first crystalline prepolymer based upon polyhexamethylene adipate and a second prepolymer based upon polytetramethylene ether glycol.
摘要:
A blend of isocyanate-terminated polyurethane prepolymers comprising: (a) a first prepolymer which comprises the reaction product of an at least essentially semicrystalline hydroxy-functional material and a polyisocyanate; (b) a second prepolymer which comprises the reaction product of a poly(tetramethylene glycol) ether and a polyisocyanate; and (c) a third prepolymer which comprises the reaction product of an essentially amorphous hydroxy-functional material and a polyisocyanate. The blend may also include a fourth prepolymer which comprises the reaction product of a slightly branched hydroxy-functional material and a polyisocyanate.
摘要:
The present invention features ionomer compositions containing nanofillers. The compositions can be used in a variety of dental and orthodontic applications, for example, as adhesives, cements, restoratives, coatings and sealants.
摘要:
A tackified composition comprising (a) a polydiorgannosiloxane polyurea segmented copolymer comprising the reaction product of (i) at least one polyaminie, wherein the polyamine comprises at least one polydiorganosiloxane diamine, or a mixture of at least one polydiorganosiloxane diamine and at least one organic polyamine, and (ii) at least one polyisocyanate, wherein the mol ratio of isocyanate to amined is between 0.9:1 and 0.95:1 or between 1.05:1 and about 1.3:1, and (b) silicate resins. The tackified compositions are useful as pressure sensitive adhesives, particularly for foamed backing tapes, medical tapes and the like, hot melt adhesives, vibration dampers, anti-corrosive materials.