公开(公告)号：US06563640B1

公开(公告)日：2003-05-13

申请号：US09720227

申请日：2001-04-02

Applicant: Leonid Y. Ignatov ,  Yuri A. Bobrov ,  Pavel I. Lazarev

Inventor： Leonid Y. Ignatov ,  Yuri A. Bobrov ,  Pavel I. Lazarev

IPC: G02B2728

CPC classification number: G02B5/3033 ,  G02B5/3016 ,  Y10S359/90

Abstract: The present invention relates to heat-resistant and plarizers that use thin films of dichroic organic substances, mainly dichroic dyes applied on the surface of rigid or flexible substrates in which the molecules of the dichroic organic substance are arranged in the form of a crystalline grid. The purpose of this invention is to widen the spectral range of the polarizer operation while improving polarization characteristics. This dichroic polarizer includes a film having a portion at least consisting of a crystalline structure that comprises at least one dichroic organic substance, wherein the molecules or molecule fragments of this substance have a planar morphology. The dichroic substance consists of a dichroic substance having at least one crest on the spectral absorption curve within spectral ranges of 400 to 700 nm and/or 200 to 400 nm and 0.7 to 13 &mgr;m. The order parameter of the film S is defined by the formula S=(D⊥−D∥)/(D⊥+2D∥) in which D⊥ and D∥ represent the optical density measured in the polarized light during the perpendicular and parallel orientations, respectively, of the polarizer polarization axis relative to the polarization plane of an electromagnetic radiation from a spectrometer. This parameter corresponds to at least one crest on the spectral absorption curve within a spectral range of 0.7 to 13 &mgr;m, and has a value not less than 0.8.

Abstract translation: 本发明涉及使用二色性有机物质的薄膜的耐热和稀释剂，主要是二色性染料，其应用于刚性或柔性基底的表面，其中二色性有机物质的分子以晶格形式排列。 本发明的目的是在改善偏振特性的同时拓宽偏振器操作的光谱范围。 该二向色偏振器包括具有至少由包含至少一种二色性有机物质的结晶结构的部分的膜，其中该物质的分子或分子片段具有平面形态。 二色性物质由在400至700nm和/或200至400nm和0.7至13μm的光谱范围内的光谱吸收曲线上具有至少一个峰的二色性物质组成。 膜S的阶数参数由公式S =（D⊥-D |）/（D⊥+ 2D |）定义，其中D⊥和D‖表示在垂直和平行的偏振光中测量的光密度 偏振器偏振轴相对于来自光谱仪的电磁辐射的偏振面的取向。 该参数对应于在0.7〜13μm的光谱范围内的光谱吸收曲线上的至少一个峰，并且具有不小于0.8的值。

公开(公告)号：US07031053B2

公开(公告)日：2006-04-18

申请号：US09792524

申请日：2001-02-23

Applicant: Yuri A. Bobrov ,  Leonid Y. Ignatov ,  Pavel I. Lazarev ,  Alla Y. Sakharova

Inventor： Yuri A. Bobrov ,  Leonid Y. Ignatov ,  Pavel I. Lazarev ,  Alla Y. Sakharova

IPC: G02B5/30 ,  G02B27/28

CPC classification number: G02B5/3033 ,  Y10T428/31515

Abstract: The invention pertains to thermo-resistant and light-resistant dichroic polarizers based on thin films of dichroic matters, in particular organic dyestuffs, in which molecules are ordered in a crystalline structure and applied on the surface of the substrate. The dichroic polarizer is characterized by the fact that it contains at least one anisotropically absorbing film comprised of oriented molecules. Anisotropically absorbing film is characterized by the fact that for the major axes of the ellipsoids of the real and imaginary parts of anisotropic refraction coefficient in the range of at least one absorption band of the following is true on the area with linear dimensions no less than the maximum wavelength: K1≧K2>K3 ( n 1 + n 2 ) 2 > n 3 where K1, K2, K3 and n1, n2, n3, are main values of the semiaxes of the ellipsoid representing the imaginary and real parts, accordingly, of the anisotropic refraction coefficient, and/or the anisotropically absorbing film is characterized by the fact that light transmission by two films with cross-oriented polarization axes does not increase at least in some range of wavelengths upon the deviation of its propagation from the normal to the polarizer plane.

公开(公告)号：US06846522B1

公开(公告)日：2005-01-25

申请号：US09407218

申请日：1999-09-27

Applicant: Yuri A. Bobrov ,  Leonid Y. Ignatov ,  Ir Gvon Khan

Inventor： Yuri A. Bobrov ,  Leonid Y. Ignatov ,  Ir Gvon Khan

IPC: B44F1/04 ,  B44F1/08 ,  G02B27/28 ,  G02B5/30 ,  G02F1/13 ,  G02F1/3335

CPC classification number: B44F1/04 ,  B44F1/08 ,  G02B27/28 ,  Y10S428/90 ,  Y10S428/913 ,  Y10T428/13 ,  Y10T428/8305

Abstract: A decorative material is disclosed which comprises two polarizers and at least one phase-shifting plate placed between the polarizers. Each polarizer has a controlled direction of polarization axis. The phase-shifting plate represents a continuous layer of an optically anisotropic material containing regions differing by optical properties.

Abstract translation: 公开了一种装饰材料，其包括两个偏振器和放置在偏振器之间的至少一个相移板。 每个偏振器具有受控的偏振轴方向。 相移板表示包含不同于光学性质的区域的光学各向异性材料的连续层。

公开(公告)号：US06399166B1

公开(公告)日：2002-06-04

申请号：US09171299

申请日：1999-04-23

Applicant: Ir Gvon Khan ,  Yuri A. Bobrov ,  Victor A. Bykov ,  Leonid Y. Ignatov ,  Pavel I. Lazarev

Inventor： Ir Gvon Khan ,  Yuri A. Bobrov ,  Victor A. Bykov ,  Leonid Y. Ignatov ,  Pavel I. Lazarev

IPC: C09K1960

CPC classification number: G02B5/3016 ,  Y10T428/1005 ,  Y10T428/1041

Abstract: A liquid crystal display has a first substrate plate and a second substrate plate, and a liquid crystal layer disposed between the plates. A polarizing coating, having molecules of one or more organic dyes capable of forming a lyotropic liquid crystalline phase, is formed overlying a selected surface of each plate. Orientation of the polarizing coating is obtained by applying a force to the dye molecules when in the liquid crystal phase and subsequently converting the liquid crystal phase to a solid film.

Abstract translation: 液晶显示器具有第一基板和第二基板，以及设置在板之间的液晶层。 具有能够形成溶致液晶相的一种或多种有机染料的分子的偏振涂层形成在每个板的选定表面上。 通过在液晶相中向染料分子施加力并随后将液晶相转化为固体膜，获得偏振涂层的取向。

公开(公告)号：US06174394B1

公开(公告)日：2001-01-16

申请号：US08998254

申请日：1997-12-24

Applicant: Khan Ir Gvon ,  Yuri A. Bobrov ,  Victor A. Bykov ,  Leonid Y. Ignatov ,  Tatiana D. Ivanova ,  Sergei I. Popov ,  Elena Y. Shishkina ,  Georgiy N. Vorozhtsov

Inventor： Khan Ir Gvon ,  Yuri A. Bobrov ,  Victor A. Bykov ,  Leonid Y. Ignatov ,  Tatiana D. Ivanova ,  Sergei I. Popov ,  Elena Y. Shishkina ,  Georgiy N. Vorozhtsov

IPC: B32B3500

CPC classification number: C09B5/62 ,  C09B5/56 ,  C09B7/10 ,  C09B35/039 ,  C09K19/60 ,  C09K19/606 ,  G02B5/3016 ,  G02F1/133528 ,  G02F1/133711

Abstract: Polarizing coatings are formed from dyestuffs which provide a stable liquid crystalline phase in a wide range of concentrations, temperatures and pH-values. Particles formed by aggregates of the liquid crystal molecules are oriented in a predetermined direction to polarize light. The stability of the liquid crystalline state allows orienting the particles by mechanical forces such as a shearing force applied when the liquid crystal (10) is spread on a support surface (20) by a knife-like doctor (90) or a tension deformation force acting on the meniscus of the liquid crystal deposited between two surfaces (20, 30) as the surfaces are peeled off one another. As a result, the polarizing coatings are formed in some embodiments by simple methods. In some embodiments, the polarizing coatings have a high lightfastness, a high thermal stability, and a high dichroic ratio.

Abstract translation: 偏光涂层由在宽范围的浓度，温度和pH值提供稳定的液晶相的染料形成。 由液晶分子的聚集体形成的颗粒沿预定方向取向以使光偏振。 液晶状态的稳定性允许通过诸如当液晶（10）通过刀状刮刀（90）在支撑表面（20）上展开的剪切力或张力变形力 当表面彼此剥离时，其作用在沉积在两个表面（20,30）之间的液晶的弯液面上。 结果，通过简单的方法在一些实施方案中形成了偏振涂层。 在一些实施方案中，偏振涂层具有高耐光性，高热稳定性和高二色性比。

公开(公告)号：US06049428A

公开(公告)日：2000-04-11

申请号：US836635

申请日：1997-08-04

Applicant: Ir G Khan ,  Yuri A. Bobrov ,  Leonid Y. Ignatov ,  Elena Y. Shishkina ,  Pavel I Lazarev ,  Alexey V. Kurbatov

Inventor： Ir G Khan ,  Yuri A. Bobrov ,  Leonid Y. Ignatov ,  Elena Y. Shishkina ,  Pavel I Lazarev ,  Alexey V. Kurbatov

IPC: C07C309/44 ,  C07C309/50 ,  C07D209/58 ,  C07D209/80 ,  C07D333/64 ,  C07D471/16 ,  C09B3/12 ,  C09B3/50 ,  C09B3/60 ,  C09B5/26 ,  C09B5/62 ,  C09B7/10 ,  C09B69/10 ,  G02B5/30 ,  C07C245/00 ,  C07D221/22 ,  C09B44/10

CPC classification number: C07D209/58 ,  C07C309/44 ,  C07C309/50 ,  C07D209/80 ,  C07D333/64 ,  C09B3/12 ,  C09B3/50 ,  C09B3/60 ,  C09B5/26 ,  C09B5/62 ,  C09B69/10 ,  C09B7/10 ,  C09K19/60 ,  G02B5/3033 ,  G02F1/133528

Abstract: The present invention provides dyes of formula I-XXXIV, described in detail below, and dichroic light polarizers based on the dyes. In the dichroic light polarizers of this invention the dye molecules are aggregated into particles oriented in a predetermined direction on a surface of a substrate to enable the dye to polarize light transmitted through the dye. In another embodiment, a dichroic light polarizer includes a molecularly oriented layer of an organic dye on a surface of a substrate. The layer has a non-periodic arrangement of different polarizing elements. Each of the polarizing elements have differing orientations of the polarization vector in the substrate plane and/or differing colors. The dichroic light polarizer may contain one or more additional dye layers and may have a transparent layer intermediate to the dye layer.

Abstract translation: PCT No.PCT / US95 / 14413 Sec。 371日期：1997年8月4日 102（e）日期1997年8月4日PCT提交1995年11月17日PCT公布。 出版物WO96 / 日期：1996年5月30日本发明提供了下面详细描述的式I-XXXIV的染料和基于染料的二色光偏振器。 在本发明的二向色光偏振器中，染料分子被聚集成在基板的表面上沿预定方向取向的颗粒，以使染料能够使透过染料的光偏振。 在另一个实施例中，二向色光偏振器包括在衬底的表面上的有机染料的分子取向层。 该层具有不同偏振元件的非周期性布置。 每个偏振元件在基板平面中具有不同的偏振矢量取向和/或不同的颜色。 二向色光偏振器可以包含一个或多个另外的染料层，并且可以具有在染料层中间的透明层。

公开(公告)号：US5739296A

公开(公告)日：1998-04-14

申请号：US556917

申请日：1995-11-20

Applicant: Khan Ir Gvon ,  Yuri A. Bobrov ,  Victor A. Bykov ,  Leonid Y. Ignatov ,  Tatiana D. Ivanova ,  Sergei I. Popov ,  Elena Y. Shishkina ,  Georgiy N. Vorozhtsov

Inventor： Khan Ir Gvon ,  Yuri A. Bobrov ,  Victor A. Bykov ,  Leonid Y. Ignatov ,  Tatiana D. Ivanova ,  Sergei I. Popov ,  Elena Y. Shishkina ,  Georgiy N. Vorozhtsov

IPC: C09K9/02 ,  C09B5/56 ,  C09B5/62 ,  C09B7/10 ,  C09B35/039 ,  C09B57/12 ,  C09K19/34 ,  C09K19/40 ,  C09K19/60 ,  G02B1/08 ,  G02B5/30 ,  G02F1/1335 ,  G02F1/1337 ,  C09B31/147 ,  C09B31/30 ,  C09B35/50 ,  C09K19/30 ,  C09K19/56

CPC classification number: C09B5/62 ,  C09B35/039 ,  C09B5/56 ,  C09B7/10 ,  C09K19/60 ,  C09K19/606 ,  G02B5/3016 ,  G02F1/133528 ,  G02F1/133711

Abstract: Polarizing coatings are formed from dyestuffs which provide a stable liquid crystalline phase in a wide range of concentrations, temperatures and pH-values. Particles formed by aggregates of the liquid crystal molecules are oriented in a predetermined direction to polarize light. The stability of the liquid crystalline state allows orienting the particles by mechanical forces such as a shearing force applied when the liquid crystal (10) is spread on a support surface (20) by a knife-like doctor (90) or a tension deformation force acting on the meniscus of the liquid crystal deposited between two surfaces (20, 30) as the surfaces are peeled off one another. As a result, the polarizing coatings are formed in some embodiments by simple methods. In some embodiments, the polarizing coatings have a high lightfastness, a high thermal stability, and a high dichroic ratio.

Abstract translation: PCT No.PCT / US94 / 05493 Sec。 371日期：1995年11月20日 102（e）1995年11月20日日期PCT 1994年5月20日PCT PCT。 公开号WO94 / 28073 日期1994年12月8日极化涂层由在宽浓度，温度和pH值范围内提供稳定液晶相的染料形成。 由液晶分子的聚集体形成的颗粒沿预定方向取向以使光偏振。 液晶状态的稳定性允许通过诸如当液晶（10）通过刀形刮刀（90）在支撑表面（20）上展开的剪切力或张力变形力 当表面彼此剥离时，其作用在沉积在两个表面（20,30）之间的液晶的弯液面上。 结果，通过简单的方法在一些实施方案中形成了偏振涂层。 在一些实施方案中，偏振涂层具有高耐光性，高热稳定性和高二色性比。