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公开(公告)号：US5851401A
公开(公告)日：1998-12-22
申请号：US853593
申请日：1997-05-09
CPC分类号： B01D15/08 , B01D15/36 , B01J20/286 , B01J20/3092 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3246 , G21F9/06 , G21F9/12 , G21F9/30 , B01J2220/54 , B01J2220/56
摘要： An extraction chromatographic material for extracting metal cations from a liquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support.
摘要翻译： 用于从液体流中提取金属阳离子的提取色谱材料。 萃取色谱材料通过将二酯化甲基二膦酸吸附在惰性颗粒载体上来制备。
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公开(公告)号：US5346618A
公开(公告)日：1994-09-13
申请号：US51608
申请日：1993-04-23
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： B01D15/00 , B01D15/08 , B01J20/281 , C01F11/00 , C07D323/00 , G01N30/50 , G01N30/88 , G21F9/06
CPC分类号： B01D15/08 , G21F9/06 , Y10S423/14 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.
摘要翻译： 描述了使用色谱柱从生物，工业和环境样品溶液中提取锶和锝值的方法和装置。 通过产生含有冠醚的稀释剂溶液并将溶液分散在树脂基材上制备柱的萃取剂介质。 样品溶液是高度酸性的并被导入色谱柱，并使用去离子水洗脱锶或锝。
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公开(公告)号：US08507284B2
公开(公告)日：2013-08-13
申请号：US13182873
申请日：2011-07-14
CPC分类号： B01D15/1871 , B01D15/363 , B01D15/3847 , C01F11/005 , C01F11/36 , G01N33/493 , G01N33/84
摘要： The present invention provides an apparatus and rapid methods for extracting strontium ions from urine to provide a concentrated and purified strontium-90 extract suitable for scintillation measurements. The methods remove organic compounds, pigments, and alkali metal ions that can interfere with quantitative determination of strontium-90 in urine. A method of the invention comprises acidifying urine and removing organic pigments therefrom, loading a known quantity of so-treated urine onto a diphosphonic acid-based ion-exchange resin; flowing aqueous methanesulfonic acid through the diphosphonic acid-based ion-exchange resin to elute alkali metal ions therefrom; eluting strontium ions off of the diphosphonic acid-based resin and on to a strontium extraction chromatographic resin with a concentrated aqueous nitric acid solution; subsequently flowing water or a dilute acid stripping solution through the strontium extraction resin to strip the strontium from the strontium extraction resin; and collecting the strontium-containing stripping solution eluting from the strontium extraction resin.
摘要翻译： 本发明提供了一种用于从尿提取锶离子以提供适用于闪烁测量的浓缩和纯化的锶-90提取物的装置和快速方法。 这些方法可以去除可能干扰尿液中锶-90的定量测定的有机化合物，颜料和碱金属离子。 本发明的方法包括酸化尿液并从其中除去有机颜料，将已知量的如此处理的尿液加载到基于二膦酸的离子交换树脂上; 通过二膦酸离子交换树脂将甲磺酸水溶液从其中洗脱出碱金属离子; 从二膦酸类树脂中洗脱锶离子，并用浓硝酸水溶液萃取锶萃取色谱树脂; 随后将水或稀酸剥离溶液通过锶萃取树脂从锶萃取树脂中剥离锶; 并收集从锶萃取树脂洗脱的含锶剥离液。
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公开(公告)号：US5344623A
公开(公告)日：1994-09-06
申请号：US76881
申请日：1993-06-15
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
摘要： The invention is a process for selectively extracting strontium values from aqueous nitric acid waste solutions containing these and other fission product values. The extractant solution is a macrocyclic polyether in an aliphatic hydrocarbon diluent containing a phase modifier. The process will selectively extract strontium values from nitric acid solutions which are up to 6 molar in nitric acid.
摘要翻译： 本发明是从含有这些和其它裂变产物值的含水硝酸废液中选择性提取锶值的方法。 萃取剂溶液是含有相改性剂的脂族烃稀释剂中的大环聚醚。 该方法将选择性地从在硝酸中高达6摩尔的硝酸溶液中提取锶值。
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公开(公告)号：US20130017613A1
公开(公告)日：2013-01-17
申请号：US13182873
申请日：2011-07-14
CPC分类号： B01D15/1871 , B01D15/363 , B01D15/3847 , C01F11/005 , C01F11/36 , G01N33/493 , G01N33/84
摘要： The present invention provides an apparatus and rapid methods for extracting strontium ions from urine to provide a concentrated and purified strontium-90 extract suitable for scintillation measurements. The methods remove organic compounds, pigments, and alkali metal ions that can interfere with quantitative determination of strontium-90 in urine. A method of the invention comprises acidifying urine and removing organic pigments therefrom, loading a known quantity of so-treated urine onto a diphosphonic acid-based ion-exchange resin; flowing aqueous methanesulfonic acid through the diphosphonic acid-based ion-exchange resin to elute alkali metal ions therefrom; eluting strontium ions off of the diphosphonic acid-based resin and on to a strontium extraction chromatographic resin with a concentrated aqueous nitric acid solution; subsequently flowing water or a dilute acid stripping solution through the strontium extraction resin to strip the strontium from the strontium extraction resin; and collecting the strontium-containing stripping solution eluting from the strontium extraction resin.
摘要翻译： 本发明提供了一种用于从尿提取锶离子以提供适用于闪烁测量的浓缩和纯化的锶-90提取物的装置和快速方法。 这些方法可以去除可能干扰尿液中锶-90的定量测定的有机化合物，颜料和碱金属离子。 本发明的方法包括酸化尿液并从其中除去有机颜料，将已知量的如此处理的尿液加载到基于二膦酸的离子交换树脂上; 通过二膦酸离子交换树脂将甲磺酸水溶液从其中洗脱出碱金属离子; 从二膦酸类树脂中洗脱锶离子，并用浓硝酸水溶液萃取锶萃取色谱树脂; 随后将水或稀酸剥离溶液通过锶萃取树脂从锶萃取树脂中剥离锶; 并收集从锶萃取树脂洗脱的含锶剥离液。
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公开(公告)号：US07211231B2
公开(公告)日：2007-05-01
申请号：US10354929
申请日：2003-01-30
CPC分类号： G21G4/08 , Y10S423/07
摘要： A bismuth-213 generator comprising an insoluble composition having the general formula Zr(Phosponate)x(HPO4)2−x.nH2O, wherein x is between 0 and 2; and n is the number of waters of hydration; and wherein cations of radioactive isotopes selected from radium, actinium and combinations thereof are immobilized on the composition. The value of x may be between about 0.2 and about 1. The phosphonate may be n-phosphonomethyl-miniodiacetic acid (PMIDA), wherein x may be between about 0.1 and about 1.9. The phosphonate may be one or more phosphonate having the formula: H2O3P—(CH2)a—N—((CH2)bCO2H)—((CH2)cCO2H), wherein a, b, and c are numbers from 1 to 3 that may or may not be equal. The value of x may also be between about 0.1 and 1.9.
摘要翻译： 一种铋-213发生器，其包含具有通式Zr（磷酸酯）x（HPO 2）2-x N）的不溶性组合物。 > 2 O，其中x在0和2之间; n是水合水的数量; 并且其中选自镭，锕及其组合的放射性同位素的阳离子固定在组合物上。 x的值可以在约0.2和约1之间。膦酸酯可以是正膦酰基甲基 - 次碘酸（PMIDA），其中x可以在约0.1和约1.9之间。 膦酸酯可以是一种或多种具有下式的膦酸酯：<？in-line-formula description =“In-line Formulas”end =“lead”？> H （CH 2）2 - （（CH 2）2）b - 2 H） - （（CH 2）2 CO 2 H），<β在线公式描述=“ 在线公式“end =”tail“？>其中a，b和c是可以相同也可以不相等的从1到3的数字。 x的值也可以在约0.1和1.9之间。
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7.发明授权
公开(公告)号：US5110474A
公开(公告)日：1992-05-05
申请号：US507419
申请日：1990-04-09
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
IPC分类号： B01D15/00 , B01D15/08 , B01J20/281 , C01F11/00 , C07D323/00 , G01N30/50 , G01N30/88 , G21F9/06
CPC分类号： B01D15/08 , G21F9/06 , Y10S423/14 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998
摘要： A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.
摘要翻译： 描述了使用色谱柱从生物，工业和环境样品溶液中提取锶和锝值的方法和装置。 通过产生含有冠醚的稀释剂溶液并将溶液分散在树脂基材上制备柱的萃取剂介质。 样品溶液是高度酸性的并被导入色谱柱，并使用去离子水洗脱锶或锝。
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公开(公告)号：US5651883A
公开(公告)日：1997-07-29
申请号：US467402
申请日：1995-06-06
CPC分类号： B01D15/08 , B01D15/36 , B01J20/286 , B01J20/3092 , B01J20/3204 , B01J20/321 , B01J20/3212 , B01J20/3246 , G21F9/06 , G21F9/12 , G21F9/30 , B01J2220/54 , B01J2220/56
摘要： An extraction chromatographic material for extracting metal cations from aiquid stream. The extraction chromatographic material is prepared by adsorbing a diesterified methanediphosphonic acid on an inert particulate support.
摘要翻译： 用于从液体流中提取金属阳离子的提取色谱材料。 萃取色谱材料通过将二酯化甲基二膦酸吸附在惰性颗粒载体上来制备。
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9.发明授权Process for the separation and purification of yttrium-90 for medical applications 失效用于医疗应用的钇-90分离和纯化方法
公开(公告)号：US5368736A
公开(公告)日：1994-11-29
申请号：US95555
申请日：1993-07-26
申请人： Philip E. Horwitz , Mark L. Dietz
发明人： Philip E. Horwitz , Mark L. Dietz
CPC分类号： G21G1/001 , C01F17/0006 , C22B59/00 , G21G2001/0094
摘要： An extraction chromatographic method for the preparation of .sup.90 Y of high chemical and radiochemical purity is disclosed. After an initial purification of a .sup.90 Sr stock solution and a suitable period of .sup.90 Y ingrowth, the solution is passed through a series of strontium-selective chromatographic columns, each of which lowers the .sup.90 Sr content of the mixture by a factor of about 10.sup.3. The .sup.90 Y remaining is freed from any residual .sup.90 Sr, from its .sup.90 Zr daughter, and from any remaining impurities by passing the sample through a final column designed to selectively retain yttrium.
摘要翻译： 公开了用于制备高化学和放射化学纯度的90Y的提取色谱方法。 在初始纯化90Sr储备溶液和合适的90Y向内生长期后，溶液通过一系列锶选择性色谱柱，每个色谱柱将混合物的90Sr含量降低约103倍。90Y 残余物从其90Zr的子体中除去任何残留的90Sr，并通过将样品通过设计成选择性保留钇的最终色谱柱从任何剩余的杂质中除去。
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10.发明授权Method for the concentration and separation of actinides from biological and environmental samples 失效从生物和环境样品中浓缩和分离锕系元素的方法
公开(公告)号：US4835107A
公开(公告)日：1989-05-30
申请号：US921282
申请日：1986-10-21
申请人： E. Philip Horwitz , Mark L. Dietz
发明人： E. Philip Horwitz , Mark L. Dietz
CPC分类号： G21F9/007 , C01G56/001 , C22B3/0043 , C22B3/24 , Y02P10/234 , Y10T436/25125
摘要： A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting.
摘要翻译： 通过将适当制备的样品通过溶解在三正丁基中的二烷基（苯基）-N，N-二甲酰基氨基甲酰基甲基氧化膦的分离柱，在无机酸溶液中通过适当制备的样品定量回收生物和环境样品中锕系元素值的方法和装置。 磷酸盐在选择性提取锕系元素值的惰性底物上。 锕系元素值可以作为一组或单独洗脱，并通过α计数定量检测其存在。
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