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    Deposition processes using group 8 (VIII) metallocene precursors
    4.
    发明授权
    Deposition processes using group 8 (VIII) metallocene precursors 有权
    使用第8（VIII）族茂金属前体的沉积方法

    公开(公告)号：US07927658B2

    公开(公告)日：2011-04-19

    申请号：US10685785

    申请日：2003-10-16

    申请人： David M. Thompson ,  Cynthia A. Hoover ,  John D. Peck ,  Michael M. Litwin

    发明人： David M. Thompson ,  Cynthia A. Hoover ,  John D. Peck ,  Michael M. Litwin

    IPC分类号： C23C16/06

    CPC分类号： C23C16/406 ,  C23C16/18 ,  C23C16/40

    摘要： Disclosed herein is a process for producing a film, coating or powder employing a metallocene or metallocene-like precursor having the general formula CpMCp′, where M is a metal selected from the group consisting of Ru, Os and Fe; Cp is a first substituted cyclopentadienyl or cyclopentadienyl-like, e.g., indenyl, moiety that includes at least one substituent group D1, where D1 is X; Ca1Hb1Xc1; Ca2Hb2Xc2(C═O)Ca1Hb1Xc1; Ca2Hb2Xc2OCa1Hb1Xc1; Ca2Hb2Xc2(C═O)OCa1Hb1Xc1; or Ca2Hb2Xc2O(C═O)Ca1Hb1Xc1; and Cp′ is a second substituted cyclopentadienyl or cyclopentadienyl-like, e.g., indenyl, moiety that includes at least one substituent group D1′, where D1′ is X; Ca1Hb1Xc1; Ca2Hb2Xc2(C═O)Ca1Hb1Xc1; Ca2Hb2Xc2OCa1Hb1Xc1; Ca2Hb2Xc2(C═O)OCa1Hb1Xc1; or Ca2Hb2Xc2O(C═O)Ca1Hb1Xc1. D1 and D1′ are different from one another. X is a halogen atom or NO2; a1 is an integer between 1 to 8; b1 is an integer between 0 and 2(a1)+1−c1; c1 is an integer between 0 and 2(a1)+1−b1; b1+c1 is at least 1; a2 is an integer between 0 and 8; b2 is an integer between 0 and 2(a2)+1−c2; and c2 is an integer between 0 and 2(a2)+1−b2. The process can be used in manufacturing or processing electronic devices.

    摘要翻译： 本文公开了使用具有通式CpMCp'的茂金属或茂金属样前体制备膜，涂层或粉末的方法，其中M是选自Ru，Os和Fe的金属; Cp是包括至少一个取代基组D1的第一取代的环戊二烯基或环戊二烯基，例如茚基，部分，其中D1是X; Ca1Hb1Xc1; Ca2Hb2Xc2（C = O）Ca1Hb1Xc1; Ca2Hb2Xc2OCa1Hb1Xc1; Ca2Hb2Xc2（C = O）OCa1Hb1Xc1; 或Ca2Hb2Xc2O（C = O）Ca1Hb1Xc1; 并且Cp'是包含至少一个取代基组D1'的第二取代的环戊二烯基或环戊二烯基，例如茚基，部分，其中D1'是X; Ca1Hb1Xc1; Ca2Hb2Xc2（C = O）Ca1Hb1Xc1; Ca2Hb2Xc2OCa1Hb1Xc1; Ca2Hb2Xc2（C = O）OCa1Hb1Xc1; 或Ca2Hb2Xc2O（C = O）Ca1Hb1Xc1。 D1和D1'彼此不同。 X是卤素原子或NO 2; a1是1〜8之间的整数; b1是0和2（a1）+ 1-c1之间的整数; c1是0和2（a1）+ 1-b1之间的整数; b1 + c1至少为1; a2是0和8之间的整数; b2是0和2（a2）+ 1-c2之间的整数; c2为0〜2（a2）+ 1-b2之间的整数。 该方法可用于制造或处理电子设备。

    OXYGEN TRANSPORT MEMBRANE BASED ADVANCED POWER CYCLE WITH LOW PRESSURE SYNTHESIS GAS SLIP STREAM
    5.
    发明申请
    OXYGEN TRANSPORT MEMBRANE BASED ADVANCED POWER CYCLE WITH LOW PRESSURE SYNTHESIS GAS SLIP STREAM 有权
    基于氧气运输膜的高压合成气循环系统

    公开(公告)号：US20140183866A1

    公开(公告)日：2014-07-03

    申请号：US14138619

    申请日：2013-12-23

    申请人： Brian R. Kromer ,  Michael M. Litwin ,  Sean M. Kelly

    发明人： Brian R. Kromer ,  Michael M. Litwin ,  Sean M. Kelly

    IPC分类号： F23L7/00 ,  H02K7/18 ,  F01K23/16 ,  F23L15/04 ,  F01K7/16 ,  F01K13/00

    CPC分类号： F23L7/007 ,  F01K7/16 ,  F01K13/006 ,  F01K23/067 ,  F01K23/16 ,  F23C2900/99011 ,  F23L15/04 ,  Y02E20/18 ,  Y02E20/344 ,  Y02E20/348

    摘要： A method and system for generating electrical power is provided in which a high pressure synthesis gas stream generated in a gasifier is partially oxidized in an oxygen transport membrane based reactor, expanded and thereafter, is combusted in an oxygen transport membrane based boiler. A low pressure synthesis gas slip stream is split off downstream of the expanders and used as the source of fuel in the oxygen transport membrane based partial oxidation reactors to allow the oxygen transport membrane to operate at low fuel pressures with high fuel utilization. The combustion within the boiler generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

    摘要翻译： 提供了一种用于产生电力的方法和系统，其中在气体发生器中产生的高压合成气流在基于氧传输膜的反应器中部分氧化，然后膨胀，然后在基于氧传输膜的锅炉中燃烧。 低压合成气滑流在膨胀机的下游被分流，并用作基于氧传输膜的部分氧化反应器中的燃料源，以允许氧输送膜在具有高燃料利用率的低燃料压力下操作。 锅炉内的燃烧产生热量以升高蒸汽，从而通过联接到蒸汽轮机的发电机发电。 所得烟道气可以被纯化以产生二氧化碳产物。

    Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream
    8.
    发明授权
    Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream 有权
    氧传输膜基于先进的动力循环与低压合成气滑流

    公开(公告)号：US09453644B2

    公开(公告)日：2016-09-27

    申请号：US14138619

    申请日：2013-12-23

    申请人： Brian R. Kromer ,  Michael M. Litwin ,  Sean M. Kelly

    发明人： Brian R. Kromer ,  Michael M. Litwin ,  Sean M. Kelly

    IPC分类号： F23L7/00 ,  F01K13/00 ,  F01K23/16 ,  F01K7/16 ,  F23L15/04 ,  F01K23/06

    CPC分类号： F23L7/007 ,  F01K7/16 ,  F01K13/006 ,  F01K23/067 ,  F01K23/16 ,  F23C2900/99011 ,  F23L15/04 ,  Y02E20/18 ,  Y02E20/344 ,  Y02E20/348

    摘要： A method and system for generating electrical power in which a high pressure synthesis gas stream generated in a gasifier is partially oxidized in an oxygen transport membrane based reactor, expanded and thereafter, is combusted in an oxygen transport membrane based boiler. A low pressure synthesis gas slip stream is split off downstream of the expanders and used as the source of fuel in the oxygen transport membrane based partial oxidation reactors to allow the oxygen transport membrane to operate at low fuel pressures with high fuel utilization. The combustion within the boiler generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

    摘要翻译： 一种用于产生电功率的方法和系统，其中在气体发生器中产生的高压合成气流在基于氧传输膜的反应器中部分氧化并膨胀，然后在基于氧传输膜的锅炉中燃烧。 低压合成气滑流在膨胀机的下游被分流，并用作基于氧传输膜的部分氧化反应器中的燃料源，以允许氧输送膜在具有高燃料利用率的低燃料压力下操作。 锅炉内的燃烧产生热量以升高蒸汽，从而通过联接到蒸汽轮机的发电机发电。 所得烟道气可以被纯化以产生二氧化碳产物。