摘要:
Process for the preparation of alkylated N- or amino, ammonium or spirobicyclic ammonium group-containing, crosslinked polymer gels, which is characterized in that a) in the crosslinkage step an aqueous solution of a polymer obtained by polymerization of the corresponding monomer is adjusted to a pH of 7.5–14 at a temperature of 0 to 90° C., then the appropriate crosslinking agent is metered in and precrosslinkage is carried out with stirring and the precrosslinked polymer is transferred for complete curing to a curing container, whereupon b) the cured crude gel is cut into a defined shape, then c) washed with methanol batchwise in a static or stirred bed and directly following this d) in methanol, the alkylation is carried out, after which the alkylated gel e) is first washed batchwise by means of methanol/NaCl washes in a static or stirred bed or continuously, then f) batchwise by means of NaCl washes and final water washes with deionized water in a static or stirred bed or continuously and also a process for the preparation of the alkylators used in sted d).
摘要:
Process for the drying of polymers containing N or amino, ammonium or spirobicyclic ammonium groups, comprising cationic N-containing groups, and suitable counterions, in which the gelled and washed polymers obtained by polymerization, crosslinkage and optionally alkylation are dried continuously using a gaseous medium under normal pressure or overpressure in a fluidized bed.
摘要:
A box bracket assembly including a box and an insert for protecting and holding a bottle securely within the box. The insert includes vertical support panels having apertures for holding the bottle. Support aperture edges hold the bottle in place centrally in an inner cavity between the support panels. The support apertures are formed in two parallel support panels. Support panels may be linked by a base. Extending from the sides of the support panels are brackets which fold along a bracket hinge to form a 90° angle with the support panels. Once folded and inserted into the box, the sides of the brackets are parallel and in contact with the sides of the box and the edges of the brackets contact the perpendicular sides of the box, such that the insert and the bottle are immobilized within the box.
摘要:
Improved method of production of 9-(Z)-retinoic acid, in which a) a β-formyl-crotonic acid C1-C10 alkyl or phenyl ester is reacted with an isolated 9-(Z)—C15-triarylphosphonium salt by the Wittig reaction in the presence of a base to the corresponding 9-(Z)-retinoic acid ester; which b) is then saponified with a base to the corresponding 9-(Z)-retinoic acid carboxylate and then, following protonation with an acid, the desired 9-(Z)-retinoic acid is obtained, and improved method for the enrichment and isolation of the 9-(Z)—C15-triarylphosphonium salt.
摘要:
A method and an apparatus are disclosed for disconnection of a fault current which has occurred in an AC power supply system. A disconnection command which is produced in a protective device is supplied to a synchronization controller in order to open a circuit breaker, in which synchronization controller a command is delayed until the circuit breaker can be opened in synchronism with the power supply system. The method includes monitoring of the disconnection command emitted from the protective device and monitoring a fault-current signal, or a status signal emitted from the circuit breaker, and formation of an emergency disconnection command if the fault-current signal or the status signal is still present following a delay time after emission of the disconnection command, which delay time is greater than a sum of a natural response time of the circuit breaker and a time for quenching of a switching arc produced on opening of the circuit breaker.
摘要:
The invention relates to a washing process for cleaning polymers containing N or amine, ammonium or spirobicyclic ammonium groups, comprising cationic groups containing N, in addition to suitable counterions, whereby the gelled-out polymers are obtained through polymerization and cross-linking by a) adding a base which is partially or fully deprotonated, b) the partially or fully deprotonated polymers are washed, then c) optionally, are reprotonated in an organic solvent or in an organic solvent/water mixture by adding an acid, whereupon d) optionally, they are washed in an organic solvent or an organic solvent/water mixture in order to shrink the gels and optionally, e) in connection with step c) or d), the steps a)-c) or -d) are repeated.
摘要:
Improved method of production of 9-(Z)-retinoic acid, in which a) a β-formyl-crotonic acid C1-C10 alkyl or phenyl ester is reacted with an isolated 9-(Z)—C15-triarylphosphonium salt by the Wittig reaction in the presence of a base to the corresponding 9-(Z)-retinoic acid ester; which b) is then saponified with a base to the corresponding 9-(Z)-retinoic acid carboxylate and then, following protonation with an acid, the desired 9-(Z)-retinoic acid is obtained, and improved method for the enrichment and isolation of the 9-(Z)—C15-triarylphosphonium salt.
摘要:
The present invention relates to a process for the preparation of the compound of formula (7) which process comprises the hydrogenation of the compound of formula (4) using bis[chloro-1,5-cyclooctadiene-iridium], (S)-i-dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]-ferrocene as a catalyst.