Photocurable thermosettting resin composition developable with aqueous
alkali solution
    1.
    发明授权
    Photocurable thermosettting resin composition developable with aqueous alkali solution 失效
    光固化热固性树脂组合物,可用碱性水溶液显影

    公开(公告)号:US5948514A

    公开(公告)日:1999-09-07

    申请号:US658446

    申请日:1996-06-05

    摘要: A photocurable and thermosetting resin composition developable with an aqueous alkali solution is disclosed. The composition comprises in combination: (A) a photosensitive prepolymer soluble in a dilute aqueous alkali solution obtained by esterifying an epoxy resin represented by the following general formula (1) with (meth)acrylic acid and further adding an acid anhydride thereto until an acid value reaches a level in the range of 60 to 120 mg KOH/g, (B) a diglycidyl ether type epoxy compound containing two epoxy groups in the molecular unit thereof, (C) a photopolymerization initiator, and (D) a diluent at such ratios of combination that said epoxy compound (B) accounts for a proportion in the range of 5 to 120 parts by weight and said photopolymerization initiator (C) for a proportion in the range of 0.1 to 30 parts by weight, based on 100 parts by weight of said photosensitive prepolymer (A): ##STR1## wherein X represents CH.sub.2, C(CH.sub.3).sub.2, or SO.sub.2, n is an average value in the range of 1 to 12, and Y represents a hydrogen atom or a glycidyl group, providing that Y is a glycidyl group where n is 1 and at least one of the plurality of Y's is a glycidyl group where n is 2 or more.

    摘要翻译: 公开了一种用碱性水溶液显影的可光固化和热固性树脂组合物。 该组合物组合包括:(A)可溶于通过将由以下通式(1)表示的环氧树脂与(甲基)丙烯酸酯化并进一步加入酸酐得到的稀碱水溶液的光敏预聚物,直到酸 值达到60〜120mg KOH / g的范围内的水平,(B)分子单元中含有2个环氧基的二缩水甘油醚型环氧化合物,(C)光聚合引发剂,(D)稀释剂 所述环氧化合物(B)的组合比例在5〜120重量份的范围内,所述光聚合引发剂(C)的比例为0.1〜30重量份,相对于100重量份 所述光敏预聚物(A)的重量:其中X表示CH 2,C(CH 3)2或SO 2,n是1至12的平均值,Y表示氢原子或缩水甘油基,条件是Y 是n为1的缩水甘油基和a 多个Y中的至少一个Y是n为2以上的缩水甘油基。