公开(公告)号：US07153413B2

公开(公告)日：2006-12-26

申请号：US09901939

申请日：2001-07-10

申请人： Terry G. Roberie ,  Ranjit Kumar ,  Michael S Ziebarth ,  Wu-Cheng Cheng ,  Xinjin Zhao ,  Nazeer Bhore

发明人： Terry G. Roberie ,  Ranjit Kumar ,  Michael S Ziebarth ,  Wu-Cheng Cheng ,  Xinjin Zhao ,  Nazeer Bhore

IPC分类号： C10G11/18

CPC分类号： C10G11/05 ,  C10G11/02

摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, is reduced in a catalytic cracking process employing a cracking catalyst containing a high content of vanadium. The cracking process involves introducing at least one vanadium compound into a hydrocarbon-sulfur containing feedstock to be charged to a fluid catalytic cracking reactor operating under steady state conditions and containing an equilibrium fluid cracking catalyst inventory within the reactor. The amount of sulfur in the liquid products, in particular gasoline and LCO fractions, is reduced as a result of the increased vanadium content on the equilibrium catalyst. Advantageously, sulfur reduction is achieved even in the presence of other metal contaminants, such as nickel and iron, on the equilibrium catalyst.

摘要翻译： 在使用含钒量高的裂化催化剂的催化裂化过程中，液体裂解产物，特别是裂化汽油的硫含量降低。 裂解过程包括将至少一种钒化合物引入含烃 - 硫的原料中，以将其装入在稳态条件下运行并在反应器内含有平衡流体裂解催化剂存量的流化催化裂化反应器。 由于在平衡催化剂上的钒含量增加，液体产物中的硫的量，特别是汽油和LCO馏分的量减少。 有利的是，即使在平衡催化剂上存在其它金属污染物如镍和铁的情况下也能实现硫还原。

公开(公告)号：US06482315B1

公开(公告)日：2002-11-19

申请号：US09649627

申请日：2000-08-28

申请人： Terry G. Roberie ,  Ranjit Kumar ,  Michael Scott Ziebarth ,  Wu-Cheng Cheng ,  Xinjin Zhao ,  Nazeer Bhore

发明人： Terry G. Roberie ,  Ranjit Kumar ,  Michael Scott Ziebarth ,  Wu-Cheng Cheng ,  Xinjin Zhao ,  Nazeer Bhore

IPC分类号： C10G2904

CPC分类号： C10G11/05 ,  C10G11/02 ,  C10G11/18 ,  C10G2300/202 ,  C10G2300/4093 ,  C10G2300/70 ,  C10G2300/80 ,  C10G2400/02 ,  C10L1/06

摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction additive comprising a non-molecular sieve support containing a high content of vanadium. Preferably, the support is alumina. The sulfur reduction catalyst is used in the form of a separate particle additive in combination with the active catalytic cracking catalyst (normally a faujasite such as zeolite Y) to process hydrocarbon feedstocks in the fluid catalytic cracking (FCC) unit to produce low-sulfur gasoline and other liquid products.

摘要翻译： 通过使用包含含有高含量钒的非分子筛载体的硫还原添加剂，催化裂化过程的液体裂解产物，特别是裂化汽油的硫含量降低。 优选地，载体是氧化铝。 硫还原催化剂以单独的颗粒添加剂的形式与活性催化裂化催化剂（通常为八面沸石如沸石Y）结合使用以处理流化催化裂化（FCC）单元中的烃原料以产生低硫汽油 和其他液体产品。