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    Gasoline sulfur reduction in fluid catalytic cracking
    1.
    发明授权
    Gasoline sulfur reduction in fluid catalytic cracking 有权
    汽油硫化液流化催化裂化

    公开(公告)号：US07452839B2

    公开(公告)日：2008-11-18

    申请号：US11013481

    申请日：2004-12-16

    Applicant: Wu-Cheng Cheng ,  Terry G. Roberie ,  Hye Kyung Cho Timken ,  Scott Kevin Purnell ,  Xinjin Zhao

    Inventor： Wu-Cheng Cheng ,  Terry G. Roberie ,  Hye Kyung Cho Timken ,  Scott Kevin Purnell ,  Xinjin Zhao

    IPC: B01J29/06

    CPC classification number: C10G11/05 ,  B01J29/072 ,  B01J29/076 ,  B01J29/166 ,  B01J2229/42

    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.

    Abstract translation: 通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属 筛子的结构以及提高裂化催化剂的裂解活性的稀土成分。 分子筛通常是诸如USY的八面沸石。 初级硫还原组分通常是元素周期3的金属，优选为钒。 稀土组分优选包括提高催化剂的硫还原活性的铈。 硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

    Zeolite GZS-11 and its dynamic preparation process
    2.
    发明授权
    Zeolite GZS-11 and its dynamic preparation process 失效
    沸石GZS-11及其动态制备工艺

    公开(公告)号：US5626828A

    公开(公告)日：1997-05-06

    申请号：US324949

    申请日：1994-10-18

    Applicant: Jianxin Wu ,  Robert R. Gatte ,  Terry G. Roberie

    Inventor： Jianxin Wu ,  Robert R. Gatte ,  Terry G. Roberie

    IPC: B01J29/04 ,  B01J29/70 ,  C01B39/48

    CPC classification number: B01J29/04 ,  B01J29/70 ,  B01J29/7007 ,  C01B39/48 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  Y10S423/27

    Abstract: A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :w H.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of +3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of +4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the as-synthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.

    Abstract translation: 制备具有由下式表示的摩尔组成的合成沸石GZS-11：[x M2 / nO +（1.0 +/- 0.2-x）R 2 / nO]：Y 2 O 3：y XO 2 :WH 2 O其中M是 无机阳离子n，R是价数n的有机阳离子，“x”的值小于1.0，Y是+3价元素中的一种或多种，​​如铝，硼，镓，铁，铬，钒 ，钼或锰，X是+4价元素中的一种或多种，​​例如硅，锗或钛，“y”的值在6至25之间，“w”的值取决于4 沸石的水合程度，并且具有基本上如表1所示的合成沸石的X射线衍射图。用于制备SiO 2 / Al 2 O 3的低比例的SiO 2 / Al 2 O 3的方法是通过调节合成 通过添加一种或多种含有沸石组分的反应性源的溶液在老化阶段期间的混合物组成。

    High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith
    3.
    发明授权
    High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith 有权
    高沸石含量和耐磨耗催化剂，其制备方法和催化方法

    公开(公告)号：US06916757B2

    公开(公告)日：2005-07-12

    申请号：US10151560

    申请日：2002-05-20

    Applicant: Michael S. Ziebarth ,  Terry G. Roberie ,  Philip S. Deitz

    Inventor： Michael S. Ziebarth ,  Terry G. Roberie ,  Philip S. Deitz

    IPC: B01J27/14 ,  B01J29/40 ,  B01J37/00 ,  B01J29/06

    CPC classification number: B01J29/40 ,  B01J27/14 ,  B01J37/0045 ,  B01J2229/26 ,  B01J2229/42

    Abstract: A catalyst composition suitable for reacting hydrocarbons, e.g., conversion processes such as fluidized catalytic cracking (FCC) of hydrocarbons, comprises attrition resistant particulate having a high level (30-85%) of stabilized zeolites having a constraint index of 1 to 12. The stabilized zeolite is bound by a phosphorous compound, alumina and optional binders wherein the alumina added to make the catalyst is about 10% by weight or less and the molar ratio of phosphorous (P2O5) to total alumina is sufficient to obtain an attrition index of about 20 or less. The composition can be used as a catalyst per se or as additive catalyst to a conventional catalyst and is especially suitable for enhancing yields of light olefins, and particularly ethylene, produced during conversion processes.

    Abstract translation: 适用于使烃类反应的催化剂组合物，例如转化过程如烃类的流化催化裂化（FCC），包括具有约1到12的约定指数的稳定沸石的高水平（30-85％）的耐磨颗粒。 稳定的沸石由磷化合物，氧化铝和任选的粘合剂结合，其中加入的氧化铝制成催化剂的量为约10重量％或更少，磷的摩尔比（P 总氧化铝足以获得约20或更小的磨耗指数。 该组合物本身可用作催化剂或作为常规催化剂的添加剂催化剂，特别适用于提高转化过程中产生的轻质烯烃，特别是乙烯的产率。

    Catalytic cracking utilizing a catalyst comprising zeolite GZS-11
    5.
    发明授权
    Catalytic cracking utilizing a catalyst comprising zeolite GZS-11 失效
    使用包含沸石GZS-11的催化剂进行催化裂化

    公开(公告)号：US5582713A

    公开(公告)日：1996-12-10

    申请号：US470156

    申请日：1995-06-06

    Applicant: Jianxin Wu ,  Robert R. Gatte ,  Terry G. Roberie

    Inventor： Jianxin Wu ,  Robert R. Gatte ,  Terry G. Roberie

    IPC: B01J29/04 ,  B01J29/70 ,  C01B39/48 ,  C10G11/02

    CPC classification number: B01J29/04 ,  B01J29/70 ,  B01J29/7007 ,  C01B39/48 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  Y10S423/27

    Abstract: A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :wH.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of+3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of+4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the assynthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.

    Abstract translation: 制备具有由下式表示的摩尔组成的合成沸石GZS-11：[x M2 / nO +（1.0 +/- 0.2-x）R 2 / nO]：Y 2 O 3：y XO 2 :WH 2 O其中M是无机 价态n的阳离子，R是价数n的有机阳离子，“x”的值小于1.0，Y是+ 3价元素中的一种或多种，​​例如铝，硼，镓，铁，铬，钒， 钼或锰，X是+ 4价元素中的一种或多种，​​例如硅，锗或钛，“y”的值在6至25之间，“w”的值取决于4 沸石的水合程度，并且具有基本上如表1所示的合成沸石的X射线衍射图。制备SiO 2 / Al 2 O 3的低比例的XO2 / Y2O3的方法是通过调节合成混合物组成在 通过添加一种或多种含有沸石组分的反应性源的溶液的老化阶段。

    Gasoline sulfur reduction in fluid catalytic cracking
    6.
    发明授权
    Gasoline sulfur reduction in fluid catalytic cracking 有权
    汽油硫化液流化催化裂化

    公开(公告)号：US07803267B2

    公开(公告)日：2010-09-28

    申请号：US11118541

    申请日：2005-04-29

    Applicant: Arthur W. Chester ,  Terry G. Roberie ,  Hye Kyung C. Timken ,  Michael S. Ziebarth

    Inventor： Arthur W. Chester ,  Terry G. Roberie ,  Hye Kyung C. Timken ,  Michael S. Ziebarth

    IPC: C10G11/05

    CPC classification number: B01J29/076 ,  B01J29/072 ,  B01J29/166 ,  B01J2229/42 ,  C10G11/05

    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.

    Abstract translation: 通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属 筛子的结构以及提高催化剂的稳定性和硫还原活性的铈组分。 分子筛通常是诸如USY的八面沸石。 初级硫还原组分通常是元素周期3的金属，优选为钒。 硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

    Gasoline sulfur reduction in fluid catalytic cracking
    8.
    发明授权
    Gasoline sulfur reduction in fluid catalytic cracking 有权
    汽油硫化液流化催化裂化

    公开(公告)号：US07153413B2

    公开(公告)日：2006-12-26

    申请号：US09901939

    申请日：2001-07-10

    Applicant: Terry G. Roberie ,  Ranjit Kumar ,  Michael S Ziebarth ,  Wu-Cheng Cheng ,  Xinjin Zhao ,  Nazeer Bhore

    Inventor： Terry G. Roberie ,  Ranjit Kumar ,  Michael S Ziebarth ,  Wu-Cheng Cheng ,  Xinjin Zhao ,  Nazeer Bhore

    IPC: C10G11/18

    CPC classification number: C10G11/05 ,  C10G11/02

    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, is reduced in a catalytic cracking process employing a cracking catalyst containing a high content of vanadium. The cracking process involves introducing at least one vanadium compound into a hydrocarbon-sulfur containing feedstock to be charged to a fluid catalytic cracking reactor operating under steady state conditions and containing an equilibrium fluid cracking catalyst inventory within the reactor. The amount of sulfur in the liquid products, in particular gasoline and LCO fractions, is reduced as a result of the increased vanadium content on the equilibrium catalyst. Advantageously, sulfur reduction is achieved even in the presence of other metal contaminants, such as nickel and iron, on the equilibrium catalyst.

    Abstract translation: 在使用含钒量高的裂化催化剂的催化裂化过程中，液体裂解产物，特别是裂化汽油的硫含量降低。 裂解过程包括将至少一种钒化合物引入含烃 - 硫的原料中，以将其装入在稳态条件下运行并在反应器内含有平衡流体裂解催化剂存量的流化催化裂化反应器。 由于在平衡催化剂上的钒含量增加，液体产物中的硫的量，特别是汽油和LCO馏分的量减少。 有利的是，即使在平衡催化剂上存在其它金属污染物如镍和铁的情况下也能实现硫还原。

    Gasoline sulfur reduction in fluid catalytic cracking
    10.
    发明授权
    Gasoline sulfur reduction in fluid catalytic cracking 有权
    汽油硫化液流化催化裂化

    公开(公告)号：US06846403B2

    公开(公告)日：2005-01-25

    申请号：US09221539

    申请日：1998-12-28

    Applicant: Wu-Cheng Cheng ,  Scott Kevin Purnell ,  Terry G. Roberie ,  Hye Kyung Cho Timken ,  Xinjin Zhao

    Inventor： Wu-Cheng Cheng ,  Scott Kevin Purnell ,  Terry G. Roberie ,  Hye Kyung Cho Timken ,  Xinjin Zhao

    IPC: B01J29/072 ,  B01J29/076 ,  B01J29/16 ,  C10G11/05 ,  C10G11/00

    CPC classification number: C10G11/05 ,  B01J29/072 ,  B01J29/076 ,  B01J29/166 ,  B01J2229/42

    Abstract: The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 4 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.

    Abstract translation: 通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属 筛子的结构以及提高裂化催化剂的裂解活性的稀土成分。 分子筛通常是诸如USY的八面沸石。 初级硫还原组分通常是周期表第4周期的金属，优选为钒。 稀土组分优选包括提高催化剂的硫还原活性的铈。 硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。

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