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公开(公告)号：US20240352339A1
公开(公告)日：2024-10-24
申请号：US18302167
申请日：2023-04-18
发明人： Aaron Chi Akah , Musaed Salem Al-Ghrami , Rabindran Jermy , Abdullah Aitani , Mohammed A.B. Siddiqui
IPC分类号： C10G11/05 , B01J29/04 , B01J29/40 , B01J29/48 , B01J35/00 , B01J35/10 , B01J37/02 , B01J37/08
CPC分类号： C10G11/05 , B01J29/045 , B01J29/405 , B01J29/48 , B01J35/394 , B01J35/633 , B01J35/66 , B01J37/0207 , B01J37/0236 , B01J37/08 , B01J2229/18 , C10G2300/1033 , C10G2300/70
摘要： A method of preparing a cracking catalyst includes converting one or more clay mineral compositions to metakaolin; synthesizing an intermediate ZSM-5 zeolite from the metakaolin, a silica source, and ZSM-5 zeolite seeds; and forming a cracking catalyst comprising a hierarchical mesoporous ZSM-5 zeolite through disintegration and recrystallization of the intermediate ZSM-5 zeolite. A cracking catalyst for steam enhanced catalytic cracking of hydrocarbons includes a hierarchical mesoporous ZSM-5 zeolite impregnated with manganese, zirconium, or manganese and zirconium, where the cracking catalyst has a mesopore volume of at least 0.30 cubic centimeters per gram (cm3/g). A process for upgrading crude oil through steam enhanced catalytic cracking includes contacting the crude oil with steam in the presence of a cracking catalyst, where the cracking catalyst comprises a hierarchical mesoporous ZSM-5 zeolite impregnated with manganese, zirconium, or both manganese and zirconium.
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公开(公告)号：US20240335823A1
公开(公告)日：2024-10-10
申请号：US18296146
申请日：2023-04-05
发明人： Furqan Aljumah , Sohel Shaikh , Munir Khokhar , Zhonglin Zhang , Shatha Alabbad
摘要： A catalyst system may be regenerated by a method that includes exposing the catalyst system to a de-coking treatment. The de-coking treatment may include three consecutive treatment conditions including a first treatment condition, a second treatment condition, and a third treatment condition. The catalyst system may include a metathesis catalyst and a cracking catalyst. The metathesis catalyst may include tungsten oxide and silica carrier, and the cracking catalyst may include ZSM-5 zeolite.
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公开(公告)号：US12083501B2
公开(公告)日：2024-09-10
申请号：US17821827
申请日：2022-08-24
发明人： Amir Sabahi , Andrew Loebl , Sandra Gavalda , Julie Francis , Eswaramoorthi Iyyamperumal , Min Li , Andrea Marcinkova
CPC分类号： B01J21/12 , B01J21/16 , B01J29/04 , B01J37/0018 , B01J37/04 , C10G11/05 , C10G11/18 , C10G2300/70
摘要： Process for the preparation of a catalyst and a catalyst comprising more than one silica is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 10 to about 45 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized colloidal silica, greater than about 0 to about 30 wt % silica from ammonia stabilized or lower sodium colloidal silica, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with good performance.
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公开(公告)号：US12012556B2
公开(公告)日：2024-06-18
申请号：US17632569
申请日：2020-07-21
发明人： Mayank Kashyap
CPC分类号： C10G11/18 , B01J8/1818 , B01J8/1854 , C10G11/05 , C10G11/182 , C10G2300/1044 , C10G2400/20
摘要： Systems and methods for producing light olefins via catalytic cracking of naphtha are disclosed. A naphtha feed stream and lift gas stream are fed into a dense phase riser reactor operated with a high solid volume fraction, a high superficial velocity, minimum back mixing. The effluent stream from the dense phase riser reactor is further separated, in a secondary reactor, to form a gaseous product stream and a catalyst stream. The catalyst stream is stripped to remove the hydrocarbons adsorbed on the catalyst particles. The stripped catalyst is regenerated in a regenerator.
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5.发明授权公开(公告)号：US12012554B2
公开(公告)日：2024-06-18
申请号：US17858186
申请日：2022-07-06
发明人： Mansour Ali Al-Herz , Musaed Salem Al-Ghrami , Qi Xu , Aaron Akah
CPC分类号： C10G11/05 , B01J21/04 , B01J21/08 , B01J21/16 , B01J29/40 , B01J37/0201 , C10G2400/20
摘要： A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.
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公开(公告)号：US20240010927A1
公开(公告)日：2024-01-11
申请号：US18349276
申请日：2023-07-10
申请人： Chevron U.S.A. Inc.
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , C10G2400/20 , C10G2400/02 , C10G2400/30 , C10G2300/1003 , C10G2300/1018 , C10G2300/1014 , C10G2300/708 , C10G2300/305
摘要： Provided is a composition comprising a blend of a waste plastic and a bio feedstock. Also provided is a process for preparing a stable blend of a plastic and bio feedstock which can be stored or transported if desired. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend can be passed to a conversion unit for conversion of the waste plastic and bio feedstock. The conversion process produces clean monomers for polymerization and chemical intermediates.
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7.发明公开公开(公告)号：US20240010926A1
公开(公告)日：2024-01-11
申请号：US17858186
申请日：2022-07-06
发明人： Mansour Ali Al-Herz , Musaed Salem Al-Ghrami , Qi Xu , Aaron Akah
CPC分类号： C10G11/05 , B01J29/40 , B01J21/16 , B01J21/08 , B01J21/04 , B01J37/0201 , C10G2400/20
摘要： A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.
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8.发明公开公开(公告)号：US20230330650A1
公开(公告)日：2023-10-19
申请号：US18337070
申请日：2023-06-19
申请人： CHINA AUTOMOTIVE TECHNOLOGY AND RESEARCH CENTER CO., LTD , CATARC AUTOMOTIVE TEST CENTER (TIANJIN) CO., LTD
发明人： Kaixiang LI , Zhenguo LI , Xiaoning REN , Yuankai SHAO , Jianhai WANG , Li ZHANG , Lingfeng JIA , Cheng LV
IPC分类号： B01J29/80 , B01J29/76 , B01J29/83 , B01J29/85 , B01J29/00 , B01J37/00 , B01J37/03 , B01J37/02 , B01J37/06 , B01J37/08 , C07C2/84 , C10G11/05
CPC分类号： B01J29/80 , B01J29/763 , B01J29/83 , B01J29/85 , B01J29/005 , B01J37/0018 , B01J37/036 , B01J37/033 , B01J37/0236 , B01J37/06 , B01J37/082 , C07C2/84 , C10G11/05 , B01J2029/062
摘要： The present disclosure provides molecular sieves with intergrown phases of AEI and CHA topologies and a catalyst thereof. A preparation method for the molecular sieves include the following steps: mixing a hydroxyphosphono organic alkali R with an aluminum source and a silicon source to obtain a sol-gel precursor, putting the sol-gel precursor into a closed hydrothermal synthesis reactor for reaction, filtering the reaction solution, washing, drying, and calcination to obtain the molecular sieves with intergrown phases of AEI and CHA topologies. The molecular sieves and the catalyst thereof can be directly synthesized under mild conditions with a hydroxyphosphono organic alkali as a structure-directing agent and a phosphorus source, have a pH value of 6-9 and low requirements for corrosion resistance of production devices, and are suitable for large-scale production.
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公开(公告)号：US11691132B2
公开(公告)日：2023-07-04
申请号：US17268679
申请日：2019-08-15
发明人： Lingping Zhou , Qiuqiao Jiang , Shuai Yuan , Hao Sha , Mingde Xu , Zhenyu Chen , Weilin Zhang , Huiping Tian
IPC分类号： B01J29/08 , B01J21/04 , B01J21/16 , B01J35/10 , B01J37/10 , B01J37/30 , C07C4/06 , C10G11/05
CPC分类号： B01J29/088 , B01J21/04 , B01J21/16 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/10 , B01J37/30 , C07C4/06 , C10G11/05 , B01J2229/186 , B01J2229/24 , B01J2229/36 , B01J2229/37 , C07C2521/04 , C07C2521/16 , C07C2529/08 , C10G2300/202 , C10G2300/308 , C10G2400/30
摘要： A modified Y-type molecular sieve has a rare earth content of about 4% to about 11% by weight on the basis of the oxide, a phosphorus content of about 0.05% to about 10% by weight on the basis of P2O5, a sodium content of no more than about 0.5% by weight on the basis of sodium oxide, a gallium content of about 0.1% to about 2.5% by weight on the basis of gallium oxide, and a zirconium content of about 0.1% to about 2.5% by weight on the basis of zirconia; and the modified Y-type molecular sieve has a total pore volume of about 0.36 mL/g to about 0.48 mL/g, a percentage of the pore volume of secondary pores having a pore size of 2-100 nm to the total pore volume of about 20% to about 40%.
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公开(公告)号：US20230167368A1
公开(公告)日：2023-06-01
申请号：US17995783
申请日：2021-03-22
发明人： Khalid A. AL-MAJNOUNI , Wojciech SUPRONOWICZ , Nabil AL-YASSIR , Talal ALDUGMAN , Ahmed ALZENAIDI
CPC分类号： C10G11/182 , B01J29/08 , C10G11/05 , B01J29/40 , C10G2400/20 , C10G2300/708 , C10G2300/1033
摘要： Systems and methods for producing light olefin(s) are disclosed. The method includes contacting a catalyst with a coke precursor to form a light olefin selective catalyst, and contacting the light olefin selective catalyst with a hydrocarbon feed under conditions sufficient to catalytically crack at least a portion of the hydrocarbon feed to form a products stream containing a light olefin, here the light olefin selective catalyst is more selective than the catalyst in catalyzing formation of the light olefin by the catalytic cracking of the hydrocarbon feed.
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