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公开(公告)号：US09427722B2
公开(公告)日：2016-08-30
申请号：US14515900
申请日：2014-10-16
IPC分类号： B01D53/047 , B01J20/22 , B01J20/28 , B01D53/02
CPC分类号： B01J20/223 , B01D53/02 , B01D53/047 , B01D2253/204 , B01D2256/10 , B01D2256/12 , B01D2256/18 , B01D2259/4525 , B01J20/226 , B01J20/2803 , B01J20/28066 , B01J20/28069 , B01J20/28076 , B01J20/2808
摘要： Adsorption systems providing a capacity of at least 200 g/L for oxygen-containing mixtures, or an oxygen-nitrogen selectivity of at least 1.4:1 or at least 1:2 with an adsorbed capacity of at least 0.6 mmol/g at 4 bar and 22° C.
摘要翻译： 为含氧混合物提供至少200g / L的容量的吸附系统，或至少1.4:1或至少1:2的氧 - 氮选择性，吸附容量至少为0.6mmol / g，在4巴 和22℃
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2.发明申请POROUS POLYMERS FOR THE ABATEMENT AND PURIFICATION OF ELECTRONIC GAS AND THE REMOVAL OF MERCURY FROM HYDROCARBON STREAMS 审中-公开用于电子废气的净化和净化的多孔聚合物以及从氢气流中去除汞的多孔聚合物公开(公告)号：US20160160348A1
公开(公告)日：2016-06-09
申请号：US14957245
申请日：2015-12-02
IPC分类号： C23C16/44 , B01J20/22 , H01L21/425 , C07F1/08 , C07F7/00 , C23C16/455 , B01J20/26 , C07F3/06
CPC分类号： C23C16/4402 , B01J20/226 , B01J20/26 , C07F1/08 , C07F3/06 , C07F7/003 , C23C16/4412 , C23C16/45544 , H01L21/425 , Y02C20/30
摘要： A porous material, including metal organic frameworks (MOFs) and porous organic polymer (POP), with reactivity with or sorptive affinity towards (a) electronic gas to substantially remove or abate electronic gas in an electronic gas-containing effluent, or (b) contaminants in a stream of electronic gas to substantially remove the contaminants from a stream of electronic gas and increase the purity of said electronic gas, or (c) trace mercury contaminant in a hydrocarbon stream to substantially remove said mercury contaminant and increase the purity of said hydrocarbon stream. MOFs are the coordination product of metal ions and multidentate organic ligands, whereas POPs are the product of polymerization between organic monomers.
摘要翻译： 或（b）多孔材料，包括金属有机骨架（MOF）和多孔有机聚合物（POP），与（a）电子气体具有反应性或吸附亲和力，以便基本上去除或消除电子气体流出物中的电子气体，或（b） 电子气体流中的污染物基本上从电子气流中除去污染物并增加所述电子气体的纯度，或（c）痕量的烃流中的汞污染物，以基本上除去所述汞污染物并增加所述的 烃流。 MOFs是金属离子和多齿有机配体的配位产物，而POPs是有机单体之间聚合的产物。
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公开(公告)号：US09138720B2
公开(公告)日：2015-09-22
申请号：US14450994
申请日：2014-08-04
CPC分类号： B01J20/226 , B01J20/28011 , B01J20/28016 , B01J20/28019 , B01J20/28042 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/2808 , B01J20/28083 , B01J20/3085 , F17C11/00 , Y02C10/08
摘要： A metal organic framework (MOF) includes a coordination product of a metal ion and an at least bidentate organic ligand, where the metal ion and the organic ligand are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas. A porous organic polymer (POP) includes polymerization product from at least a plurality of organic monomers, where the organic monomers are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas.
摘要翻译： 金属有机骨架（MOF）包括金属离子和至少二齿有机配体的配位产物，其中选择金属离子和有机配体以提供电子气体的至少70g / l的可输送吸附容量 。 多孔有机聚合物（POP）包括来自至少多种有机单体的聚合产物，其中选择有机单体以为电子气体提供至少70g / l的可输送吸附能力。
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公开(公告)号：US20150105250A1
公开(公告)日：2015-04-16
申请号：US14515900
申请日：2014-10-16
发明人： Mitchell Hugh WESTON
IPC分类号： B01J20/22 , B01J20/28 , B01D53/02 , B01D53/047
CPC分类号： B01J20/223 , B01D53/02 , B01D53/047 , B01D2253/204 , B01D2256/10 , B01D2256/12 , B01D2256/18 , B01D2259/4525 , B01J20/226 , B01J20/2803 , B01J20/28066 , B01J20/28069 , B01J20/28076 , B01J20/2808
摘要： Adsorption systems providing a capacity of at least 200 g/L for oxygen-containing mixtures, or an oxygen-nitrogen selectivity of at least 1.4:1 or at least 1:2 with an adsorbed capacity of at least 0.6 mmol/g at 4 bar and 22° C.
摘要翻译： 为含氧混合物提供至少200g / L的容量的吸附系统，或至少1.4:1或至少1:2的氧 - 氮选择性，吸附容量至少为0.6mmol / g，在4巴 和22℃
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公开(公告)号：US11253838B2
公开(公告)日：2022-02-22
申请号：US16993803
申请日：2020-08-14
IPC分类号： B01J20/22 , B01J20/28 , B01J20/30 , B01J35/02 , B01J35/04 , B01J35/08 , B01J35/10 , B01J37/04 , B01J37/10 , B01J31/16 , B01J31/22 , C07F1/08 , B01D53/86 , B01D53/82 , B01D53/58
摘要： This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.
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6.发明申请公开(公告)号：US20210379559A1
公开(公告)日：2021-12-09
申请号：US17217793
申请日：2021-03-30
发明人： Mitchell Hugh Weston , William Morris , William Joseph Hoover , Patrick Emmett Fuller , John Paul Siegfried , Randi Danielle Groy , Jeffrey Loren Wells , Timothy Chiaan Wang , Edwin Alfonso Argueta Fajardo
摘要： This invention relates to modified MOF materials, methods of preparing them and processes using them. A modified MOF of the invention is modified by impregnating a MOF with an inorganic metal salt. The starting MOF contains at least one linker or ligand which contains an aryl amino group as part of its structure. These modified MOFs are able to adsorb either basic or acidic toxic industrial compounds (TIC). The modified MOFs can be used to remove TICs from various gaseous streams such as air.
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公开(公告)号：US20210354107A1
公开(公告)日：2021-11-18
申请号：US17319848
申请日：2021-05-13
摘要： This invention relates to a method of using MOF adsorbents to remove elemental impurities from feed streams comprising active pharmaceutical ingredients (API). The process involves contacting the feed stream comprising API and elemental impurities with the MOF at purification conditions to obtain a purified stream with provides an API which has a concentration of the elemental impurity below its permitted daily exposure. The process can be carried in a batch mode where the MOF and feed stream are admixed in a vessel for a given amount of time or continuously by flowing the feed stream through a column or adsorbent bed containing the MOF adsorbent.
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公开(公告)号：US20150352519A1
公开(公告)日：2015-12-10
申请号：US14828097
申请日：2015-08-17
CPC分类号： B01J20/226 , B01J20/28011 , B01J20/28016 , B01J20/28019 , B01J20/28042 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/2808 , B01J20/28083 , B01J20/3085 , F17C11/00 , Y02C10/08
摘要： A metal organic framework (MOF) includes a coordination product of a metal ion and an at least bidentate organic ligand, where the metal ion and the organic ligand are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas. A porous organic polymer (POP) includes polymerization product from at least a plurality of organic monomers, where the organic monomers are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas.
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公开(公告)号：US20150034500A1
公开(公告)日：2015-02-05
申请号：US14450994
申请日：2014-08-04
CPC分类号： B01J20/226 , B01J20/28011 , B01J20/28016 , B01J20/28019 , B01J20/28042 , B01J20/28066 , B01J20/28071 , B01J20/28073 , B01J20/28076 , B01J20/2808 , B01J20/28083 , B01J20/3085 , F17C11/00 , Y02C10/08
摘要： A metal organic framework (MOF) includes a coordination product of a metal ion and an at least bidentate organic ligand, where the metal ion and the organic ligand are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas. A porous organic polymer (POP) includes polymerization product from at least a plurality of organic monomers, where the organic monomers are selected to provide a deliverable adsorption capacity of at least 70 g/l for an electronic gas.
摘要翻译： 金属有机骨架（MOF）包括金属离子和至少二齿有机配体的配位产物，其中选择金属离子和有机配体以提供电子气体的至少70g / l的可输送吸附容量 。 多孔有机聚合物（POP）包括来自至少多种有机单体的聚合产物，其中选择有机单体以为电子气体提供至少70g / l的可输送吸附能力。
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10.发明申请公开(公告)号：US20220126268A1
公开(公告)日：2022-04-28
申请号：US17571073
申请日：2022-01-07
IPC分类号： B01J20/22 , B01J20/28 , B01J31/16 , C07F1/08 , B01D53/86 , B01D53/82 , B01D53/58 , B01J20/30 , B01J35/02 , B01J35/04 , B01J35/08 , B01J35/10 , B01J37/04 , B01J37/10
摘要： This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.
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