公开(公告)号：US06479217B1

公开(公告)日：2002-11-12

申请号：US09790996

申请日：2001-02-22

申请人： Oleg V. Grinevich ,  Alexander Mejiritski ,  Petr Serguievski ,  Douglas C. Neckers

发明人： Oleg V. Grinevich ,  Alexander Mejiritski ,  Petr Serguievski ,  Douglas C. Neckers

IPC分类号： G03F730

CPC分类号： G03F7/105 ,  G03F7/027 ,  G03F7/2022

摘要： A method for forming selectively colored printing plates using photosensitive recording elements is disclosed wherein the photosensitive recording element contains a photopolymerizable recording layer comprising a photopolymerizable monomer, a radical photoinitiator, a color former, and a color photoinitiator. A method for producing a printing plate from the photosensitive recording element involves exposing the back surface of the recording layer to a dose of actinic radiation, imagewise exposing the front of the photopolymerizable recording layer to another dose of actinic radiation thereby forming exposed and unexposed areas on the front of the recording layer wherein the exposed areas are cured and undergo a color change by exposure to the actinic radiation, and then removing the unexposed areas of the imagewise exposed recording layer thereby forming an image in relief wherein the image portion and the non-image portion are of different color and wherein the contrast between these portions due to the color difference is visually detectable.

摘要翻译： 公开了一种使用光敏记录元件形成选择性着色印版的方法，其中光敏记录元件含有可光聚合的记录层，其包含可光聚合单体，自由基光引发剂，成色剂和彩色光引发剂。 从感光记录元件制造印版的方法包括将记录层的背面暴露于一定量的光化辐射，将可光聚合记录层的前部成像曝光到另一剂量的光化辐射，从而形成曝光和未曝光区域 记录层的前部，其中暴露的区域被固化并通过暴露于光化辐射而经历颜色变化，然后去除图像曝光的记录层的未曝光区域，从而形成图像，其中图像部分和非 - 图像部分具有不同的颜色，并且其中由于色差导致的这些部分之间的对比度在视觉上是可视的。

公开(公告)号：US06586494B2

公开(公告)日：2003-07-01

申请号：US09924911

申请日：2001-08-08

申请人： Alexandre Mejiritski ,  Oleg V. Grinevich ,  Dustin B. Martin ,  Douglas C. Neckers

发明人： Alexandre Mejiritski ,  Oleg V. Grinevich ,  Dustin B. Martin ,  Douglas C. Neckers

IPC分类号： C08F246

CPC分类号： C09D11/101 ,  B33Y10/00 ,  B33Y70/00 ,  C08L67/07 ,  C09D175/16 ,  Y10S525/921 ,  Y10T428/31794

摘要： A radiation-curable inkjet composition for forming 3-D models or images comprising a semi-crystalline or crystalline, low-shrinkage, radiation-curable oligomeric material, a photoinitiator, and a diluent, said inkjet composition having a viscosity of between about 10 to about 50 cps at at least one temperature between 50 to 140° C.

公开(公告)号：US06309797B1

公开(公告)日：2001-10-30

申请号：US09558599

申请日：2000-04-26

申请人： Oleg V. Grinevich ,  John H. Malpert ,  Alexandre Mejiritski ,  Douglas C. Neckers

发明人： Oleg V. Grinevich ,  John H. Malpert ,  Alexandre Mejiritski ,  Douglas C. Neckers

IPC分类号： G03C700

CPC分类号： G03C7/00 ,  B29C35/08 ,  B29C2035/0833 ,  B29K2105/0032 ,  G03F7/0037 ,  G03F7/038 ,  G03F7/105

摘要： Selectively colorable polymerizable compositions and a method for forming selectively colored polymeric bodies using such compositions are disclosed. In accordance with the invention, a selectively colorable polymerizable composition comprising both a leucobase color former and a leuconitrile color former is irradiated with light of a particular wavelength and specific intensity for a specified duration. Exposure to actinic radiation cures the composition and activates the color formers. The irradiation dosage can be varied to selectively color the polymeric body whereby the resultant color of any particular area depends on the exposure dose received at that location. By varying the dose, a polymeric body can be prepared having distinctly colored elements at specific locations.

摘要翻译： 公开了选择性着色的可聚合组合物和使用这种组合物形成选择性着色聚合物体的方法。 根据本发明，将特定波长和特定强度的光在特定持续时间内照射包含亮氨酸双酯成色剂和亮氨酸成色剂的可选择着色的可聚合组合物。 暴露于光化辐射治疗组合物并激活成色剂。 可以改变照射剂量以选择性地着色聚合物体，由此任何特定区域的所得颜色取决于在该位置处接收的暴露剂量。 通过改变剂量，可以在特定位置制备具有明显着色元素的聚合体。

公开(公告)号：US06433035B1

公开(公告)日：2002-08-13

申请号：US09638252

申请日：2000-08-14

申请人： Oleg V. Grinevich ,  Douglas C. Neckers

发明人： Oleg V. Grinevich ,  Douglas C. Neckers

IPC分类号： C08J328

CPC分类号： C08J3/28 ,  G03C1/732

摘要： Selectively colorable compositions and a method for forming selectively colored polymeric bodies using such compositions are disclosed. In accordance with the invention, a selectively colorable polymerizable composition comprising a leucobase color former is irradiated with light of a particular wavelength and specific intensity for a specified duration. Exposure to actinic radiation cures the composition and activates the color former. Exposure to higher dosages of actinic radiation can bleach the composition. The irradiation dosage can be varied to selectively color the polymeric body whereby the resultant color of any particular area depends on the exposure dose received at that location. By varying the dose, a polymeric body can be prepared having distinctly colored elements at specific locations.

摘要翻译： 公开了选择性着色的组合物和使用这种组合物形成选择性着色聚合物体的方法。 根据本发明，在特定的持续时间内，用特定波长和特定强度的光照射包含白点变色剂成色剂的选择性可着色聚合组合物。 暴露于光化辐射治疗组合物并激活着色剂。 暴露于较高剂量的光化辐射可以漂白组合物。 可以改变照射剂量以选择性地着色聚合物体，由此任何特定区域的所得颜色取决于在该位置处接收的暴露剂量。 通过改变剂量，可以在特定位置制备具有明显着色元素的聚合体。

公开(公告)号：US06200646B1

公开(公告)日：2001-03-13

申请号：US09382889

申请日：1999-08-25

申请人： Douglas C. Neckers ,  Kathleen G. Specht ,  Oleg V. Grinevich ,  Alexandre Mejiritski

发明人： Douglas C. Neckers ,  Kathleen G. Specht ,  Oleg V. Grinevich ,  Alexandre Mejiritski

IPC分类号： B05D300

CPC分类号： G03F7/0037 ,  B29C64/129 ,  B29K2995/0021 ,  B33Y10/00 ,  G03F7/00

摘要： A method for precisely and efficiently creating three dimensional bodies, relief images or patterns, colored bodies, or a combination of these using photopolymers, photocolorizable polymers or photoresponsive coatings, in one irradiation step as disclosed. In particular this invention describes a method of generating objects or patterns with differential control of properties (depth, pore size, color, density, mechanical strength, hardness, degree of cross-linking, tackiness, etc.) such that the property varies across the xy array.

摘要翻译： 在所公开的一个照射步骤中，使用光聚合物，可光着色聚合物或光响应涂层精确有效地创建三维体，浮雕图案或图案，着色体或它们的组合的方法。 特别地，本发明描述了一种通过性质（深度，孔径，颜色，密度，机械强度，硬度，交联度，粘性等）的差异控制产生物体或图案的方法，使得该性质在 xy数组。