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公开(公告)号：US20120103615A1
公开(公告)日：2012-05-03
申请号：US13221573
申请日：2011-08-30
申请人： Oren A. Scherman , Eric Appel , Trevor Hughes
发明人： Oren A. Scherman , Eric Appel , Trevor Hughes
摘要： A wellbore fluid contains a viscosifying polymer in which portions of the polymer are connected through formation of an inclusion complex involving cucurbituril 8 (i.e. CB[8]) as host molecule. The fluid contains guest molecules with first and second guest groups covalently attached wherein at least one of the guest molecules comprises a polymer chain. The CB [8] host and the guest molecules attach together through reception of first and second guest groups within CB[8] host cavities, thereby connecting polymer chains together as a larger, supramolecular polymer and enhancing viscosity of the fluid. Polymer molecules may be synthetic polymers and guest groups may be attached to monomers before polymerization. Alternatively guest groups may be attached to existing polymers which may be polysaccharide.
摘要翻译： 井眼流体含有增粘聚合物，其中部分聚合物通过形成包含葫芦巴8（即CB [8]）的包合物作为宿主分子连接起来。 该流体含有客体分子与共价连接的第一和第二客体基团，其中至少一个客体分子包含聚合物链。 CB [8]主体和客体分子通过接收CB [8]主体腔内的第一和第二客体群而连接在一起，从而将聚合物链连接在一起作为较大的超分子聚合物并增强流体的粘度。 聚合物分子可以是合成聚合物，并且客体基团可以在聚合之前连接到单体上。 或者客体组可以连接到可以是多糖的现有聚合物上。
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2.发明授权Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms 有权含有两个或多个杂原子的桥连双环和多环烯烃的开环易位聚合公开(公告)号：US06884859B2
公开(公告)日：2005-04-26
申请号：US10232105
申请日：2002-08-29
CPC分类号： C08F8/04 , C08G61/06 , C08G61/08 , C08G2261/3324 , C08G2261/418
摘要： A method is provided for synthesizing a polymer in a controlled fashion using a ring-opening metathesis polymerization (ROMP) reaction, wherein polymerization is carried out using a catalytically effective amount of an olefin metathesis catalyst and a bridged bicyclic or polycyclic olefin monomer that contains at least two heteroatoms directly or indirectly linked to each other. Preferred catalysts are Group 8 transition metal complexes, particularly complexes of Ru and Os. Such complexes include the ruthenium bisphosphine complex (PCy3)2(Cl)2Ru═CHPh (1) and the ruthenium carbene complex (IMesH2)(PCy3)(Cl)2Ru═CHPh (2). The invention also provides novel regioregular polymers synthesized using the aforementioned methodology, wherein the polymers may be saturated, unsaturated, protected, and/or telechelic. An exemplary polymer is poly((vinyl alcohol)2-alt-methylene)(MVOH).
摘要翻译： 提供了一种使用开环易位聚合（ROMP）反应以受控的方式合成聚合物的方法，其中使用催化有效量的烯烃复分解催化剂和桥连的双环或多环烯烃单体进行聚合， 至少两个直接或间接连接的杂原子。 优选的催化剂是第8族过渡金属络合物，特别是Ru和Os的络合物。 这样的络合物包括钌双膦络合物（PCy 3 N 2）（Cl）2 Ru-CHPh（1）和钌卡宾络合物（IMesH （C 3）（Cl）2 Ru-CHPh（2）。 本发明还提供了使用上述方法合成的新的区域规整聚合物，其中聚合物可以是饱和的，不饱和的，保护的和/或遥爪的。 示例性聚合物是聚（（乙烯醇）2 - 亚甲基）（MVOH）。
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公开(公告)号：US20200095400A1
公开(公告)日：2020-03-26
申请号：US16494653
申请日：2018-03-16
申请人： Oren A. Scherman , Jade A. McCune
发明人： Oren A. Scherman , Jade A. McCune
IPC分类号： C08L5/16 , C08B37/16 , C08J3/09 , C08J3/11 , C07D213/22 , C07D487/04 , G02F1/1503 , E06B9/24
摘要： Disclosed herein are compositions of a deep eutectic solvent with a host, such as a supramolecular host, and the use of the composition to form a composition comprising the host in complex with one or more guests. The deep eutectic solvent provides an alternative medium to the aqueous-based media that have been used in the art to date. Also disclosed are compositions of a deep eutectic solvent with a redox-active compound, such as a viologen compound, and the use of the composition, for example, in a smart window or for agricultural use, such as in an agricultural product.
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公开(公告)号：US08757264B2
公开(公告)日：2014-06-24
申请号：US13221573
申请日：2011-08-30
申请人： Oren A. Scherman , Eric Appel , Trevor Hughes
发明人： Oren A. Scherman , Eric Appel , Trevor Hughes
IPC分类号： E21B43/16
摘要： A wellbore fluid contains a viscosifying polymer in which portions of the polymer are connected through formation of an inclusion complex involving cucurbituril 8 (i.e. CB[8]) as host molecule. The fluid contains guest molecules with first and second guest groups covalently attached wherein at least one of the guest molecules comprises a polymer chain. The CB[8] host and the guest molecules attach together through reception of first and second guest groups within CB[8] host cavities, thereby connecting polymer chains together as a larger, supramolecular polymer and enhancing viscosity of the fluid. Polymer molecules may be synthetic polymers and guest groups may be attached to monomers before polymerization. Alternatively guest groups may be attached to existing polymers which may be polysaccharide.
摘要翻译： 井眼流体含有增粘聚合物，其中部分聚合物通过形成包含葫芦巴8（即CB [8]）的包合物作为宿主分子连接起来。 该流体含有客体分子与共价连接的第一和第二客体基团，其中至少一个客体分子包含聚合物链。 CB [8]主体和客体分子通过接收CB [8]主体腔内的第一和第二客体群而连接在一起，从而将聚合物链连接在一起作为较大的超分子聚合物并增强流体的粘度。 聚合物分子可以是合成聚合物，并且客体基团可以在聚合之前连接到单体上。 或者客体组可以连接到可以是多糖的现有聚合物上。
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