公开(公告)号：US5235115A

公开(公告)日：1993-08-10

申请号：US745482

申请日：1991-08-15

申请人： Gary P. Hagen ,  Wen-Dong Chang ,  Andreas B. Ernst ,  David A. Palmer ,  Daniel B. Pourreau ,  Patrick E. McMahon ,  John G. Schaffhausen

发明人： Gary P. Hagen ,  Wen-Dong Chang ,  Andreas B. Ernst ,  David A. Palmer ,  Daniel B. Pourreau ,  Patrick E. McMahon ,  John G. Schaffhausen

IPC分类号： C07C6/12 ,  C07C41/30 ,  C07C43/20

CPC分类号： C07C41/30 ,  C07C6/126 ,  C07C2521/06 ,  C07C2527/10 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/128 ,  C07C2527/133 ,  C07C2527/135 ,  C07C2527/138 ,  C07C2531/025

摘要： A method for the selective ethylation of 2-alkoxy-naphthalene compounds at the 6 position of the naphthalene nucleus is disclosed.

摘要翻译： 公开了在萘核6位上选择性乙基化2-烷氧基 - 萘化合物的方法。

公开(公告)号：US5227530A

公开(公告)日：1993-07-13

申请号：US856483

申请日：1992-03-24

申请人： Larry C. Satek ,  Patrick E. McMahon

发明人： Larry C. Satek ,  Patrick E. McMahon

IPC分类号： C07C45/00

CPC分类号： C07C45/002

摘要： Conversion of alcohol to organic compounds which comprises contacting the alcohol with a heterogeneous catalyst composition comprising crystallineCu.sub.2-X Cr.sub.y Al.sub.6-y B.sub.4 O.sub.17 M.sub.m M'.sub.nwhere M is a divalent metal, M' is a monovalent metal, m is a number in a range from 0 to 0.8, n is a number in a range from 0 to 1.6, X is a number in a range from 0 to 10 0.8 and is equal to the sum of m and n/2, and y is a number in a range from 0.01 to 3, having a characteristic X-ray diffraction pattern.

摘要翻译： 将醇转化为有机化合物，其包括使醇与包含结晶Cu2-XCryAl6-yB4O17MmM'n的多相催化剂组合物接触，其中M为二价金属，M'为一价金属，m为0至0.8的数 ，n为0〜1.6的数，X为0〜10的数，0.8以上，m与n / 2的和，y为0.01〜3的数。 具有特征X射线衍射图案。

公开(公告)号：US4740647A

公开(公告)日：1988-04-26

申请号：US925326

申请日：1986-10-31

申请人： Gregory P. Hussmann ,  Patrick E. McMahon

发明人： Gregory P. Hussmann ,  Patrick E. McMahon

IPC分类号： C07C5/31 ,  C07C5/41

CPC分类号： C07C5/417 ,  C07C5/31 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/72

摘要： Cyclization of aliphatic moieties of 3-20 carbons which comprises contacting a suitable starting compound comprising the aliphatic moiety with a catalyst comprising at least one member selected from the group consisting of copper aluminum borate and zero valent copper on a support comprising aluminum borate under appropriate reaction conditions to obtain a compound having at least one more cyclic moiety than the starting compound. Preferably, the aromatic which undergoes cyclization is an alkenyl group attached to an aromatic nucleus. The present invention can be used to dehydrocyclize alkenylbenzenes to alkylnaphthalenes. In particular, 5-(o-tolyl)pentene can be dehydrocyclized to mixtures of 1,5-, 1,6-, and 2,6-dimethylnaphthalene.

摘要翻译： 包括3-20个碳的脂族部分的环化，该方法包括使包含脂族部分的合适起始化合物与包含选自硼酸铜铝和零价铜中的至少一种的催化剂在包含硼酸铝的载体上进行适当反应 获得具有比起始化合物至少多一个环状部分的化合物的条件。 优选地，经历环化的芳族化合物是连接到芳族核的烯基。 本发明可用于将烯基苯脱氢环化成烷基萘。 特别地，5-（邻甲苯基）戊烯可以脱氢环化为1,5-，1,6-和2,6-二甲基萘的混合物。

公开(公告)号：US5332838A

公开(公告)日：1994-07-26

申请号：US174822

申请日：1988-03-29

申请人： Patrick E. McMahon ,  Larry C. Satek

发明人： Patrick E. McMahon ,  Larry C. Satek

IPC分类号： C07D209/04 ,  C07D209/86 ,  C07D215/02 ,  C07D217/02 ,  C07D219/02 ,  C07D231/56 ,  C07D307/79 ,  C07D311/04

CPC分类号： C07D311/04 ,  C07D209/04 ,  C07D209/86 ,  C07D215/02 ,  C07D217/02 ,  C07D219/02 ,  C07D231/56 ,  C07D307/79

摘要： The present invention is a cyclization process utilizing the catalyst copper aluminum borate which process comprises the step of contacting (1) a compound having a fragment in which a carbon-containing chain of at least three atoms in sequence is bonded at one end thereof to a nitrogen, oxygen, or sulfur atom, and at the opposite end to a carbon, nitrogen, oxygen, or sulfur atom, where the latter are bonded to at least one hydrogen atom; with (2) a catalyst comprising at least one member selected from the group consisting of copper aluminum borate and zero valent copper on a support comprising aluminum borate, under conditions sufficient to effect ring closure between the ends of the fragment to obtain a compound comprising a heterocyclic ring.

摘要翻译： 本发明是利用催化剂铜铝酸锂的环化方法，该方法包括使（1）具有其中至少三个原子的含碳链在其一端被结合的片段的化合物与 氮，氧或硫原子，并且在与碳，氮，氧或硫原子相反的一端，其中后者与至少一个氢原子键合; 其中（2）在足以在片段的末端之间实现闭环的条件下，在包含硼酸铝的载体上，包含选自硼酸铝铝和零价铜中的至少一种的催化剂，以获得包含 杂环。

公开(公告)号：US5157182A

公开(公告)日：1992-10-20

申请号：US717382

申请日：1991-06-19

申请人： Patrick E. McMahon ,  Larry C. Satek

发明人： Patrick E. McMahon ,  Larry C. Satek

IPC分类号： C07C5/333

CPC分类号： C07C5/333 ,  C07C5/3335 ,  C07C2102/24

摘要： A dehydrocyclization process is described for producing polynuclear organic compounds by contacting a starting organic material having at least one ring moiety comprising at least two adjacent ring carbon atoms each bonded to an independently selected monovalent radical comprising at most about eight carbon atoms provided at least one of the monovalent hydrocarbon radicals comprises more than one carbon atom with a crystalline copper aluminum borate catalyst. The preferred catalyst comprises at least one member selected from the group consisting of (a) crystalline copper aluminum borate and (b) zero valent copper on a support comprising at least one member selected from the group consisting of Al.sub.4 B.sub.2 O.sub.9 and the crystalline copper aluminum borate, the zero valent copper on the support being formed by the reduction of the crystalline copper aluminum borate. The process is conducted under conditions sufficient to effect cyclization between (i) a carbon atom of one of the radicals and (ii) a carbon atom of the other radical forming a dehydrocyclization product comprising a polynuclear compound wherein the new ring comprises at least 5 carbon atoms.

摘要翻译： 描述了一种脱氢环化方法，用于通过使具有至少一个包含至少两个相邻环碳原子的环部分的起始有机材料与至少包含至多约8个碳原子的独立选择的一价基团键合，起始有机材料提供至少一个 一价烃基包含多于一个碳原子与结晶的硼酸铜铝催化剂。 优选的催化剂包括选自（a）结晶的硼酸铝铝和（b）在包含选自Al 4 B 2 O 9和结晶的硼酸铜铝的至少一种的载体上的零价铜的至少一种， 通过还原结晶的硼酸铝铝形成载体上的零价铜。 该方法在足以在（i）一个基团的碳原子和（ii）形成包含多核化合物的脱氢环化产物的另一个基团的碳原子之间进行环化的条件下进行，其中该新环包含至少5个碳 原子

公开(公告)号：US5108973A

公开(公告)日：1992-04-28

申请号：US705742

申请日：1991-05-28

申请人： Larry C. Satek ,  Patrick E. McMahon

发明人： Larry C. Satek ,  Patrick E. McMahon

IPC分类号： B01J21/02 ,  B01J23/86

CPC分类号： B01J23/868 ,  B01J21/02

摘要： The preparation, structure, and properties of solid inorganic materials containing at least copper, chromium, aluminum, boron and oxygen which new materials have a characteristic X-ray diffraction pattern are described. Also described is the use of such materials in catalytic compositions for the conversion of organic compounds. In particular, new compositions comprising material having a structureCu.sub.2-x Cr.sub.y Al.sub.6-y B.sub.4 O.sub.17 M.sub.m M'.sub.nwhere M is a divalent metal, M' is a monovalent metal, m is a number in a range from 0 to 0.8, n is a number in a range from 0 to 1.6, X is a number in a range from 0 to 0.8 and is equal to the sum of m and n/2, and y is a number in a range from 0.01 to 3, having a characteristic X-ray diffraction pattern are described as well as the use of such materials in various catalyzed processes including dehydrogenation of hydrocarbons and oxygen-containing hydrocarbons.

摘要翻译： 描述了新材料具有特征X射线衍射图案的至少含有铜，铬，铝，硼和氧的固体无机材料的制备，结构和性能。 还描述了这样的材料在催化组合物中用于有机化合物转化的用途。 特别地，包含具有Cu2-xCryAl6-yB4O17MmM'n结构的材料的新组合物，其中M是二价金属，M'是一价金属，m是0至0.8范围内的数，n是一个范围内的数字 从0到1.6，X是0至0.8范围内的数字，并且等于m和n / 2之和，y是0.01至3的数，具有特征X射线衍射图 以及在各种催化方法中使用这些材料，包括烃和含氧烃的脱氢。

公开(公告)号：US4783570A

公开(公告)日：1988-11-08

申请号：US53797

申请日：1987-05-26

申请人： Gregory P. Hussmann ,  Patrick E. McMahon

发明人： Gregory P. Hussmann ,  Patrick E. McMahon

IPC分类号： C07C5/27 ,  C07C5/22

CPC分类号： C07C5/2732 ,  C07C5/2737 ,  C07C2529/06 ,  C07C2529/86

摘要： A gas-phase isomerizaiton process wherein a feed containing one or more members of the 2,7-DMN isomer triad is selectively isomerized over a lower-acidity, supported, molecular-sieve-based catalyst composition to form essentially equilibrium amounts of the members of the 2,7-triad and reduced amounts of outside-the-triad products.

摘要翻译： 一种气相异构化方法，其中含有一种或多种2,7- DMN异构体三单元组分的进料在低酸度负载的分子筛基催化剂组合物上选择性异构化，以形成基本平衡量的 2/3三合一和减少的黑社会产品数量。

公开(公告)号：US4697010A

公开(公告)日：1987-09-29

申请号：US870822

申请日：1986-06-05

申请人： Patrick E. McMahon

发明人： Patrick E. McMahon

IPC分类号： C07D201/04

CPC分类号： C07D201/04

摘要： A process for the catalyzed conversion of oximes such as cyclohexanone oxime to amides such as caprolactam via a high conversion, high selectivity, long catalyst lifetime reaction over a HAMS-1B crystalline borosilicate-based catalyst composition.

摘要翻译： 通过HAMS-1B结晶硼硅酸盐基催化剂组合物的高转化率，高选择性，长催化剂寿命反应，将肟如环己酮肟催化转化为酰胺如己内酰胺的方法。

公开(公告)号：US4891462A

公开(公告)日：1990-01-02

申请号：US186358

申请日：1988-04-25

申请人： Patrick E. McMahon

发明人： Patrick E. McMahon

IPC分类号： C07C5/31 ,  C07C5/41

CPC分类号： C07C5/417 ,  C07C5/31 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2523/72

摘要： A copper aluminum borate catalyzed cyclization-dehydrogenation process useful for converting 1-ethylnaphthalene to mixtures of vinylnaphthalens, acenaphthene and acenaphthylene.

摘要翻译： 硼酸铜铝催化环化脱氢方法，可用于将1-乙基萘转化为乙烯基萘，苊和苊的混合物。

公开(公告)号：US4883915A

公开(公告)日：1989-11-28

申请号：US35868

申请日：1987-04-08

申请人： Patrick E. McMahon

发明人： Patrick E. McMahon

IPC分类号： C07D201/04

CPC分类号： C07D201/04

摘要： A process for the catalyzed conversion fo oximes such as cyclohexanone oxime to amides such as caprolactam via a high conversion, high selectivity, long catalyst lifetime reaction over a HAMS-1B crystalline borosilicate-based catalyst composition.

摘要翻译： 通过HAMS-1B结晶硼硅酸盐基催化剂组合物的高转化率，高选择性，长的催化剂寿命反应，催化转化如环己酮肟向酰胺如己内酰胺转化的方法。