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公开(公告)号：US06552108B1
公开(公告)日：2003-04-22
申请号：US09686215
申请日：2000-10-11
IPC分类号： C08K529
CPC分类号： C08L23/283 , C08F8/32 , C08F2800/20 , C08F2810/50 , C08K5/1545 , C08K5/17 , C08L21/00 , C08L23/10 , C08L77/00 , C08L101/00 , C08L2205/02 , C08F210/10 , C08L23/28 , C08L2666/06 , C08L2666/14 , C08L2666/04 , C08F210/12
摘要： The present invention relates generally to rubber compositions having improved green strength and thermal stability. These compositions comprise blends of a first rubber component, an isoolefin/para-alkylstyrene copolymer component, and an amine component reacted in situ prior to curing. The present invention further relates to methods for preparing these compositions.
摘要翻译： 本发明一般涉及具有改善的生坯强度和热稳定性的橡胶组合物。 这些组合物包含第一橡胶组分，异烯烃/对烷基苯乙烯共聚物组分和在固化前原位反应的胺组分的共混物。 本发明还涉及制备这些组合物的方法。
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公开(公告)号：US06545101B2
公开(公告)日：2003-04-08
申请号：US09777398
申请日：2001-02-06
IPC分类号： C08F1000
CPC分类号： C08G83/003 , C08F8/26 , C08F8/46 , C08F2810/30 , C08F2810/40 , C08G81/00 , C08G81/02 , C08G81/024 , C08G83/001 , C08F110/10
摘要： Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succinimide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
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公开(公告)号：US06228978B1
公开(公告)日：2001-05-08
申请号：US09100271
申请日：1998-06-19
IPC分类号： C08G7300
CPC分类号： C08G83/003 , C08F8/26 , C08F8/46 , C08F2810/30 , C08F2810/40 , C08G81/00 , C08F110/10
摘要： Polyisobutylene (PIB) functionalized with terminal reactive unsaturation is disclosed. Carbocationically polymerized monohalogen-terminated PIB is dehydrohalogenated in a hydrocarbon solvent using an alkoxide of the formula RO-M wherein R is alkyl of at least 5 carbon atoms and M is alkali metal. The PIB obtained has terminal unsaturation which is 100% in the reactive ‘exo’ form which can be converted to succinic anhydride groups (PIB-SA) by the ene reaction with maleic anhydride. The PIB-SA is reactive with amine functional dendrimers to obtain a star-branched polymer having a dendrimer core and PIB branches joined by succininide linkages. Blends of the star-branched polymer with polypropylene have improved energy absorption properties and controllable moisture/oxygen permeabilities useful in films.
摘要翻译： 公开了用末端反应性不饱和官能化的聚异丁烯（PIB）。 碳氢化合物封端的PIB在烃溶剂中使用式RO-M的醇盐进行脱卤化氢，其中R是至少5个碳原子的烷基，M是碱金属。 得到的PIB具有末端不饱和度，其反应性“外”形式为100％，可通过与马来酸酐的烯酯反应转化为琥珀酸酐基团（PIB-SA），PIB-SA与胺官能树枝状大分子反应以获得 具有树枝状聚合物核心和通过琥珀酰亚胺键连接的PIB分支的星形支化聚合物。星形支化聚合物与聚丙烯的共混物具有改善的能量吸收性能和可用于膜中的水分/氧气渗透性。
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公开(公告)号：US06977287B2
公开(公告)日：2005-12-20
申请号：US10602177
申请日：2003-06-24
申请人： Pawan Kumar Agarwal , Weiqing Weng , Aspy K. Mehta , Armenag H. Dekmezian , Main Chang , Rajan K. Chudgar , Christopher R. Davey , Chon-Yie Lin , Galen C. Richeson , Palanisamy Arjunan , Olivier Jean Georjon
发明人： Pawan Kumar Agarwal , Weiqing Weng , Aspy K. Mehta , Armenag H. Dekmezian , Main Chang , Rajan K. Chudgar , Christopher R. Davey , Chon-Yie Lin , Galen C. Richeson , Palanisamy Arjunan , Olivier Jean Georjon
IPC分类号： C08F4/659 , C08F4/6592 , C08F110/06 , C08F210/06 , C08L23/14 , C08L23/16 , C08F236/20
CPC分类号： C08F4/65927 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/06 , C08F210/06 , C08L23/14 , C08L23/145 , C08L23/16 , C08L2666/04 , C08F236/20 , C08F2500/12 , C08F2500/03 , C08F2500/04 , C08F2500/26
摘要： The co-polymerization reaction of one or more olefin monomers, such as propylene, with α,ω-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of α,ω-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1° C. to 8° C. More desirably, one of the crystalline populations has a melting point in the range from 152° C. to 158° C. and another crystalline population has a melting point in the range from 142° C. to 148° C.
摘要翻译： 提供一种或多种烯烃单体如丙烯与α，ω-二烯单元和所得共聚物的共聚反应。 更具体地说，共聚物可以具有90至99.999重量％的烯烃和0.001至2.000重量％的α，ω-二烯。 该共聚物的重均分子量可以在50,000至2,000,000范围内，结晶温度在115℃至135℃的范围内，熔体流动速率在0.1dg / min至100dg / 分钟 这些共聚物可以用于各种应用中，其制品包括例如膜，纤维，例如纺粘和熔喷纤维，织物如无纺织物和模塑制品。 该共聚物可进一步包括至少两个结晶群。 理想地，一种结晶群体的熔点范围与另一结晶群体的熔点范围可以区别在1℃至8℃的温度范围内。更期望的是，一个结晶群体具有熔点 在152℃至158℃的范围内，另一结晶群的熔点范围为142℃至148℃。
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5.发明授权
公开(公告)号：US5795946A
公开(公告)日：1998-08-18
申请号：US908831
申请日：1997-08-08
CPC分类号： C08J5/18 , C08J2323/14 , Y10S428/91 , Y10T428/31855 , Y10T428/31938
摘要： Film is provided wherein, at least one layer comprises polymer, a molecular majority of which is derived from propylene, having water vapor transmission rate of less than or equal to about (-7.4428 g.times..mu.m/m.sup.2 .times.day.times.% polymer crystallinity) (% polymer crystallinity)+627.32 g.times..mu.m/m.sup.2 .times.day, or (-0.0189 g.times.mil/100 in.sup.2 .times.day.times.% polymer crystallinity) (% polymer crystallity)+1.593 g.times.mil/100 in.sup.2 .times.day.
摘要翻译： 提供膜，其中至少一层包含聚合物，其分子主要来源于丙烯，其水蒸气透过率小于或等于约（-7.4428g×m / m 2×x％x％聚合物结晶度）（％聚合物结晶度 ）+627.32gxm / m 2×日，或（-0.0189gxmil / 100 in 2xdayx％聚合物结晶度）（％聚合物结晶度）+1.593gxmil / 100 in2xday。
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公开(公告)号：US06809168B2
公开(公告)日：2004-10-26
申请号：US10406036
申请日：2003-04-02
申请人： Pawan Kumar Agarwal , Weiqing Weng , Aspy K. Mehta , Armenag H. Dekmezian , Main Chang , Rajan K. Chudgar , Olivier Jean Georjon , Chon-Yie Lin , Michael C. Chen , Galen C. Richeson , Palanisamy Arjunan
发明人： Pawan Kumar Agarwal , Weiqing Weng , Aspy K. Mehta , Armenag H. Dekmezian , Main Chang , Rajan K. Chudgar , Olivier Jean Georjon , Chon-Yie Lin , Michael C. Chen , Galen C. Richeson , Palanisamy Arjunan
IPC分类号： C08F23620
CPC分类号： C08F4/65927 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/06 , C08F210/06 , C08L23/14 , C08L23/145 , C08L23/16 , C08L2666/04 , C08F236/20 , C08F2500/12 , C08F2500/03 , C08F2500/04 , C08F2500/26
摘要： The co-polymerization reaction of one or more olefin monomers, such as propylene, with &agr;,&ohgr;-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of &agr;,&ohgr;-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115° C. to 135° C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1° C. to 8° C. More desirably, one of the crystalline populations has a melting point in the range from 152° C. to 158° C. and another crystalline population has a melting point in the range from 142° C. to 148° C.
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公开(公告)号：US06512019B1
公开(公告)日：2003-01-28
申请号：US09702326
申请日：2000-11-01
申请人： Pawan Kumar Agarwal , Aspy K. Mehta
发明人： Pawan Kumar Agarwal , Aspy K. Mehta
IPC分类号： C08J900
CPC分类号： C08J9/14 , C08F10/06 , C08F110/06 , C08F210/06 , C08J2201/03 , C08J2323/12 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L2203/14 , C08L2308/00 , C08F2/001 , C08L2666/04 , C08F2500/12 , C08F2500/15 , C08F210/16
摘要： This invention relates generally to foamable crystalline propylene polymers obtained from metallocene catalysis and to their methods of production. The foamed crystalline propylene polymers have molecular weight distributions and densities that fall within broad ranges. The crystalline propylene polymers may be prepared in a multiple stage polymerization process using a combination of metallocene components in at least two stages.
摘要翻译： 本发明一般涉及由茂金属催化得到的可发泡结晶丙烯聚合物及其生产方法。 发泡结晶丙烯聚合物具有落在宽范围内的分子量分布和密度。 结晶丙烯聚合物可以在至少两个阶段中使用茂金属组分的组合的多阶段聚合方法中制备。
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8.发明授权Elastic fibers and articles made therefrom, including crystalline and crystallizable polymers of propylene 有权由其制成的弹性纤维和制品，包括丙烯的结晶和可结晶的聚合物公开(公告)号：US06342565B1
公开(公告)日：2002-01-29
申请号：US09570584
申请日：2000-05-12
IPC分类号： D01F646
CPC分类号： D01F6/46 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L2203/12 , C08L2205/02 , C08L2314/06 , C08L2666/04 , C08L2666/06
摘要： Improved thermoplastic polymer soft elastic fiber blend compositions including a crystalline isotactic polypropylene component and a crystallizable alpha-olefin and propylene copolymer component, the copolymer comprising crystallizable alpha-olefin sequences. In a preferred embodiment, improved thermoplastic polymer blends are provided prepared from 0% to 95%, preferably 2% to 40% of the crystalline isotactic polypropylene and from 5% to 100%, preferably 60% to 98% of a crystallizable ethylene and propylene copolymer, wherein said copolymer comprises isotactically crystallizable propylene sequences and is predominately propylene. The resultant blends manifest unexpected compatibility characteristics, increased tensile strength, and, improved resistance to elastic deformation.
摘要翻译： 包括结晶全同立构聚丙烯组分和可结晶的α-烯烃和丙烯共聚物组分的改进的热塑性聚合物软弹性纤维混合组合物，该共聚物包含可结晶的α-烯烃序列。 在优选的实施方案中，提供了改进的热塑性聚合物共混物，其由0％至95％，优选2％至40％的结晶全同立构聚丙烯和5％至100％，优选60％至98％的可结晶乙烯和丙烯 共聚物，其中所述共聚物包含等度可结晶的丙烯序列，主要是丙烯。 所得到的混合物表现出意想不到的相容性，增加拉伸强度，改善弹性变形性。
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