公开(公告)号：US5268523A

公开(公告)日：1993-12-07

申请号：US659416

申请日：1992-01-23

申请人： Jere D. Fellmann ,  Paul R. Wentrcek ,  Peter H. Kilner

发明人： Jere D. Fellmann ,  Paul R. Wentrcek ,  Peter H. Kilner

IPC分类号： C07C7/13 ,  C07C2/64 ,  C07C2/68 ,  C07C7/12

CPC分类号： C07C7/13

摘要： The invention relates to a process for the separation cf various dialkyl multinuclear aromatic compounds from a feed stream of mixed isomers of those compounds. A shape selective adsorbent is employed resulting in a process that is more efficient than processes based upon prior separation techniques. Of special interest are combination processes involving synthesis steps followed by sorption steps using the same shape selective materials.

摘要翻译： PCT No.PCT / US90 / 04153 Sec。 371日期1992年1月23日 102（e）日期1992年1月23日PCT 1990年7月24日PCT申请。本发明涉及从这些化合物的混合异构体的进料流中分离各种二烷基多核芳族化合物的方法。 使用形状选择性吸附剂，导致比基于现有分离技术的方法更有效的方法。 特别感兴趣的是包括合成步骤的组合方法，随后使用相同形状选择性材料的吸附步骤。

公开(公告)号：US4537978A

公开(公告)日：1985-08-27

申请号：US591468

申请日：1984-03-20

申请人： Peter H. Kilner ,  Joseph P. Egan, Jr. ,  Stephen G. Ceisel ,  Wayne P. Schammel

发明人： Peter H. Kilner ,  Joseph P. Egan, Jr. ,  Stephen G. Ceisel ,  Wayne P. Schammel

IPC分类号： C07C51/265 ,  C07D307/89

CPC分类号： C07C51/265

摘要： A process for the oxidation of pseudocumene to trimellitic acid anhydride which comprises catalytic oxidation of pseudocumene with air in the presence of acetic acid in an oxidation zone in the liquid phase and wherein the weight ratio of acetic acid to pseudocumene is in the range of about 1.0-2.5:1.0 and the catalyst comprises one or more heavy metal oxidation catalysts comprising zirconium, cobalt and manganese to provide about 0.2 to about 0.4 weight percent total metals based on pseudocumene and a source of bromine. The addition of the bromine component is controlled to provide a total of about 0.10 to about 0.30 weight percent total bromine based on pseudocumene. The total weight ratio of bromide ions to total metals ions is about 0.7 to about 2.0. The zirconium content is about 1 to about 5% and manganese content is about 14 to about 24% each by weight of the total metals. The reaction temperature is about 100.degree. C. to about 250.degree. C. The acetic acid and water of reaction are withdrawn during the last 5 to about 20% of the reaction.

摘要翻译： 一种用于将假阳离子氧化为偏苯三酸酐的方法，其包括在液相中的氧化区中在乙酸存在下用空气催化氧化假枯烯，并且其中乙酸与假枯烯的重量比在约1.0的范围内 -2.5:1.0，并且催化剂包含一种或多种包含锆，钴和锰的重金属氧化催化剂，以提供约0.2至约0.4重量％的基于假阳离子和溴源的总金属。 控制加入溴组分以提供基于假枯烯的总共约0.10至约0.30重量％的总溴。 溴离子与总金属离子的总重量比为约0.7至约2.0。 锆含量为约1至约5％，锰含量为总金属重量的约14至约24％。 反应温度为约100℃至约250℃。在反应的最后5至约20％期间，将乙酸和反应水取出。

公开(公告)号：US5003120A

公开(公告)日：1991-03-26

申请号：US303575

申请日：1989-01-27

申请人： Stanley F. Newman ,  Jere D. Fellmann ,  Peter H. Kilner

发明人： Stanley F. Newman ,  Jere D. Fellmann ,  Peter H. Kilner

IPC分类号： B01J29/83 ,  B01J29/04 ,  B01J29/06 ,  B01J29/18 ,  B01J29/85 ,  C07B61/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/86 ,  C07C6/12 ,  C07C15/24

CPC分类号： C07C15/24 ,  C07C2/66 ,  C07C6/126 ,  B01J2229/12 ,  B01J2229/14 ,  B01J2229/32 ,  B01J2229/34 ,  B01J29/18 ,  C07C2521/12 ,  C07C2529/18 ,  C07C2529/70 ,  C07C2529/85 ,  Y02P20/582

摘要： A process for the selective manufacture of 2,6-diisopropylnaphthalene from naphthalene advantageously combines an equilibration reactor to enhance the amount of monoisopropylnaphthalene fed to the alkylation reactor, and the use of a shape selective catalyst in the alkylation reactor, to obtain an alkylation reaction product in which the 2,6-diisopropylnaphthalene isomer comprises greater than 39 mole percent of the total diisopropylnaphthalene obtained. Further, this combination of reaction steps and conditions produces a reaction product in which the ratio of 2,6-diisopropylnaphthalene to 2,7-diisopropylnaphthalene is greater than 1.0, preferably greater than 1.2. Recycled process components are fed to the equilibration reactor where they are combined with fresh naphthalene feed to provide a monoisopropylnaphthalene enriched feed to the alkylation reactor.

摘要翻译： 用于从萘选择性制备2,6-二异丙基萘的方法有利地结合了平衡反应器以增加进料到烷基化反应器中的单异丙基萘的量，以及在烷基化反应器中使用形状选择性催化剂，以获得烷基化反应产物 其中2,6-二异丙基萘异构体含有所获得的总二异丙基萘的39摩尔％以上。 此外，反应步骤和条件的这种组合产生其中2,6-二异丙基萘与2,7-二异丙基萘的比率大于1.0，优选大于1.2的反应产物。 将再循环的工艺组分进料到平衡反应器中，在那里将它们与新鲜的萘进料结合，以提供富含单异丙基萘的进料至烷基化反应器。

公开(公告)号：US4587350A

公开(公告)日：1986-05-06

申请号：US744925

申请日：1985-06-14

申请人： Peter H. Kilner ,  Joseph P. Egan, Jr. ,  Stephen G. Ceisel ,  Wayne P. Schammel

发明人： Peter H. Kilner ,  Joseph P. Egan, Jr. ,  Stephen G. Ceisel ,  Wayne P. Schammel

IPC分类号： C07D307/89

CPC分类号： C07D307/89

摘要： A process for the oxidation of pseudocumene to trimellitic acid anhydride is disclosed which comprises catalytic oxidation of pseudocumene with air in the presence of acetic acid in an oxidation zone in the liquid phase wherein the weight ratio of acetic acid to pseudocumene is in the range of about 0.5-4.0:1.0 and the catalyst comprises one or more heavy metal oxidation catalysts comprising zirconium, cobalt, and manganese to provide about 0.1 to about 0.4 weight percent total metals based on pseudocumene and a source of bromine. The addition of the bromine component is controlled to provide a total of about 0.10 to about 0.30 weight percent total bromine based on pseudocumene. The total weight ratio of bromine ions to total metals ions is about 0.5 to about 2.0. The zirconium content is about 1 to about 5% and the manganese content is about 14 to about 60% each by weight of the total metals. The reaction temperature is about 100.degree. C. to about 250.degree. C. The acetic acid and water of reaction are withdrawn during the last 5 to about 20% of the reaction.

摘要翻译： 公开了将假枯烯氧化成偏苯三酸酐的方法，其包括在液相中的氧化区中在乙酸存在下用空气催化氧化假枯烯，其中乙酸与假枯烯的重量比在约 0.5-4.0:1.0，并且催化剂包含一种或多种包含锆，钴和锰的重金属氧化催化剂，以提供约0.1至约0.4重量％的基于假阳离子和溴源的总金属。 控制加入溴组分以提供基于假枯烯的总共约0.10至约0.30重量％的总溴。 溴离子与总金属离子的总重量比为约0.5至约2.0。 锆含量为约1至约5％，锰含量为总金属重量的约14至约60％。 反应温度为约100℃至约250℃。在反应的最后5至约20％期间，将乙酸和反应水取出。

公开(公告)号：US20130210085A1

公开(公告)日：2013-08-15

申请号：US13745403

申请日：2013-01-18

申请人： PETER H. KILNER ,  THOMAS P. GRIFFIN ,  BERNARD COOKER ,  ROGER WEINBERG

发明人： PETER H. KILNER ,  THOMAS P. GRIFFIN ,  BERNARD COOKER ,  ROGER WEINBERG

IPC分类号： C12P19/14

CPC分类号： C12P19/14 ,  C12M45/02 ,  C12M45/06 ,  C12P19/00 ,  C12P2201/00

摘要： A method for the pretreatment of biomass solids includes hydrating the biomass solids to form a biomass slurry, shear treating the biomass solids, and hydrolyzing the biomass solids in the presence of reactive enzymes in a pressure hydrolysis zone. Shear treatment of the biomass solids reduces the particle size of the biomass solids, modifies the particle or slurry morphology, and/or ruptures the cell walls of the biomass solids. The pressure hydrolysis zone includes a high-shear, high-pressure, low-temperature heat exchange and reaction zone and a low-pressure, low-temperature polishing zone. Sugars formed from the biomass solids treated in accordance with the methods described above may be used to produce various biofuels.

摘要翻译： 用于预处理生物质固体的方法包括将生物质固体水合以形成生物质浆料，剪切处理生物质固体，以及在反应性酶存在下在压力水解区中水解生物质固体。 生物质固体的剪切处理降低了生物质固体的粒径，改变了颗粒或浆料的形态，和/或破坏了生物质固体的细胞壁。 压力水解区包括高剪切，高压，低温的热交换和反应区以及低压低温抛光区。 由根据上述方法处理的生物质固体形成的糖可用于生产各种生物燃料。