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    Process for producing an alpha olefin, a tertiary olefin and/or an ether from an unsaturated hydrocarbon cut
    1.
    发明授权
    Process for producing an alpha olefin, a tertiary olefin and/or an ether from an unsaturated hydrocarbon cut 失效
    从不饱和烃馏分制备α-烯烃，叔烯烃和/或醚的方法

    公开(公告)号：US5994594A

    公开(公告)日：1999-11-30

    申请号：US53061

    申请日：1998-04-01

    申请人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    发明人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    IPC分类号： C07C11/02 ,  C07C41/06 ,  C07C41/00 ,  C07C2/00 ,  C07C7/00 ,  C07C9/00

    CPC分类号： C07C11/02 ,  C07C41/06 ,  C07C41/42

    摘要： A process for producing an alpha olefin, a tertiary olefin or a tertiary alkyl ether from an unsaturated hydrocarbon cut containing at least one alpha olefin and at least one etherifiable tertiary olefin comprises synthesising at least one tertiary alkyl ether to obtain a product which is separated into a fraction (O1) which is depleted in ether and containing the alpha olefin and a fraction (E1) which is enriched in ether, followed by decomposition of at least a portion of the ether in fraction (E1) into a product (P1) containing at least one alcohol and at least one tertiary olefin, which is fractionated in a fractionation zone (C5) into a fraction (B1) containing the major portion of the tertiary olefin and a fraction (A1) containing the major portion of the alcohol.

    摘要翻译： 从含有至少一种α烯烃和至少一种可醚化叔烯烃的不饱和烃馏分中制备α-烯烃，叔烯烃或叔烷基醚的方法包括合成至少一种叔烷基醚以获得分离成 在乙醚中耗尽并含有α-烯烃的馏分（O1）和富含乙醚的馏分（E1），然后将部分（E1）中的至少一部分乙醚分解成含有 至少一种醇和至少一种叔烯烃，其在分馏区（C5）中分馏成含有主要部分的叔烯烃的级分（B1）和含有主要部分醇的级分（A1）。

    Process for producing a tertiary olefin by decomposing a tertiary alkyl ether
    2.
    发明授权
    Process for producing a tertiary olefin by decomposing a tertiary alkyl ether 失效
    通过分解叔烷基醚生产叔烯烃的方法

    公开(公告)号：US6100438A

    公开(公告)日：2000-08-08

    申请号：US26682

    申请日：1998-02-20

    申请人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    发明人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    IPC分类号： C07C1/20 ,  C07C11/02 ,  C07C1/00

    CPC分类号： C07C11/02 ,  C07C1/20 ,  C07C2531/025 ,  C07C2531/06

    摘要： A process for producing a tertiary olefin by decomposing a tertiary alkyl ether comprises a) decomposing at least one ether to a product containing an alcohol and a tertiary olefin, b) fractionating at least a portion of the product from a) in a fractionation zone (C1) to obtain the tertiary olefin and the alcohol, c) purifying at least a portion of the tertiary olefin obtained from step b) wherein said portion is sent to a water washing extraction zone (L1) from which a fraction (D) containing the tertiary olefin is recovered, and d) a step in which at least a portion of the fraction (D) from c) is sent to a separation zone (Co) from which a liquid aqueous fraction (Le) and a liquid hydrocarbon fraction (Lc) containing the major portion of the tertiary olefin are recovered.

    摘要翻译： 通过分解叔烷基醚来生产叔烯烃的方法包括：a）将至少一种醚分解成含有醇和叔烯烃的产物，b）在分馏区（a）中分馏至少一部分产物， C1）以获得叔烯烃和醇，c）纯化至少一部分由步骤b）获得的叔烯烃，其中所述部分被送至水洗提取区（L1），从其中含有 回收叔烯烃，d）将来自c）的馏分（D）的至少一部分送至分离区（Co）的步骤，液体含水馏分（Le）和液体烃馏分（Lc ）回收了主要部分的叔烯烃。

    Process for producing a tertiary olefin by decomposing a tertiary alkylether, comprising a first step of purification by washing with water
    3.
    发明授权
    Process for producing a tertiary olefin by decomposing a tertiary alkylether, comprising a first step of purification by washing with water 失效
    通过分解叔烷基醚生产叔烯烃的方法，包括通过用水洗涤来净化的第一步骤

    公开(公告)号：US6072095A

    公开(公告)日：2000-06-06

    申请号：US30916

    申请日：1998-02-26

    申请人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    发明人： Marie-Claire Marion ,  Vincent Coupard ,  Alain Forestiere ,  Philippe Travers ,  Jean-Charles Viltard

    IPC分类号： C07C1/20 ,  C07C11/02 ,  C07C1/00

    CPC分类号： C07C11/02 ,  C07C1/20

    摘要： A process for producing a tertiary olefin by decomposing an ether comprises a) decomposing an ether to a product containing an alcohol and a tertiary olefin, b) purifying at least a portion of the product from a) in a water washing extraction zone (L1) to obtain an aqueous fraction (A1) containing the major portion of the alcohol and a fraction (B1) containing the major portion of the tertiary olefin, the fraction (B1) containing the tertiary olefin, water, possibly ether and light compounds and being substantially free of alcohol, and c) in which at least a portion of the fraction (B1) from b) is sent to a separation zone (Co1) from which a liquid aqueous fraction (La1) and a liquid fraction (Lb1) containing the major portion of the tertiary olefin, possibly ether and possibly light compounds, are recovered.

    摘要翻译： 通过分解醚制备叔烯烃的方法包括：a）将乙醚分解成含有醇和叔烯烃的产物，b）在水洗提取区（L1）中从a）中纯化至少一部分产物， 得到含有主要部分醇的含水馏分（A1）和含有主要部分的叔烯烃的馏分（B1），含有叔烯烃的馏分（B1），水，可能的醚和轻质化合物，并且基本上 不含醇，c）将来自b）的馏分（B1）的至少一部分送至分离区（Co1），分离区（Co1）从该分离区（Co1）中分出含有主要的液体含水馏分（La1）和液体馏分（Lb1） 回收了部分叔烯烃，可能是醚和可能的轻化合物。

    Process and apparatus for reactive distillation with a particular distribution of liquid and vapour phases
    5.
    发明授权
    Process and apparatus for reactive distillation with a particular distribution of liquid and vapour phases 失效
    具有液相和汽相特定分布的反应蒸馏的方法和装置

    公开(公告)号：US5776320A

    公开(公告)日：1998-07-07

    申请号：US686101

    申请日：1996-07-24

    申请人： Marie-Claire Marion ,  Jean-Charles Viltard ,  Philippe Travers ,  Isabelle Harter ,  Alain Forestiere

    发明人： Marie-Claire Marion ,  Jean-Charles Viltard ,  Philippe Travers ,  Isabelle Harter ,  Alain Forestiere

    IPC分类号： B01D3/26 ,  B01D3/00 ,  B01J8/04 ,  B01J19/24 ,  C07C2/64 ,  C07C15/073 ,  C07C41/42 ,  C07C43/04 ,  C10G7/00 ,  B01D3/34

    CPC分类号： B01J8/0469 ,  B01D3/009 ,  B01J8/0492 ,  Y02P20/127

    摘要： The invention concerns a reactive distillation process carried out in a reactive distillation zone which includes at least one catalytic zone flanked by two distillation zones, the vapor from the distillation circulating from bottom to top so as to be in practically no contact with the catalyst, and the liquid circulating from the upper distillation zone (5) to a substantially central zone at the bottom of the catalytic zone without contacting the catalyst, then circulating radially below the catalytic zone via at least one means (20) so as to be introduced into a liquid distribution zone (23), then circulating through the catalytic bed (8) in the catalytic zone, following which the liquid is recovered via at least one liquid overflow means (19) in a lower distillation zone (14). The invention also concerns an apparatus for reactive distillation.

    摘要翻译： 本发明涉及在反应蒸馏区中进行的反应蒸馏方法，该反应蒸馏区包括至少一个侧面有两个蒸馏区的催化区，来自蒸馏的蒸气从底部到顶部循环，以便几乎不与催化剂接触，以及 所述液体从所述上部蒸馏区域（5）循环到所述催化区域的底部的基本中心区域，而不接触所述催化剂，然后经由至少一个装置（20）径向地在所述催化区域下方循环，以便被引入到 液体分配区（23），然后在催化区循环通过催化床（8），随后通过下蒸馏区（14）中的至少一个液体溢流装置（19）回收液体。 本发明还涉及用于反应蒸馏的装置。