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公开(公告)号：US11213805B2
公开(公告)日：2022-01-04
申请号：US16470190
申请日：2017-11-02
申请人： ROSNEFT OIL COMPANY
发明人： Sergey Aleksandrovich Mikhajlov , Gilyana Evgen'evna Dzhungurova , Nikolaj Aleksandrovich Mamonov , Dmitrij Aleksandrovich Grigor'ev , Mikhail Nikolaevich Mikhajlov
摘要： A catalyst in a calcined state has a specific surface area of 20-50 m2/g of catalyst, and a specific surface area of nickel metal after reduction of the catalyst of 8 to 11 m2/g, wherein the average particle size of nickel metal is 3-8 nm, the dispersion of the particles is 10-16%, and the content of nickel is 5-15 wt. % based on the weight of calcined catalyst. A support has a specific surface area of 40-120 m2/g with a pore volume of the support of 0.2-0.4 cm3/g, wherein the support is selected from a mixture of zirconium oxide and cerium oxide or magnesium oxide, cerium oxide and the ballast being zirconium oxide. The catalyst further contains a promoter selected from the group consisting of palladium and ruthenium, in an amount of from 0.01 to 0.5 wt. %. The catalyst is prepared by co-precipitation with ammonium hydroxide from a solution containing nickel, cerium and zirconium precursors and distilled water or from a solution containing nickel, cerium, zirconium, and magnesium precursors and distilled water, and having a pH of 8.0-9.0. The process is carried out under agitation at a temperature of 40-45° C. for 1-2 hours, followed by filtration, drying at a temperature of 100-110° C. for 6-8 hours, and calcining at a temperature of 400-650° C. for 4-6 hours. The invention provides a high average conversion of natural/associated gas of at least 90% in an autothermal reforming reaction of natural or associated gas, and a high synthesis gas output of at least 7000 m3/m3cat·h.
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公开(公告)号：US10710049B2
公开(公告)日：2020-07-14
申请号：US16470191
申请日：2017-11-02
发明人： Mikhail Nikolaevich Mikhajlov , Dmitrij Aleksandrovich Grigor'ev , Oleg Nikolaevich Protasov , Nikolaj Aleksandrovich Mamonov , Aleksej Eduardovich Bessudnov , Pavel Mikhajlovich Stupakov , Aleksandr Vasil'evich Sandin
摘要： The invention relates to Fischer-Tropsch synthesis in a compact version. A compact reactor comprises a housing, rectangular reaction channels inside the housing, which are filled with a cobalt catalyst, synthesis gas injection nozzles in the number determined by the ratio of the number of channels to the number of synthesis gas injection nozzles, an input and output nozzle for heat transfer medium on which a pressure controller installed, and an assembly for withdrawing synthetic hydrocarbons. The cobalt catalyst is activated by passing hydrogen through it. Synthetic hydrocarbons are produced by passing synthesis gas through the reaction channels filled with the activated cobalt catalyst. The space velocity of synthesis gas is increased every 300-500 h, followed by returning to the initial process conditions. This provides a high-molecular-weight hydrocarbon output per unit mass of the reactor.
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公开(公告)号：US20180128760A1
公开(公告)日：2018-05-10
申请号：US15570039
申请日：2016-04-26
申请人： ROSNEFT OIL COMPANY
发明人： Evgeny Evgenievich Karpov , Alexey Pavlovich Karelin , Alexey Anatolievich Suchkov , Ilya Vladimirovich Roslyakov , Irina Valerievna Kolesnik , Kirill Sergeevich Napolskii
CPC分类号： G01N25/385 , G01N25/32 , G01N27/128 , G01N27/14
摘要： The invention relates to gas analysis and to combustible gas and vapour analyzers based on a thermocatalytic operating principle. The subject of the invention is a sensor the sensitive elements of which are manufactured by planar techniques that can be easily automated. The main distinguishing feature is that a working sensitive element and a reference sensitive element are colocated in a single micron-sized structural component (a microchip) on a common substrate made of porous anodic aluminium oxide. The design of the sensitive elements provides for film-wise heat transfer from heated parts of the working and reference sensitive elements. Measuring microheaters which heat the working and reference sensitive elements up to working temperatures and provide for differentially measuring an output signal in a measuring bridge circuit are spaced apart at opposite sides of the anodic aluminium oxide substrate and are disposed on arms projecting beyond the common substrate configuration. The sensitive elements are disposed in a reaction chamber having restricted diffusion access via a calibrated orifice, and the diameter of regular pores in the microchip substrate is increased to sizes that provide for a predominantly molecular diffusion mode in the pores (100 nm or more).
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公开(公告)号：US09765256B2
公开(公告)日：2017-09-19
申请号：US14786623
申请日：2014-05-13
申请人： ROSNEFT OIL COMPANY
发明人： Vladimir Vladimirovich Afanasiev , Sergey Anatolievich Alkhimov , Nataliya Borisovna Bespalova , Tatyana Modestovna Yumasheva
IPC分类号： C09K8/80 , C08F32/06 , C08F132/06
CPC分类号： C09K8/80 , C08F32/06 , C08F132/06
摘要： The polymer proppant and method for producing the same relate to oil and gas production technology using materials of high-molecular weight compounds with higher requirements for physical and mechanical properties. The proppant is used as propping granules utilized in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant whose material provides a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The polymer proppant represents microspheres of metathesis-radically cross-linked mixture of oligocyclopentadienes.
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公开(公告)号：US20160075939A1
公开(公告)日：2016-03-17
申请号：US14786642
申请日：2014-05-13
发明人： Vladimir Vladimirovich Afanasiev , Sergey Anatolievich Alkhimov , Nataliya Borisovna Bespalova , Egor Vladimirovich Shutko , Tatyana Modestovna Yumasheva
IPC分类号： C09K8/80
CPC分类号： C09K8/80 , C08F220/10
摘要： The material for proppant and method for producing the same relate to the chemistry of high-molecular weight compounds, and more particularly, to polymer materials with high requirements for physical and mechanical properties, for instance, for the production of proppants, i.e., propping granules, used in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant material providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The method consists in the following. A mixture of oligocyclopentadienes is obtained by heating dicyclopentadiene (DCPD) to a temperature of 150-220° C. and holding at this temperature for 15-360 minutes. The oligomerization of dicyclopentadiene occurs. The mixture of oligomers is cooled down to 20-50° C., and polymer stabilizers, radical initiators, methacrylates and a catalyst are sequentially added thereto. The resultant polymer matrix is heated up to a temperature of 50-340° C. and is held at this temperature for 1-360 minutes, and thereafter is cooled down to room temperature. A metathesis polymerization (MP) and radical polymerization (RP) cross-linkage of the mixture of oligocyclopentadienes with methacrylic esters occurs.
摘要翻译： 用于支撑剂的材料及其制备方法涉及高分子量化合物的化学性质，更具体地说涉及对物理和机械性能要求高的聚合物材料，例如用于生产支撑剂，即支撑颗粒 用于石油和天然气生产中通过水力压裂成形的方法。 通过实施本发明的技术结果是在不低于100℃的温度下提供抗压强度至少为150MPa的支撑剂材料的热强度增加。该方法包括以下。 通过将二环戊二烯（DCPD）加热至150-220℃并在该温度下保持15-360分钟来获得低聚环戊二烯的混合物。 发生二环戊二烯的低聚。 将低聚物的混合物冷却至20-50℃，并向其中依次加入聚合物稳定剂，自由基引发剂，甲基丙烯酸酯和催化剂。 将所得聚合物基体加热至50-340℃，并在该温度下保持1-360分钟，然后冷却至室温。 发生低聚环戊二烯与甲基丙烯酸酯的混合物的易位聚合（MP）和自由基聚合（RP）交联。
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公开(公告)号：US20220252748A1
公开(公告)日：2022-08-11
申请号：US17614283
申请日：2019-05-28
发明人： Mathias CONTANT
摘要： Example seismic sensors and methods relating thereto are disclosed. In an embodiment, the seismic sensor includes an outer housing and a proof mass disposed in the inner cavity of the outer housing. In addition, the seismic sensor includes a first biasing member positioned in the inner cavity between the proof mass and an outer housing upper end that is configured to flex in response to axial movement of the outer housing relative to the proof mass. Further, the seismic sensor includes a second biasing member positioned in the inner cavity between the first biasing member and the outer housing upper end. Still further, the seismic sensor includes a sensor element positioned in the inner cavity between the proof mass and an outer housing lower end that is configured to generate a potential in response to movement of the outer housing relative to the proof mass.
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公开(公告)号：US10828599B2
公开(公告)日：2020-11-10
申请号：US16341867
申请日：2017-10-03
发明人： Andrei Anatolievich Eliseev , Artem Anatolievich Eliseev , Dmitrii Igorevich Petukhov , Andrei Aleksandrovich Poyarkov , Alexey Viktorovich Lukashin , Ekaterina Aleksandrovna Chernova , Evgenii Sergeevich Piatkov
摘要： The invention relates to the field of membrane gas separation. A method of removing components of gas mixtures which is based on passing the components of a gas mixture through a nanoporous membrane and subsequently selectively absorbing them with a liquid absorbent that is in contact with the nanoporous membrane, wherein to prevent the gas from getting into the liquid phase of the absorbent and the liquid phase of the absorbent from getting into the gas phase, a nanoporous membrane with homogeneous porosity (size distribution less than 50%) and a pore diameter in the range of 5-500 nm is used, and the pressure differential between the gas phase and the liquid absorbent is kept below the membrane bubble point pressure. An acid gas removal performance of more than 0.3 nm3/(m2 hour) in terms of CO2 is achieved at a hollow-fiber membrane packing density of up to 3200 m2/m3, which corresponds to a specific volumetric performance of acid gas removal of up to 1000 nm3 (m3 hour). The technical result is that of providing effective extraction of undesirable components from natural and process gas mixtures.
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公开(公告)号：US20200016578A1
公开(公告)日：2020-01-16
申请号：US16470190
申请日：2017-11-02
申请人： ROSNEFT OIL COMPANY
发明人： Sergey Aleksandrovich MIKHAJLOV , Gilyana Evgen'evna DZHUNGUROVA , Nikolaj Aleksandrovich MAMONOV , Dmitrij Aleksandrovich GRIGOR'EV , Mikhail Nikolaevich MIKHAJLOV
摘要： A catalyst in a calcined state has a specific surface area of 20-50 m2/g of catalyst, and a specific surface area of nickel metal after reduction of the catalyst of 8 to 11 m2/g, wherein the average particle size of nickel metal is 3-8 nm, the dispersion of the particles is 10-16%, and the content of nickel is 5-15 wt. % based on the weight of calcined catalyst. A support has a specific surface area of 40-120 m2/g with a pore volume of the support of 0.2-0.4 cm3/g, wherein the support is selected from a mixture of zirconium oxide and cerium oxide or magnesium oxide, cerium oxide and the ballast being zirconium oxide. The catalyst further contains a promoter selected from the group consisting of palladium and ruthenium, in an amount of from 0.01 to 0.5 wt. %. The catalyst is prepared by co-precipitation with ammonium hydroxide from a solution containing nickel, cerium and zirconium precursors and distilled water or from a solution containing nickel, cerium, zirconium, and magnesium precursors and distilled water, and having a pH of 8.0-9.0. The process is carried out under agitation at a temperature of 40-45° C. for 1-2 hours, followed by filtration, drying at a temperature of 100-110° C. for 6-8 hours, and calcining at a temperature of 400-650° C. for 4-6 hours. The invention provides a high average conversion of natural/associated gas of at least 90% in an autothermal reforming reaction of natural or associated gas, and a high synthesis gas output of at least 7000 m3/m3cat·h.
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公开(公告)号：US09926487B2
公开(公告)日：2018-03-27
申请号：US14786607
申请日：2014-05-13
发明人： Vladimir Vladimirovich Afanasiev , Sergey Anatolievich Alkhimov , Nataliya Borisovna Bespalova , Egor Vladimirovich Shutko , Tatyana Modestovna Yumasheva , Igor Alekseevich Kiselev , Olga Vasilievna Masloboyschikova
IPC分类号： C09K8/80 , C08F232/06 , C08F220/18
CPC分类号： C09K8/80 , C08F220/18 , C08F232/06
摘要： The increased thermal strength polymer proppant and method for producing the same relate to the oil and gas production technology using materials of high-molecular compounds, especially to proppants of polymer materials with high requirements for the physical and mechanical characteristics, utilized as propping granules in the oil and gas production by a method of hydraulic fracturing. The proppant is made of a metathesis-radically cross-linked mixture of oligocyclopentadienes and methylcarboxy norbornene esters. The proppant represents microspheres having a roundness and sphericity of at least 0.9 for no less than 80% by weight, whose average size being in the range 0.25-1.1 mm and a bulk density being in the range of 0.5-0.7 g/cm3. The technical result is an increase in thermal strength of the proppant material, providing for a compressive strength of at least 150 MPa at a temperature of not less than 100° C.
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公开(公告)号：US20160130498A1
公开(公告)日：2016-05-12
申请号：US14786623
申请日：2014-05-13
发明人： Vladimir Vladimirovich Afanasiev , Sergey Anatolievich Alkhimov , Nataliya Borisovna Bespalova , Tatyana Modestovna Yumasheva
IPC分类号： C09K8/80
CPC分类号： C09K8/80 , C08F32/06 , C08F132/06
摘要： The polymer proppant and method for producing the same relate to oil and gas production technology using materials of high-molecular weight compounds with higher requirements for physical and mechanical properties. The proppant is used as propping granules utilized in the oil and gas production by a method of hydraulic fracturing of formation. The technical result achieved by implementation of the present invention is an increase in thermal strength of the proppant whose material provides a compressive strength of at least 150 MPa at a temperature of not less than 100° C. The polymer proppant represents microspheres of metathesis-radically cross-linked mixture of oligocyclopentadienes.
摘要翻译： 聚合物支撑剂及其制备方法涉及使用对物理和机械性能要求较高的高分子量化合物材料的油气生产技术。 支撑剂用作石油和天然气生产中的支撑颗粒，通过水力压裂成形的方法。 通过实施本发明实现的技术结果是在不低于100℃的温度下其材料提供至少150MPa的抗压强度的支撑剂的热强度的增加。聚合物支撑剂表示复分解的微球 低聚环戊二烯的交联混合物。
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