公开(公告)号：US4473498A

公开(公告)日：1984-09-25

申请号：US288386

申请日：1981-07-30

申请人： Ludwig Schlafer ,  Reinhard Hahnle

发明人： Ludwig Schlafer ,  Reinhard Hahnle

IPC分类号： C07C67/00 ,  C07C313/00 ,  C07C317/44 ,  C09B62/503 ,  C09B62/505 ,  C09B62/51 ,  C09B62/513 ,  C09B62/515 ,  C09B62/517 ,  D06M13/02 ,  D06M13/244 ,  D06M13/248 ,  D06M13/268 ,  D06M13/278 ,  D06M13/322 ,  D06M13/402 ,  D06M13/415 ,  D06M13/438 ,  D06M101/00 ,  D06M101/02 ,  D06M101/06 ,  D06M101/08 ,  D06M101/10 ,  D06M101/16 ,  D06M101/18 ,  D06M101/30 ,  D06M101/34 ,  D06P5/00 ,  C09B62/523 ,  C09B62/525 ,  C09B62/527 ,  C09B62/53 ,  C09B62/535 ,  C09B62/537

CPC分类号： D06M13/278 ,  C09B62/503

摘要： Novel organic, water-soluble compounds having fiber-reactive and fiber-finishing properties and containing, as a fiber-reactive group, one or two .beta.-chloroethylsulfonylmethyl-benzoic acid amide groups. These compounds can be prepared (1) by reacting novel .beta.-chloroethylsulfonylmethyl-benzoic acid halide compounds with an organic, water-soluble compound having fiber-finishing properties and containing one or two amino groups, or (2) analogously to known and usual procedures, from precursors containing the .beta.-chloroethylsulfonylmethyl-benzoic acid amide grouping. The novel fiber-finishing compounds are applied to and fixed on suitable fiber materials, especially cellulose fiber material and natural or synthetic polyamide fiber materials, by methods corresponding to those which are conventional for application and fixation of fiber-reactive compounds. The above-mentioned .beta.-chloroethylsulfonylmethyl-benzoic acid halides are synthesized by monochlorinating the methyl grouping of a toluenecarboxylic acid or an alkyl ester thereof or an acid halide thereof, converting this monochlorinated compound by reaction with 2-mercaptoethanol in aqueous solution, optionally with simultaneous hydrolysis of the carboxylic acid chloride group, to form the thioether compound, hydrolyzing the carbalkoxy grouping optionally present in this thioether compound, and then oxidizing said thioether compound by means of an oxidizing agent to form the corresponding sulfonyl compound; the .beta.-hydroxyethylsulfonylmethyl grouping is subsequently reacted with a chlorinating agent.

摘要翻译： 具有纤维反应性和纤维整理性能的新型有机水溶性化合物，作为纤维反应性基团含有一个或两个β-氯乙基磺酰基甲基 - 苯甲酸酰胺基团。 这些化合物可以通过使新的β-氯乙基磺酰基甲基 - 苯甲酸卤化物与具有纤维整理性质并含有一个或两个氨基的有机水溶性化合物反应来制备（1），或（2）类似于已知和常规方法 ，来自含有β-氯乙基磺酰基甲基 - 苯甲酸酰胺基团的前体。 通过与常规用于纤维反应性化合物的施用和固定的方法相对应的方法，将新型纤维整理剂施用并固定在合适的纤维材料，特别是纤维素纤维材料和天然或合成聚酰胺纤维材料上。 上述β-氯乙基磺酰基甲基 - 苯甲酸卤化物是通过一甲基甲苯甲酸或其烷基酯或其酰卤单氯化合成的，通过与2-巯基乙醇在水溶液中的反应转化该一氯化合物，任选地同时 水解羰基氯化物基团，形成硫醚化合物，水解任选存在于该硫醚化合物中的烷氧基，然后用氧化剂氧化所述硫醚化合物，形成相应的磺酰化合物; 然后将β-羟乙基磺酰基甲基与氯化剂反应。

公开(公告)号：US3939141A

公开(公告)日：1976-02-17

申请号：US430485

申请日：1974-01-03

申请人： Fritz Meininger ,  Reinhard Hahnle

发明人： Fritz Meininger ,  Reinhard Hahnle

IPC分类号： C09B62/515 ,  C09B45/18 ,  C09B62/44 ,  C09B62/74 ,  C09B62/82

CPC分类号： C09B62/515

摘要： Copper containing monoazo dyestuffs of the general formula ##SPC1##Wherein X is-- SO.sub.2 -- CH.sub.2 -- CH.sub.2 -- Z or-- SO.sub.2 -- CH = CH.sub.2in which Z is hydroxy or an inorganic or organic radical capable of being split off by alkaline agents. The said dyestuffs are easily soluble in water in the form of their alkali metal salts giving blue solutions which may be used for the dyeing or printing of nitrogen containing fibrous materials, materials containing hydroxyl groups or modified polyacrylonitrile fibrous materials, the dyeings obtained on wool or cellulose fibres being distinguished by high tinctorial strength and good fastness properties in general, and in particular to light, to wet processing, to weather, to chlorinated water and to hypochlorite.

摘要翻译： 具有通式的含铜单偶氮染料WHEREIN X是-SO 2 -CH 2 -CH 2 - Z或-SO 2 -CH = CH 2，其中Z是羟基或能够被碱性试剂分解的无机或有机基团。 所述染料以其碱金属盐的形式易溶于水，得到蓝色溶液，其可用于含氮纤维材料，含羟基或改性聚丙烯腈纤维材料的材料的染色或印刷，羊毛或 纤维素纤维通常具有高的着色强度和良好的坚牢度特性，特别是对于湿处理，耐候性，耐氯化水和次氯酸盐的区别。

公开(公告)号：US5430147A

公开(公告)日：1995-07-04

申请号：US161757

申请日：1993-12-03

申请人： Jorg Dannheim ,  Reinhard Hahnle ,  Werner H. Russ

发明人： Jorg Dannheim ,  Reinhard Hahnle ,  Werner H. Russ

IPC分类号： C09B62/06 ,  C07C261/04 ,  C09B62/44 ,  C07D251/00

CPC分类号： C09B62/4409 ,  C07C261/04 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/924

摘要： Water-soluble anthraquinone compounds, preparation thereof, and use thereof as dyes.There are described anthraquinone compounds conforming to the formula (1) ##STR1## where A is the radical of a sulfo-containing anthraquinone radical,R.sup.1 and R.sup.2 are each independently of the other hydrogen or lower alkyl,X is an alkali-detachable radical, such as fluorine and chlorine,R is hydrogen, lower alkyl or lower alkoxy, andM is hydrogen or an alkali metal.The anthraquinone compounds have fiber-reactive properties and are used as dyes for dyeing and printing hydroxy- and/or carboxamido-containing material, in particular fiber material, for example cellulose fiber materials, wool and synthetic polyamide, in brilliant blue shades.

摘要翻译： 水溶性蒽醌化合物，其制备方法及其作为染料的用途。 描述符合式（1）的蒽醌化合物其中A是含磺基蒽醌基团的基团，R 1和R 2各自独立于另一个氢或低级烷基，X是碱金属化合物， 可分离的基团如氟和氯，R是氢，低级烷基或低级烷氧基，M是氢或碱金属。 蒽醌化合物具有纤维反应性，并用作用于染色和印刷含有羟基和/或羧酰氨基的材料，特别是纤维材料，例如纤维素纤维材料，羊毛和合成聚酰胺，以明亮的蓝色色调的染料。

公开(公告)号：US5227475A

公开(公告)日：1993-07-13

申请号：US776305

申请日：1992-01-10

申请人： Holger M. Buch ,  Reinhard Hahnle ,  Hartmut Springer

发明人： Holger M. Buch ,  Reinhard Hahnle ,  Hartmut Springer

IPC分类号： C09B62/503 ,  C09B62/44 ,  D06P1/384 ,  D06P3/10 ,  D06P3/66

CPC分类号： C09B62/4403 ,  C09B62/503 ,  Y10S8/918 ,  Y10S8/921

摘要： Water-soluble dyestuffs which correspond to the formula (1) given below, have fiber-reactive properties and dye synthetic and natural materials, in particular fiber materials, containing hydroxyl and/or carboxamide groups, such as wool and in particular cellulose fiber materials, in deep shades ##STR1## in which: F is the radical of a dyestuff, such as of an azo dyestuff, heavy metal complex azo dyestuff, anthraquinone dyestuff or phthalocyanine dyestuff,R.sup.x is hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato;n is the number 1 or 2; andQ is a group of the formula ##STR2## in whichR.sup.z is hydrogen or lower alkyl, which can be substituted by halogen, hydroxyl, cyano, lower alkoxy, carboxyl, sulfamoyl, sulfo, sulfato or by optionally substituted phenyl, or is cyclohexyl or optionally substituted phenyl, W is optionally substituted arylene or a combined radical of alkylene and arylene, in which the alkylene radicals and arylene radicals can be substituted and the alkylene radicals and alkylene-arylene radicals can likewise be interrupted by hetero groups; the group --SO.sub.2 --Y is a fiber-reactive group from the vinylsulfone series, z is the number 1 or 2, A is the number zero or 1, B is the number 1 or 2, the sum of (A+B) being 2, X, together with the N atom and 1 or 2 lower alkylene groups and if appropriate 1 or 2 hetero groups, forms the radical of a heterocyclic ring and alk is a lower alkylene,are described.

摘要翻译： PCT No.PCT / EP90 / 00715 Sec。 371日期1992年1月10日 102（e）日期1992年1月10日PCT提交1990年5月4日PCT公布。 出版物WO90 / 13604 1990年11月15日。对应于下面给出的式（1）的水溶性染料具有纤维反应性质和染料合成和天然材料，特别是含有羟基和/或羧酰胺基团的纤维材料，例如羊毛 特别是纤维素纤维材料，其中：F是染料的基团，例如偶氮染料，重金属络合物偶氮染料，蒽醌染料或酞菁染料，Rx是氢或 羟基，氰基，低级烷氧基，低级烷氧基羰基，羧基，氨磺酰基，磺基或硫酸根取代的低级烷基; n是数字1或2; 其中Rz是氢或低级烷基，其可以被卤素，羟基，氰基，低级烷氧基，羧基，氨磺酰基，磺基， 硫酸根或任选取代的苯基，或是环己基或任选取代的苯基，W是任选取代的亚芳基或亚烷基和亚芳基的组合基团，其中亚烷基和亚芳基可以被取代，并且亚烷基和亚烷基 - 亚芳基可以 同样被杂基中断; 基团-SO 2 -Y是来自乙烯基砜系列的纤维反应性基团，z是数字1或2，A是数字0或1，B是数字1或2，（A + B）的和 2，X与N原子和1或2个低级亚烷基，如果合适的话，1或2个杂原子形成杂环基，而alk是低级亚烷基。

公开(公告)号：US4422854A

公开(公告)日：1983-12-27

申请号：US383732

申请日：1982-06-01

申请人： Reinhard Hahnle ,  Manfred Schneider ,  Claus Schuster ,  Rudolf Schickfluss

发明人： Reinhard Hahnle ,  Manfred Schneider ,  Claus Schuster ,  Rudolf Schickfluss

IPC分类号： D06P5/00 ,  B41J2/325 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  D06P5/28 ,  B41M5/02

CPC分类号： D06P5/006 ,  Y10S8/922

摘要： Transfer printing supports impregnated or printed with a formulation containing a dyestuff of the formula I ##STR1## in which R.sup.1 is alkyl having from 1 to 4 carbon atoms, R.sup.2 is hydrogen or has the meaning of R.sup.1, R.sup.3 is methyl, methoxy or ethoxy, and R.sup.4 is hydrogen, methyl, methoxy or ethoxy, or containing mixtures of such dyestuffs, a process for the manufacture of these supports, which comprises impregnating or printing the support material with formulations containing a dyestuff of the formula I or mixtures of such dyestuffs, and the use of these supports for the dyeing and printing of flat web or sheet structures of synthetic or natural materials according to the heat transfer printing process.

摘要翻译： 用含有式I的染料（I）的制剂浸渍或印刷的转印印刷载体，其中R 1是具有1至4个碳原子的烷基，R 2是氢或具有R 1的意义，R 3是甲基，甲氧基 或乙氧基，R 4为氢，甲基，甲氧基或乙氧基，或含有这些染料的混合物，制备这些载体的方法，其包括用含有式I染料的制剂浸渍或印刷载体材料或 这种染料，以及根据热转印印刷方法使用这些载体用于染色和印刷合成或天然材料的平板或片状结构。

公开(公告)号：US09402745B2

公开(公告)日：2016-08-02

申请号：US12624631

申请日：2009-11-24

申请人： Malan de Villiers ,  Ulrich Reinhard Hahnle

发明人： Malan de Villiers ,  Ulrich Reinhard Hahnle

IPC分类号： A61F2/46 ,  A61F2/44 ,  A61B17/17 ,  A61F2/30

CPC分类号： A61B17/025 ,  A61B17/1671 ,  A61B17/1757 ,  A61B90/39 ,  A61B2017/0256 ,  A61B2090/3916 ,  A61F2/44 ,  A61F2/442 ,  A61F2/4657 ,  A61F2002/3008 ,  A61F2002/4658 ,  A61F2250/0098

摘要： The invention concerns an intervertebral prosthesis placement instrument which can be used to facilitate accurate positioning of a spinal disc prosthesis between adjacent spinal vertebrae. The instrument (10) has opposed jaws 12 formed with tips (24) that are shaped for insertion between the vertebrae. The jaws can be moved apart from one another to distract the vertebrae, allowing the prosthesis to enter between the vertebrae. The jaws also have opposed surfaces which are shaped to embrace the prosthesis between them and to guide the prosthesis into position.

摘要翻译： 本发明涉及一种椎间假体放置器械，其可以用于促进椎间盘假体在相邻脊椎椎骨之间的精确定位。 仪器（10）具有形成有尖端（24）的相对的钳口12，其被成形为用于插入在椎骨之间。 颌骨可以彼此分开移动以分散椎骨，允许假体进入椎骨之间。 钳口还具有相对的表面，其被成形为在它们之间包围假体并且将假体引导到位。

公开(公告)号：US4845202A

公开(公告)日：1989-07-04

申请号：US113528

申请日：1987-10-23

申请人： Ludwig Schlafer ,  Hartmut Springer ,  Reinhard Hahnle

发明人： Ludwig Schlafer ,  Hartmut Springer ,  Reinhard Hahnle

IPC分类号： C09B62/09 ,  C09B62/44 ,  C09B62/513 ,  D06P1/38 ,  D06P3/872

CPC分类号： C09B62/4415

摘要： Water-soluble disazo compounds having useful fiber-reactive dye properties, which conform to the general formula (1) defined hereinafter and dye carboxamido- and/or hydroxy-containing materials in fast shades. Fast dyeings on cellulose fiber materials can also be obtained in a weakly acid to neutral pH range, for example together with disperse dyes for dyeing a polyester fiber portion. ##STR1## in which: A is phenylene which may be substituted by methyl, ethyl, methoxy, chlorine or sulfo, or is a radical of the formula ##STR2## in which G is a direct bond or a group of the formula --CH.dbd.CH-- or --NH--CO--NH-- and R.sup.1 and R.sup.2 are each independently of the other hydrogen, sulfo, methyl, ethyl, methoxy or ethoxy;D is phenylene which may be substituted by methyl, ethyl, methoxy, ethoxy, sulfo, carboxy, chlorine or bromine, or is naphthalene which may be substituted by sulfo or is a group of the formula ##STR3## and K, as a radical of a coupling component, is a radical of the formula ##STR4## in which M is hydrogen or an alkali metal and R.sup.o is hydrogen or sulfo and the free azo-bond in the amino-naphthol radical is ortho to the hydroxy group, R* is hydrogen, methyl or ethyl and the benzene nucleus a can be substituted by methyl, ethyl, methoxy, ethoxy lower alkanoylamino, benzoylamino, ureido or chlorine;X is vinyl, .beta.-sulfatoethyl or .beta.-chloroethyl;R is carboxy or carbamoyl.

摘要翻译： 具有适用于纤维反应性染料性质的水溶性双偶氮化合物，其符合下文定义的通式（1），并以快速色调染料甲酰胺基和/或羟基的材料。 纤维素纤维材料上的快速染色也可以在弱酸性至中性pH范围内获得，例如与用于染色聚酯纤维部分的分散染料一起获得。 （1）其中：A是可以被甲基，乙基，甲氧基，氯或磺基取代的亚苯基，或者是其中G是直接键的式“IMAGE”的基团或式 -CH = CH-或-NH-CO-NH-，R 1和R 2各自独立地为氢，磺基，甲基，乙基，甲氧基或乙氧基; D是可以被甲基，乙基，甲氧基，乙氧基，磺基，羧基，氯或溴取代的亚苯基，或者是可以被磺基取代的萘或者是作为式 偶联组分是式（I）的基团，其中M是氢或碱金属，而R o是氢或磺基，氨基萘酚基中的游离的偶氮键是羟基的邻位，R *是 氢，甲基或乙基，苯核a可被甲基，乙基，甲氧基，乙氧基低级烷酰氨基，苯甲酰氨基，脲基或氯取代; X是乙烯基，β-磺基乙基或β-氯乙基; R是羧基或氨基甲酰基。

公开(公告)号：US4552699A

公开(公告)日：1985-11-12

申请号：US560919

申请日：1983-12-13

申请人： Reinhard Hahnle ,  Theodor Grewer

发明人： Reinhard Hahnle ,  Theodor Grewer

IPC分类号： C07C231/02 ,  C07C67/00 ,  C07C231/00 ,  C07C233/43 ,  C07C233/78 ,  C07C233/80 ,  C07C102/04

CPC分类号： C07C231/02

摘要： A process for the preparation of 3-acylaminoanilines of the general formula (1) ##STR1## in which R denotes a branched or unbranched alkyl radical having 1-7 carbon atoms or the phenyl group, which can be substituted by 1-2 methyl groups or by 1-2 chlorine atoms, which comprises reacting a carboxylic acid of the general formula (2)R--COOH (2)in which R has the meaning mentioned, with an excess of 1,3-diaminobenzene, and separating the reaction mixture by distillation.

摘要翻译： 制备通式（1）的3-酰基氨基苯胺的方法其中R表示具有1-7个碳原子的支链或非支链烷基或苯基，其可以被1- 2个甲基或1-2个氯原子，其包括使通式（2）的羧酸与其中R具有上述含义的R-COOH（2）与过量的1,3-二氨基苯反应，并分离 反应混合物通过蒸馏。

公开(公告)号：US4430090A

公开(公告)日：1984-02-07

申请号：US409585

申请日：1982-08-19

申请人： Ulrich Buhler ,  Reinhard Hahnle ,  Joachim Ribka ,  Helmut Richter

发明人： Ulrich Buhler ,  Reinhard Hahnle ,  Joachim Ribka ,  Helmut Richter

IPC分类号： C08K5/00 ,  C08J3/20 ,  C08K5/22 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L101/00 ,  C09B29/08 ,  C09B43/42 ,  C10L1/00 ,  C10M171/00 ,  C08K5/23 ,  C10L1/22

CPC分类号： C10L1/003 ,  C09B29/081 ,  C09B43/42 ,  C10M171/007 ,  Y10S534/01 ,  Y10S8/928 ,  Y10S8/938

摘要： Dyestuffs of the formula ##STR1## are used for coloring organic solvents, mineral oil products, waxes, plastics and surface coatings, wherein R is alkyl having 1 to 7 carbon atoms, R.sup.1 is alkyl having 1 to 8 carbon atoms or alkenyl having 3 or 4 carbon atoms, and R.sup.2 is hydrogen, alkyl having 1 to 8 carbon atoms or alkenyl having 3 or 4 carbon atoms.

摘要翻译： 具有式的染料用于着色有机溶剂，矿物油产品，蜡，塑料和表面涂层，其中R是具有1至7个碳原子的烷基，R 1是具有1至8个碳原子的烷基或具有3或 4个碳原子，R 2是氢，具有1至8个碳原子的烷基或具有3或4个碳原子的烯基。

公开(公告)号：US4381262A

公开(公告)日：1983-04-26

申请号：US349574

申请日：1982-02-17

申请人： Ulrich Buhler ,  Dieter Cornelius ,  Rudolf Lowenfeld ,  Uwe Kosubek ,  Reinhard Hahnle ,  Rudolf Schickfluss

发明人： Ulrich Buhler ,  Dieter Cornelius ,  Rudolf Lowenfeld ,  Uwe Kosubek ,  Reinhard Hahnle ,  Rudolf Schickfluss

IPC分类号： C09B29/085 ,  C09B29/08 ,  C09B43/42

CPC分类号： C09B43/42 ,  C09B29/081

摘要： An azo dyestuff of the formula ##STR1## wherein R is linear alkyl having 2 to 4 carbon atoms and R' is linear alkyl having 3 to 5 carbon atoms and isopropyl.

摘要翻译： 式IMA的偶氮染料，其中R是具有2至4个碳原子的直链烷基，R'是具有3至5个碳原子的直链烷基和异丙基。