公开(公告)号：US07223890B2

公开(公告)日：2007-05-29

申请号：US10683241

申请日：2003-10-10

申请人： David A. Radovich ,  Richard G. Skorpenske ,  Gary W. Munko

发明人： David A. Radovich ,  Richard G. Skorpenske ,  Gary W. Munko

IPC分类号： C00C43/00

CPC分类号： C08G18/4009 ,  C08G18/283 ,  C08G18/2865 ,  C08G18/4866 ,  C08G18/61

摘要： The present invention relates to an improved isocyanate reactive mixture containing at least one DMC-catalyzed polyol and about 0.25 to about 15 wt. %, based on the total weight of the isocyanate-reactive mixture, of at least one ethylene oxide (EO) containing water compatibilizer. The isocyanate reactive mixtures of the present invention may find use in the preparation of polyurethane foams, coatings, elastomers, sealants, adhesives and the like.

摘要翻译： 本发明涉及含有至少一种DMC催化的多元醇和约0.25至约15wt。％的改进的异氰酸酯反应混合物。 基于异氰酸酯反应性混合物的总重量，含有至少一种含有水相增容剂的环氧乙烷（EO）。 本发明的异氰酸酯反应性混合物可用于制备聚氨酯泡沫，涂料，弹性体，密封剂，粘合剂等。

公开(公告)号：US5373028A

公开(公告)日：1994-12-13

申请号：US137309

申请日：1993-10-15

申请人： Carl D. McAfee ,  Richard G. Skorpenske ,  Don H. Ridgway ,  Stephen K. Lewis ,  Eugene P. Wiltz, Jr.

发明人： Carl D. McAfee ,  Richard G. Skorpenske ,  Don H. Ridgway ,  Stephen K. Lewis ,  Eugene P. Wiltz, Jr.

IPC分类号： C08G18/40 ,  C08G20060101 ,  C08G18/00 ,  C08G18/08 ,  C08G18/48 ,  C08G18/50 ,  C08G101/00 ,  C08J9/00 ,  C08L75/04

CPC分类号： C08J9/0004 ,  C08G18/40 ,  C08G18/4829 ,  C08G18/4837 ,  C08G18/4883 ,  C08G18/5021 ,  C08J9/0066 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  C08J2375/04

摘要： In a method of preparing a poly-urethane and/or -urea foam from a formulation including (a) a polyisocyanate, (b) an isocyanate-reactive component, and (c) a visible emissions producing component, wherein (a), (b) and (e) are reacted under reaction conditions sufficient to form a poly-urethane and/or -urea foam and the foam is then cooled, whereby visible emissions are emitted during cooling, an improvement comprising including in the formulation a visible emissions reducing agent, such that the amount of the visible emissions is reduced as compared with the amount emitted by a foam prepared from a formulation which does not contain the visible emissions reducing agent but which is otherwise substantially similar. Foams prepared therefrom exhibit reduction in visible emissions during the cure period, which is particularly evident when the foams are mechanically cooled. They also exhibit generally good physical properties.

摘要翻译： 在制备包含（a）多异氰酸酯，（b）异氰酸酯反应性组分和（c）可见发射产生组分的制剂中的聚氨酯和/或脲泡沫的方法中，其中（a），（ b）和（e）在足以形成聚氨酯和/或脲泡沫的反应条件下反应，然后将泡沫冷却，从而在冷却期间发射可见的排放物，其改进包括在制剂中包括可见的减排 使得与由不含可见光发射减少剂但其基本类似的制剂制备的泡沫的量相比，可见光的释放量减少。 由此制备的泡沫在固化期间可见的排放减少，这在泡沫机械冷却时尤为明显。 它们也表现出通常良好的物理性质。

公开(公告)号：US5182310A

公开(公告)日：1993-01-26

申请号：US736270

申请日：1991-07-25

申请人： Richard G. Skorpenske ,  Alan K. Schrock

发明人： Richard G. Skorpenske ,  Alan K. Schrock

IPC分类号： C08G18/28 ,  C08K5/00

CPC分类号： C08G18/28 ,  C08K5/005

摘要： The present invention refers to isocyanate-reactive compositions containing hindered phenolic antioxidants having a molecular weight of at least 700. These compositions, when used to prepare flexible polyurethane foams, especially slabstock foam, provide foams which exhibit a significant reduction of scorch.

摘要翻译： 本发明涉及含有分子量至少为700的受阻酚抗氧化剂的异氰酸酯反应性组合物。当用于制备柔性聚氨酯泡沫，特别是块状泡沫塑料时，这些组合物提供显着降低焦烧的泡沫。

公开(公告)号：US20130023599A1

公开(公告)日：2013-01-24

申请号：US13627127

申请日：2012-09-26

申请人： Yu-Ling Hsiao ,  Richard G. Skorpenske ,  Bryan D. Kaushiva ,  Kenneth G. McDaniel ,  Jose F. Pazos ,  Stanley L. Hager ,  Karl W. Haider

发明人： Yu-Ling Hsiao ,  Richard G. Skorpenske ,  Bryan D. Kaushiva ,  Kenneth G. McDaniel ,  Jose F. Pazos ,  Stanley L. Hager ,  Karl W. Haider

IPC分类号： C07C51/367 ,  C08G18/68

CPC分类号： C08G18/4891 ,  C08G18/4866 ,  C08G2101/0008 ,  C08G2101/005

摘要： The present invention provides polyurethane foams and elastomers made with an alkoxylated vegetable oil hydroxylate replacing at least a portion of the typically used petroleum-based polyol(s). Also provided are processes for making the inventive foams and elastomers and for making alkoxylated vegetable oil hydroxylates. The alkoxylated vegetable oil hydroxylates are environmentally-friendly, bio-based polyols which advantageously also offer the potential of improved hydrophobicity in polyurethane foams and elastomers. The inventive polyurethane foams and elastomers may find use in a wide variety of products such as automobile interior parts, polyurethane structural foams, floor coatings and athletic running tracks.

摘要翻译： 本发明提供用烷氧基化植物油羟基化物制备的聚氨酯泡沫和弹性体，代替至少一部分通常使用的石油基多元醇。 还提供了制备本发明的泡沫和弹性体以及用于制备烷氧基化植物油羟基化物的方法。 烷氧基化植物油羟基化物是环境友好的基于生物的多元醇，其有利地还提供聚氨酯泡沫和弹性体中改善的疏水性的潜力。 本发明的聚氨酯泡沫和弹性体可以用于各种各样的产品，例如汽车内部部件，聚氨酯结构泡沫，地板涂料和运动跑道。

公开(公告)号：US5618854A

公开(公告)日：1997-04-08

申请号：US390391

申请日：1995-02-16

申请人： Richard G. Skorpenske ,  Alan K. Schrock

发明人： Richard G. Skorpenske ,  Alan K. Schrock

IPC分类号： C08G18/65 ,  C08G18/32

CPC分类号： C08G18/657 ,  C08G18/6517 ,  C08G18/6535 ,  C08G2101/0008 ,  C08G2101/0041 ,  C08G2101/0083

摘要： Disclosed is an active hydrogen-containing composition suitable for the production of flexible polyurethane foam when reacted with a polyisocyanate, said composition comprising,(a) a polyol having an average functionality of about 2.0 to about 4.0, and an equivalent weight in the range of from about 500 to about 5000;(b) from about 0.5 to about 5 parts, per 100 parts by weight of component (a), of a crosslinker selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, methylene bis(o-chloroaniline) and mixtures thereof; and(c) from about 0.3 to about 15 parts per 100 parts by weight of component (a), of a compound having at least 3 hydroxyl groups, at least two of which are secondary hydroxyl groups; and an equivalent weight of less than about 500;as well as flexible polyurethane foams prepared therefrom. The active hydrogen-containing composition of the invention has been discovered to be useful in the production of polyurethane foams which pass certain standard laboratory flammability tests.

摘要翻译： 公开了一种适用于在与多异氰酸酯反应时生产柔性聚氨酯泡沫的活性含氢组合物，所述组合物包含（a）平均官能度为约2.0至约4.0的多元醇和在 约500至约5000; （b）每100重量份组分（a）约0.5至约5份，选自单乙醇胺，二乙醇胺，三乙醇胺，单异丙醇胺，二异丙醇胺，亚甲基双（邻氯苯胺）和混合物的混合物 的; 和（c）每100重量份组分（a）约0.3至约15份具有至少3个羟基的化合物，其中至少两个是仲羟基; 并且当量重量小于约500; 以及由其制备的柔性聚氨酯泡沫。 已经发现本发明的含活性氢的组合物可用于生产通过某些标准实验室可燃性试验的聚氨酯泡沫体。