Aqueous coating composition
    1.
    发明授权
    Aqueous coating composition 失效
    水性涂​​料组合物

    公开(公告)号:US06297311B1

    公开(公告)日:2001-10-02

    申请号:US09055464

    申请日:1998-04-06

    IPC分类号: C08J8300

    摘要: An aqueous coating composition comprising a dispersion in an aqueous medium of an acrylic addition polymer having carboxyl groups in which a proportion of the carboxyl groups are derived from a carboxyl functional chain transfer agent, the composition also comprising a base in an amount sufficient to at least partially neutralise the carboxyl groups on the polymer.

    摘要翻译: 一种水性涂料组合物,其包含在具有羧基的丙烯酸加成聚合物的水性介质中的分散体,其中一部分羧基衍生自羧基官能团转移剂,所述组合物还包含足以至少 部分中和聚合物上的羧基。

    Silicon containing compounds
    2.
    发明授权

    公开(公告)号:US07064174B2

    公开(公告)日:2006-06-20

    申请号:US10203203

    申请日:2001-02-07

    IPC分类号: C08G77/26

    摘要: A silicon containing adduct having the formula (I) wherein X is an electron withdrawing group selected from the group consisting of carbonyl and sulphone groups, sulphonium and phosphonium salts; R is selected from the group consisting of hydrogen, linear and branched alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, aryl, alkaryl, aralkyl, alkoxyaryl, alkoxyalkyl, oligoalkoxyalkyl, di-alkylaminoalkyl, N-aryl-N-alky-laminoalkyl, hydroxyalkoxy, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, cycloalkenyloxy, cycloalkynyloxy, aralkoxy, alkoxyaryloxy, alkoxyalkoxy, oligoalkoxyalkoxy, di-alkylaminoalkoxy, N-aryl-N-alkylamino-alkoxy, acyloxy, acyloxyalkyl, N-diacyl-iminoalkyl groups, organosilane, organosiloxane, hydroxyaryl, hydroxyalkenyl, hydroxyalkynyl and hydroxy groups and any of the above groups substituted with one or more hydroxyl or xzwitterionic group Z, or R—X— is a nitrile group; R3 and R4 are individually selected from the group consisting of hydrogen, linear and branched alkyl, alkenyl, and alkynyl groups, aryl, alkoxycarbonyl, alkylaminocarbonyl, cycloalkyl, cycloalkenyl, cycloalkynyl, haloaryl, haloalkyl, alkaryl, aralkyl, alkoxyaryl, alkoxyalkyl, oligoalkoxyalkyl, aminoalkyl, mono- and di-alkylaminoalkyl, arylaminoalkyl, N-aryl-N-alkylaminoalkyl and -aminoaryl, acyloxy, acyloxyalkyl, acylaminoalkyl, N-diacyl-iminoalkyl groups, alkylaminocarbonyl, oxacycloalkyl, oxacycloalkenyl, organosilane and organosiloxane groups and any of the above groups substituted with a zwitterionic group Z, a hydroxyl group or an isocyanate group; R1 and R2 are individually selected from hydrogen and C1-12 alkyl groups; and at least one of groups R, R3, and R4 contain an organosiloxane group Y and/or an organosilane group U. The invention additionally provides processes for the production of such an adduct, polymers formed therefrom, coating processes and compositions comprising an adduct or polymers produced therefrom

    Polymer solutions
    3.
    发明授权
    Polymer solutions 有权
    聚合物溶液

    公开(公告)号:US06841639B1

    公开(公告)日:2005-01-11

    申请号:US09979682

    申请日:2000-05-30

    CPC分类号: C08F246/00

    摘要: Copolymers of zwitterionic monomer, especially 2-methacryloyloxyethyl-2′-trimethylammoniumethyl phosphate inner salt, and hydrophobic comonomer, especially dodecylmethacrylate, are made in a monomer starved polymerization process in which solutions of monomers are fed to the reaction vessel in which initiator is present over an extended period. The copolymers have improved compositional uniformity and provide better coatings on a range of substrates. The novel copolymers can be distinguished from prior art batch type bulk solution polymerization polymers of the same monomer composition by solubility characteristics especially in alcohol/water mixtures. Particularly preferred coating compositions comprise an alcohol:water mixture containing around 20 to 40% by volume alcohol.

    摘要翻译: 两性离子单体的共聚物,特别是2-甲基丙烯酰氧基乙基-2'-三甲基铵乙基磷酸酯内盐和疏水性共聚单体,特别是十二烷基甲基丙烯酸酯,是在单体缺乏聚合方法中制备的,其中将单体溶液加入到其中存在引发剂的反应容器中 一段时间 共聚物具有改善的组成均匀性并在一系列基材上提供更好的涂层。 新型共聚物可以区别于具有相同单体组成的现有技术的分散型本体溶液聚合物,其溶解性特别是在醇/水混合物中。 特别优选的涂料组合物包含含有约20至40体积%的醇的醇:水混合物。

    Zwitterionic groups containing compounds from michael-type reactions useful as monomers and macromers
    5.
    发明授权
    Zwitterionic groups containing compounds from michael-type reactions useful as monomers and macromers 有权
    含有来自迈克尔型反应的化合物的两性离子基团可用作单体和大分子单体

    公开(公告)号:US06828029B1

    公开(公告)日:2004-12-07

    申请号:US10203212

    申请日:2002-10-04

    IPC分类号: B32B2520

    摘要: A zwitterion containing an adduct having the formula (I) wherein Z is a zwitterionic group; X is an electron withdrawing group selected from the group consisting of carbonyl and sulphone groups, sulphonium and phosphonium salts; R is a difunctional organic group; A is O or NR6 where R6 is hydrogen or lower alkyl; R1 and R2 are independently selected from hydrogen and C1-C12 alkyl groups; and R3 is hydrogen or an organic group; R4 is an organic group, preferably an optionally substituted alkyl group, an organopolysiloxane group, an organosilyl group or an oligo alkoxyalkyl group. The invention additionally provides processes for the production of such an adduct, polymers formed therefrom, coating processes and compositions comprising an adduct or polymers produced therefrom.

    摘要翻译: 含有具有式(I)的加合物的两性离子,其中Z是两性离子基团; X是选自羰基和砜基,锍盐和鏻盐的吸电子基团; R是双官能有机基团; A是O或NR 6,其中R 6是氢或低级烷基; R 1和R 2独立地选自氢和C 1 -C 12烷基; 和R 3是氢或有机基团; R 4是有机基团,优选任选取代的烷基,有机聚硅氧烷基团,有机甲硅烷基或低级烷氧基烷基。 本发明另外提供了生产这种加合物的方法,由其形成的聚合物,包括加工物或由其制备的聚合物的包衣方法和组合物。