公开(公告)号：US08268943B2

公开(公告)日：2012-09-18

申请号：US13454574

申请日：2012-04-24

申请人： Ricky McCormick ,  David Knoeppel

发明人： Ricky McCormick ,  David Knoeppel

IPC分类号： C08F4/24 ,  C08F2/00 ,  B01J23/00

CPC分类号： C08F210/16 ,  C08F4/22 ,  C08F4/69 ,  C08F4/24 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/07

摘要： A process for the preparation of a chromium-type supported olefin polymerization catalyst. A fluidized bed of support particles in an inert carrier gas is established. A chromium (III) compound is added to the fluidized support particles to provide a supported catalyst component. The supported catalyst component is activated to convert at least a portion of the chromium (III) to Chromium (VI). The chromium (III) containing particles may be recovered from the fluidized bed and then activated or they may be activated in the fluidized bed. Also the support particles can be treated in the fluidized bed with other treatment agents. The support particles may be pretreated with a solution of a boron treating agent prior to incorporation of the support in the fluidized bed.

公开(公告)号：US08258246B2

公开(公告)日：2012-09-04

申请号：US12012038

申请日：2008-01-31

申请人： Ricky McCormick ,  David Knoeppel

发明人： Ricky McCormick ,  David Knoeppel

IPC分类号： C08F2/00 ,  C08F4/24 ,  C08F210/00 ,  C08F110/02

CPC分类号： C08F210/16 ,  C08F4/22 ,  C08F4/69 ,  C08F4/24 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/07

摘要： A process for the preparation of a chromium-type supported olefin polymerization catalyst. A fluidized bed of support particles in an inert carrier gas is established. A chromium (III) compound is added to the fluidized support particles to provide a supported catalyst component. The supported catalyst component is activated to convert at least a portion of the chromium (III) to Chromium (VI). The chromium (III) containing particles may be recovered from the fluidized bed and then activated or they may be activated in the fluidized bed. Also the support particles can be treated in the fluidized bed with other treatment agents. The support particles may be pretreated with a solution of a boron treating agent prior to incorporation of the support in the fluidized bed.

摘要翻译： 一种制备铬型负载型烯烃聚合催化剂的方法。 建立了惰性载气中载体颗粒的流化床。 向流化载体颗粒中加入铬（III）化合物以提供负载型催化剂组分。 活化负载的催化剂组分以将至少一部分铬（III）转化为铬（VI）。 含有铬（III）的颗粒可以从流化床中回收，然后活化，或者它们可以在流化床中活化。 还可以在流化床中用其它处理剂处理载体颗粒。 在将载体引入流化床之前，载体颗粒可以用硼处理剂的溶液进行预处理。

公开(公告)号：US20120108769A1

公开(公告)日：2012-05-03

申请号：US12914071

申请日：2010-10-28

申请人： Ricky McCormick ,  Steven Gray ,  Tim Coffy ,  David Knoeppel

发明人： Ricky McCormick ,  Steven Gray ,  Tim Coffy ,  David Knoeppel

IPC分类号： C08F4/76 ,  C08F210/06 ,  C08F10/02

CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/06 ,  C08F210/16 ,  C08F4/76 ,  C08F4/24 ,  C08F2500/07 ,  C08F2500/12 ,  C08F210/14

摘要： Polymerization processes and polymers formed therefrom are described herein. The polymerization processes generally include contacting ethylene and propylene with a multi-component catalyst composition including a first catalyst component including a chromium oxide based catalyst and a second catalyst component selected from metallocene and Ziegler-Natta catalysts within a polymerization reaction vessel to form a random copolymer, wherein the second catalyst component exhibits a higher comonomer response than the first catalyst component.

摘要翻译： 本文描述了聚合方法和由其形成的聚合物。 聚合方法通常包括使乙烯和丙烯与多组分催化剂组合物接触，所述多组分催化剂组合物包含在聚合反应容器内的包含基于氧化铬的催化剂的第一催化剂组分和选自茂金属和齐格勒 - 纳塔催化剂的第二催化剂组分以形成无规共聚物 ，其中所述第二催化剂组分表现出比所述第一催化剂组分更高的共聚单体响应。

公开(公告)号：US20080153998A1

公开(公告)日：2008-06-26

申请号：US11613766

申请日：2006-12-20

申请人： Ricky McCormick ,  David W. Knoeppel ,  Steven D. Gray ,  Tim J. Coffy

发明人： Ricky McCormick ,  David W. Knoeppel ,  Steven D. Gray ,  Tim J. Coffy

IPC分类号： B01J31/14 ,  C08F4/22 ,  B01J21/02 ,  B01J21/08

CPC分类号： B01J31/143 ,  B01J23/26 ,  B01J31/146 ,  C08F10/00 ,  C08F210/16 ,  C08F2410/01 ,  C08F4/69 ,  C08F210/06 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/04

摘要： Chromium catalysts may be prepared using a process including contacting a chromium catalyst precursor with a treatment agent. This catalyst may be used for polymerization of a variety of monomers, particularly olefins, to form polymers for a wide variety of applications. The catalyst exhibits desirable activity rates and polymers produced therewith may exhibit improved melt flow, polydisperity values, and changes in shear thinning as compared to those prepared under similar conditions but using the same treatment agent as a cocatalyst instead.

摘要翻译： 可以使用包括使铬催化剂前体与处理剂接触的方法来制备铬催化剂。 该催化剂可用于各种单体，特别是烯烃的聚合，以形成用于各种应用的聚合物。 催化剂表现出所需的活性速率，与之相比，使用与助催化剂相同的处理剂，与在相似条件下制备的那些相比，可以显示改善的熔体流动性，多不连续性值和剪切稀化变化。

公开(公告)号：US20090198026A1

公开(公告)日：2009-08-06

申请号：US12012038

申请日：2008-01-31

申请人： Ricky McCormick ,  David Knoeppel

发明人： Ricky McCormick ,  David Knoeppel

IPC分类号： C08F4/24 ,  B01J23/26

CPC分类号： C08F210/16 ,  C08F4/22 ,  C08F4/69 ,  C08F4/24 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/07

摘要： A process for the preparation of a chromium-type supported olefin polymerization catalyst. A fluidized bed of support particles in an inert carrier gas is established. A chromium (III) compound is added to the fluidized support particles to provide a supported catalyst component. The supported catalyst component is activated to convert at least a portion of the chromium (III) to Chromium (VI). The chromium (III) containing particles may be recovered from the fluidized bed and then activated or they may be activated in the fluidized bed. Also the support particles can be treated in the fluidized bed with other treatment agents. The support particles may be pretreated with a solution of a boron treating agent prior to incorporation of the support in the fluidized bed.

摘要翻译： 一种制备铬型负载型烯烃聚合催化剂的方法。 建立了惰性载气中载体颗粒的流化床。 向流化载体颗粒中加入铬（III）化合物以提供负载型催化剂组分。 活化负载的催化剂组分以将至少一部分铬（III）转化为铬（VI）。 含有铬（III）的颗粒可以从流化床中回收，然后活化，或者它们可以在流化床中活化。 还可以在流化床中用其它处理剂处理载体颗粒。 在将载体引入流化床之前，载体颗粒可以用硼处理剂的溶液进行预处理。

公开(公告)号：US20120208694A1

公开(公告)日：2012-08-16

申请号：US13454574

申请日：2012-04-24

申请人： Ricky McCormick ,  David Knoeppel

发明人： Ricky McCormick ,  David Knoeppel

IPC分类号： C08F4/00 ,  C08F4/18 ,  C08F4/69

CPC分类号： C08F210/16 ,  C08F4/22 ,  C08F4/69 ,  C08F4/24 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/19 ,  C08F2500/07

摘要： A process for the preparation of a chromium-type supported olefin polymerization catalyst. A fluidized bed of support particles in an inert carrier gas is established. A chromium (III) compound is added to the fluidized support particles to provide a supported catalyst component. The supported catalyst component is activated to convert at least a portion of the chromium (III) to Chromium (VI). The chromium (III) containing particles may be recovered from the fluidized bed and then activated or they may be activated in the fluidized bed. Also the support particles can be treated in the fluidized bed with other treatment agents. The support particles may be pretreated with a solution of a boron treating agent prior to incorporation of the support in the fluidized bed.

摘要翻译： 一种制备铬型负载型烯烃聚合催化剂的方法。 建立了惰性载气中载体颗粒的流化床。 向流化载体颗粒中加入铬（III）化合物以提供负载型催化剂组分。 活化负载的催化剂组分以将至少一部分铬（III）转化为铬（VI）。 含有铬（III）的颗粒可以从流化床中回收，然后活化，或者它们可以在流化床中活化。 还可以在流化床中用其它处理剂处理载体颗粒。 在将载体引入流化床之前，载体颗粒可以用硼处理剂的溶液进行预处理。