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    Fluorinated Transition Metal Catalysts and Formation Thereof
    6.
    发明申请
    Fluorinated Transition Metal Catalysts and Formation Thereof 审中-公开
    氟化过渡金属催化剂及其形成

    公开(公告)号：US20070255021A1

    公开(公告)日：2007-11-01

    申请号：US11740478

    申请日：2007-04-26

    申请人： Vladimir Marin ,  Margarito Lopez ,  Abbas Razavi ,  Tim Coffy

    发明人： Vladimir Marin ,  Margarito Lopez ,  Abbas Razavi ,  Tim Coffy

    IPC分类号： C08F4/44 ,  B01J31/00

    CPC分类号： B01J21/12 ,  B01J37/26 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08F2400/02 ,  C08F2/00 ,  C08F4/025 ,  C08F2500/20 ,  C08F2500/03 ,  C08F2500/12 ,  C08F210/14 ,  C08F2500/04 ,  C08F210/16

    摘要： Supported catalyst systems, methods of forming the supported catalyst systems and polymerization processes including the supported catalyst systems are described herein. The methods generally include providing an inorganic support composition, wherein the inorganic support composition comprises aluminum, fluorine and silica and contacting the inorganic support composition with a transition metal compound to form a supported catalyst system, wherein the transition metal compound is represented by the formula [L]mM[A]n; wherein L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to the transition metal valency. The methods further include contacting the inorganic support composition, the transition metal compound, the supported catalyst system or combinations thereof with at least one compound represented by the formula XRn, wherein X is selected from Group 12 to 13 metals, lanthanide series metals or combinations thereof and each R is independently selected from alkyls, alkoxys, aryls, aryloxys, halogens, hydrides, Group 1 or 2 metals, organic nitrogen compounds, organic phosphorous compounds and combinations thereof and n is from 2 to 5.

    摘要翻译： 本文描述了负载型催化剂体系，形成负载型催化剂体系的方法和包括负载型催化剂体系的聚合方法。 所述方法通常包括提供无机载体组合物，其中无机载体组合物包含铝，氟和二氧化硅，并使无机载体组合物与过渡金属化合物接触以形成负载型催化剂体系，其中过渡金属化合物由式[ M] [A] n < 其中L是大体积配体，A是离去基团，M是过渡金属，m和n使总配体的化合价对应于过渡金属的价态。 所述方法还包括使无机载体组合物，过渡金属化合物，负载型催化剂体系或其组合与至少一种由式XR n n表示的化合物接触，其中X选自第12至13族 金属，镧系金属或其组合，每个R独立地选自烷基，烷氧基，芳基，芳氧基，卤素，氢化物，第1或2族金属，有机氮化合物，有机磷化合物及其组合，n为2至5 。

    Silica supported ziegler-natta catalysts useful for preparing polyolefins
    7.
    发明申请
    Silica supported ziegler-natta catalysts useful for preparing polyolefins 审中-公开
    用于制备聚烯烃的二氧化硅负载的齐格勒 - 纳塔催化剂

    公开(公告)号：US20060252636A1

    公开(公告)日：2006-11-09

    申请号：US11122920

    申请日：2005-05-05

    申请人： Kayo Vizzini ,  Steven Gray ,  Tim Coffy

    发明人： Kayo Vizzini ,  Steven Gray ,  Tim Coffy

    IPC分类号： C08F4/02 ,  B01J31/00

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/025 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/04 ,  C08F2500/24 ,  C08F2500/19

    摘要： A silica supported catalyst system can be prepared that includes the product of admixing a magnesium alkoxide with a group 4, 5, or 6 transition metal complex to form a magnesium transition metal alkoxide adduct having the general formula: MgM(OR)2(OR1)pClq wherein M is a group 4, 5, or 6 transition metal; R is an alkyl or aryl moiety; R1 is a alkyl or aryl moiety having from 1 to 10 carbons, and p and q are 0 or an integer such that p+q equals the highest formal oxidation state of M; contacting the magnesium transition metal alkoxide adduct with a silica template to form a silica supported catalyst precursor; contacting the silica supported catalyst precursor chlorinating agent to form a chlorinated catalyst precursor; and contacting the chlorinated catalyst precursor with an aluminum alkyl to form a silica supported catalyst.

    摘要翻译： 可以制备二氧化硅负载的催化剂体系，其包括将烷氧基镁与基团4,5,5或6过渡金属络合物混合以形成具有以下通式的镁过渡金属醇盐加合物的产物： =“在线公式”end =“lead”？> MgM（OR）2（或<1>） <？in-line-formula description =“In-line Formulas”end =“tail”？>其中M是4,5或6族过渡金属; R是烷基或芳基部分; R 1是具有1至10个碳的烷基或芳基部分，p和q是0或整数，使得p + q等于M的最高形式氧化态; 使镁过渡金属醇盐加合物与二氧化硅模板接触以形成二氧化硅负载的催化剂前体; 使二氧化硅负载的催化剂前体氯化剂接触以形成氯化催化剂前体; 并使氯化催化剂前体与烷基铝接触以形成二氧化硅负载的催化剂。

    Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
    9.
    发明授权
    Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins 有权
    用于形成原位多相共聚物和/或改变二甲苯可溶物的多组分催化剂体系和聚合方法聚烯烃含量

    公开(公告)号：US08759243B2

    公开(公告)日：2014-06-24

    申请号：US13180672

    申请日：2011-07-12

    申请人： Tim Coffy ,  Michel Daumerie ,  Kenneth Blackmon ,  William J. Gauthier ,  Jun Tian ,  Joseph L. Thorman

    发明人： Tim Coffy ,  Michel Daumerie ,  Kenneth Blackmon ,  William J. Gauthier ,  Jun Tian ,  Joseph L. Thorman

    IPC分类号： C08F4/653 ,  C08F4/6592 ,  C08F210/06

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/06 ,  Y10S526/943 ,  C08F4/65904 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/05

    摘要： Embodiments of the invention generally include multi-component catalyst systems, polymerization processes and heterophasic copolymers formed by the processes. The multi-component catalyst system generally includes a first catalyst component selected from Ziegler-Natta catalyst systems including a diether internal electron donor and a metallocene catalyst represented by the general formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4. The multi-component catalyst system further includes a second catalyst component generally represented by the formula XCpACpBMAn, wherein X is a structural bridge, CpA and CpB each denote a cyclopentadienyl group or derivatives thereof, each being the same or different and which may be either substituted or unsubstituted, M is a transition metal and A is an alkyl, hydrocarbyl or halogen group and n is an integer between 0 and 4 and wherein the second catalyst component exhibits a higher ethylene response than the first catalyst component.

    摘要翻译： 本发明的实施方案通常包括通过该方法形成的多组分催化剂体系，聚合方法和多相共聚物。 多组分催化剂体系通常包括选自齐格勒 - 纳塔催化剂体系的第一催化剂组分，其包括二醚内电子给体和由通式XCpACpBMAn表示的茂金属催化剂，其中X是结构桥，CpA和CpB各自表示环戊二烯基 基团或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是过渡金属，A是烷基，烃基或卤素基团，n是0和4之间的整数。多组分催化剂 系统还包括通常由式XCpACpBMAn表示的第二催化剂组分，其中X是结构桥，CpA和CpB各自表示环戊二烯基或其衍生物，各自相同或不同，并且可以是取代或未取代的，M是 过渡金属，A是烷基，烃基或卤素基团，n是0至4之间的整数， nd催化剂组分表现出比第一催化剂组分更高的乙烯响应。