公开(公告)号：US06132518A

公开(公告)日：2000-10-17

申请号：US471398

申请日：1999-12-23

申请人： Miroslav Milinkovic ,  Rodney P. Reynolds ,  Dmitri S. Terekhov

发明人： Miroslav Milinkovic ,  Rodney P. Reynolds ,  Dmitri S. Terekhov

IPC分类号： C23C16/16 ,  C23C16/44 ,  C23C16/455 ,  C23C16/00

CPC分类号： C23C16/45593 ,  C23C16/16 ,  C23C16/4412 ,  C23C16/4487 ,  C23C16/45561

摘要： A closed loop, carbon monoxide self-contained preferably continuous process and apparatus for the production of nickel or nickel coated objects by nickel vapor deposition (NVD), comprising placing an object to be treated with nickel carbonyl in a deposition chamber; feeding a gaseous mixture of nickel carbonyl and carbon monoxide to the chamber; producing the nickel or nickel coated object and a nickel carbonyl-depleted gaseous mixture; removing nickel carbonyl from the nickel carbonyl-depleted gaseous mixture in a primary and subsequent secondary condensation unit and, preferably, a tertiary condensation unit to produce an essentially nickel carbonyl-free gas. The secondary and tertiary condensation units operably freeze out and subsequently thaw nickel carbonyl and most preferably each comprises a pair of units linked in parallel arrangement operative in alternating, alternate freeze-thaw modes. Carbon monoxide-containing gas is recycled to a nickel carbonyl reactor. The process and apparatus provides a more economic to operate, safe and more operably reliable than prior art NVD processes.

摘要翻译： 一种闭环，一氧化碳独立的优选连续的方法和用于通过镍气相沉积（NVD）生产镍或镍涂覆物体的装置，包括将待处理的物体用镍羰基放置在沉积室中; 将镍羰基和一氧化碳的气体混合物进料到所述室中; 生产镍或镍涂层物体和贫碳酸镍气体混合物; 在主要和随后的二级冷凝单元中，优选地，三级冷凝单元从贫碳酸镍的气态混合物中除去羰基镍以产生基本上不含羰基的气体。 二级和三级冷凝单元可操作地冷冻并随后使羰基羰基解冻，最优选地每一个都包含以交替的替代冻融模式并行布置的一对单元。 一氧化碳的气体被再循环到羰基镍反应器中。 该方法和装置提供比现有技术的NVD方法更经济的操作，安全和更可操作的可靠性。

公开(公告)号：US6048578A

公开(公告)日：2000-04-11

申请号：US185519

申请日：1998-11-04

申请人： Miroslav Milinkovic ,  Rodney P. Reynolds ,  Dmitri S. Terekhov

发明人： Miroslav Milinkovic ,  Rodney P. Reynolds ,  Dmitri S. Terekhov

IPC分类号： B01D53/00 ,  C22B23/06 ,  C23C16/16 ,  C23C16/44 ,  C23C16/455

CPC分类号： C23C16/45593 ,  B01D53/002 ,  C22B23/065 ,  C23C16/16 ,  C23C16/4412 ,  C23C16/4487 ,  C23C16/45561

摘要： A closed loop, carbon monoxide self-contained preferably continuous process and apparatus for the production of nickel or nickel coated objects by nickel vapor deposition (NVD), comprising placing an object to be treated with nickel carbonyl in a deposition chamber; feeding a gaseous mixture of nickel carbonyl and carbon monoxide to the chamber; producing the nickel or nickel coated object and a nickel carbonyl-depleted gaseous mixture; removing nickel carbonyl from the nickel carbonyl-depleted gaseous mixture in a primary and subsequent secondary condensation unit and, preferably, a tertiary condensation unit to produce an essentially nickel carbonyl-free gas. The secondary and tertiary condensation units operably freeze out and subsequently thaw nickel carbonyl and most preferably each comprises a pair of units linked in parallel arrangement operative in alternating, alternate freeze-thaw modes. Carbon monoxide-containing gas is recycled to a nickel carbonyl reactor. The process and apparatus provides a more economic to operate, safe and more operably reliable than prior art NVD processes.

摘要翻译： 一种闭环，一氧化碳独立的优选连续的方法和用于通过镍气相沉积（NVD）生产镍或镍涂覆物体的装置，包括将待处理的物体用镍羰基放置在沉积室中; 将镍羰基和一氧化碳的气体混合物进料到所述室中; 生产镍或镍涂层物体和贫碳酸镍气体混合物; 在主要和随后的二级冷凝单元中，优选地，三级冷凝单元从贫碳酸镍的气态混合物中除去羰基镍以产生基本上不含羰基的气体。 二级和三级冷凝单元可操作地冷冻并随后使羰基羰基解冻，最优选地每一个都包含以交替的替代冻融模式并行布置的一对单元。 一氧化碳的气体被再循环到羰基镍反应器中。 该方法和装置提供比现有技术的NVD方法更经济的操作，安全和更可操作的可靠性。