摘要:
The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. The invention further relates to a high-performance polyethylene multifilament yarn, and to semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites.
摘要:
The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. The invention further relates to a high-performance polyethylene multifilament yarn, and to semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites.
摘要:
Ballistic-resistant assemblies include monolayers formed of high-performance polyethylene multi-filament yarns. The assemblies have an areal density of at least 1.5 kg/m2 and a specific energy absorption of at least 300 J·m2/kg as measured against a 9*19 mm FMJ Parabellum bullet according to a test procedure based on Stanag 2920.
摘要:
The invention relates to a process for the manufacture of an object, curved in one or more directions, from a package of at least one stacked ply containing polymeric fibres by the deforming thereof at elevated temperature, the process comprising imposing on the fibres a tensile stress at a temperature lying between the melting point of the fibres at the imposed tensile stress and 20° C. below the melting point, which tensile stress is high enough for the fibres to be drawn. This process allows objects, curved in one or more directions, to be produced from flat fibre plies without appreciable wrinkling using even fibre plies with low internal and/or mutual deformability and without material being drawn into the die in a controlled manner. The invention also relates to an object, curved in one or more directions, obtainable by the process according to the invention.
摘要:
Processes for making high-performance polyethylene multi-filament yarns include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4.
摘要:
The invention relates to a process for the manufacture of an object, curved in one or more directions, from a package of at least one stacked ply containing polymeric fibers by the deforming thereof at elevated temperature, the process comprising imposing on the fibres a tensile stress at a temperature lying between the melting point of the fibers at the imposed tensile stress and 20° C. below the melting point, which tensile stress is high enough for the fibers to be drawn. This process allows objects, curved in one or more directions, to be produced from flat fiber plies without appreciable wrinkling using even fiber plies with low internal and/or mutual deformability and without material being drawn into the die in a controlled manner. The invention also relates to an object, curved in one or more directions, obtainable by the process according to the invention.
摘要:
The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. The invention further relates to a high-performance polyethylene multifilament yarn, and to semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites.
摘要:
The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid =DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1. The invention further relates to a high-performance polyethylene multifilament yarn, and to semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites.
摘要翻译:本发明涉及一种制备高性能聚乙烯复丝纱线的方法,包括以下步骤:a)将超高摩尔质量的聚乙烯溶液制成溶剂; b)将溶液通过包含至少5个喷孔的平板旋转到气隙中以形成流体细丝,同时施加拉伸比DR SUB>; c)冷却流体细丝以形成含溶剂的凝胶细丝; d)从长丝中至少部分去除溶剂; 和e)在所述溶剂去除之前,期间和/或之后至少一个步骤中拉丝,同时施加至少为4的拉伸比固体,其中在步骤b)中,每个纺丝孔包括 具有特定尺寸的收缩区域和直径为D 的下游区域和长度为D SUB>的区域,其中L N / N / N > 0至至多25,导致至少150的拉伸比DR SUB> = DR SUB> 喷丝头的拉伸比是喷丝头中的拉伸比,并且DR气囊中的拉伸比是气隙中的拉伸比,其中DR> SP SUB>大于1 本发明还涉及一种高性能聚乙烯复丝纱线,以及含有所述纱线的半成品或最终用途产品,特别是涉及绳索和弹道防弹复合材料。