公开(公告)号：US06960304B1

公开(公告)日：2005-11-01

申请号：US10610892

申请日：2003-07-01

Applicant: David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

Inventor： David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

IPC: C02F1/00 ,  C02F1/68 ,  C02F1/76

CPC classification number: C02F1/76 ,  C02F1/68 ,  C02F2101/325 ,  C02F2103/001 ,  C02F2303/12 ,  Y02W10/37

Abstract: Methods for treating wastewater comprising adding to wastewater a defoaming and/or surfactant-effective quantity of at least one base-catalyzed branched reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3  (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY  (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group or a C1–C6 alkylamino group, n is at least 1; wherein the mole ratio of the linking compound a) to b) is from 0.1:1 to 5:1; and to wastewaters containing the above base-catalyzed reaction products.

Abstract translation: 用于处理废水的方法包括将消泡和/或表面活性剂有效量的至少一种碱催化的支化反应产物加入到废水中，所述支化反应产物包含以下反应物：A）至少一种式I化合物<？在线配方说明= “在线公式”end =“lead”？> R <1>（X）3（I）<？in-line-formula description =“In-Line Formulas “end =”tail“？>其中每个X基团是卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R 1中的两个相邻碳原子连接， / SUP>基团以形成环氧基，R 1是含有3至10个碳原子的烷三基; 和B）至少一种具有式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> R 2 X（AO）n Y（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 2是取代或未取代的饱和或不饱和的， 具有1至36个碳原子的有机基团; X是-O-，-S-或-NR 3 - ，其中R 3是氢或C 1 -C 3 - 18个烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; 并且Y是氢，或Y可以是巯基或氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是 当Y是巯基或氨基或C 1 -C 6烷基氨基时，n至少为1; 其中所述连接化合物a）至b）的摩尔比为0.1:1至5:1; 以及含有上述碱催化反应产物的废水。

公开(公告)号：US06770129B1

公开(公告)日：2004-08-03

申请号：US10352530

申请日：2003-01-28

Applicant: David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

Inventor： David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

IPC: C09D706

CPC classification number: D21H19/62 ,  D21H19/40

Abstract: Aqueous paper coating compositions containing at least one of a clay, a starch, casein, a resin, and a wax; and wherein the composition contains from about 0.001% to about 5% by weight of at least one base-catalyzed branched reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3  (I)  wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY  (II)  wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group (amino or C1-C6 alkylamino group) in place of a terminal —OH group, provided that when Y is mercapto or an amino group, n is at least 1; wherein the mole ratio of the linking compound A) to B) is from 0.1:1 to 5:1.

Abstract translation: 含有粘土，淀粉，酪蛋白，树脂和蜡中的至少一种的水性纸涂料组合物; 并且其中所述组合物含有约0.001重量％至约5重量％的至少一种碱催化的支化反应产物，其包含以下反应物：A）至少一种式I化合物，其中每个X基团为卤素原子或一个X基团 是卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，R 1是含有3至10个碳的烷基三 原子 和B）至少一种具有式II的化合物，其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S - 或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y是氢，Y可以是巯基或氨基（氨基或C1-C6烷基氨基）代替末端-OH基团，条件是当Y是巯基或氨基时，n至少为1 ;其中连接化合物A）与B）的摩尔比为0.1:1至5:1。

公开(公告)号：US06572691B2

公开(公告)日：2003-06-03

申请号：US10229723

申请日：2002-08-28

Applicant: David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

Inventor： David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

IPC: C09D1100

CPC classification number: C09D11/30 ,  C09D11/03 ,  C09D11/16 ,  C09D11/18

Abstract: Ink compositions containing a surfactant-effective and/or defoaming-effective quantity of at least one reaction product comprising the following reactants: A) at least one compound of formula I R1(X)3  (I)  wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) at least one compound having the formula II R2X(AO)nY   (II)  wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or NR33— where R3 is hydrogen or a C1-C18 group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200, preferably from 1 to 100, more preferably from 2 to 20; and Y is hydrogen, or Y can be a mercapto group or an amino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, n is at least 1.

Abstract translation: 含有表面活性剂有效和/或消泡有效量的至少一种包含以下反应物的反应产物的油墨组合物：A）至少一种式I化合物，其中每个X基团是卤素原子或一个X基团是卤素原子 并且两个X基团表示环氧氧原子，其与R1基团中的两个相邻碳原子连接以形成环氧基，并且R 1是含有3至10个碳原子的烷三基; 和B）至少一种具有式II的化合物，其中R 2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O-，-S-或NR33-，其中R3是氢或C1-C18基团; 每个AO基团独立地为乙烯氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200，优选1至100，更优选2至20的数; Y是氢，Y可以是巯基或氨基代替末端-OH基团，条件是当Y是巯基或氨基时，n至少为1。

公开(公告)号：US06303663B1

公开(公告)日：2001-10-16

申请号：US09277708

申请日：1999-03-26

Applicant: Ronald W. Broadbent ,  Dharmesh Chovatia

Inventor： Ronald W. Broadbent ,  Dharmesh Chovatia

IPC: C01B33145

CPC classification number: B01D19/0409 ,  B01D19/0404 ,  Y10T428/2995

Abstract: Silica is rendered hydrophobic by a catalyst-free, in-situ process that includes contact with a hydrophobing agent under vacuum at elevated temperature for a time sufficient to replace adsorbed water in the silica with the hydrophobing agent. The resulting dispersion of hydrophobic silica in an inert, liquid, hydrophobic carrier medium is then subjected to high shear forces for a time sufficient to produce a homogeneous dispersion of hydrophobic silica particles in a defoaming composition.

Abstract translation: 二氧化硅通过无催化剂的原位方法使其疏水，包括在真空下在高温下与疏水剂接触足够的时间以用疏水剂代替二氧化硅中的吸附水。 然后将所得的疏水性二氧化硅在惰性，液体，疏水性载体介质中的分散体经受高剪切力足以在疏水性组合物中产生疏水性二氧化硅颗粒的均匀分散体。

公开(公告)号：US5080937A

公开(公告)日：1992-01-14

申请号：US429443

申请日：1989-10-30

Applicant: Ronald W. Broadbent

Inventor： Ronald W. Broadbent

IPC: C09D127/08 ,  B05D7/14 ,  C09D5/08 ,  C09D127/04

CPC classification number: C09D5/088 ,  B05D7/142

Abstract: Pinhole and blister formation during autodeposition coating of active metal objects, particularly galvanized steel, other zinciferous surfaces, and even ordinary steel that has been abraded, scratched, or otherwise strained, can be greatly reduced by exposing the active metal surfaces to a solution containing cystine before using a autodeposition process itself, or by adding cystine to an otherwise conventional autodeposition composition.

Abstract translation: 通过将活性金属表面暴露于含有胱氨酸的溶液中，活性金属物体，特别是镀锌钢，其他含锌表面，甚至普通的被磨损，划伤或其他应变的钢的自沉积涂层中的针孔和气泡形成可以大大降低 在使用自身沉积过程本身之前，或者将胱氨酸加入到常规的自动沉积组合物中。

公开(公告)号：US4632851A

公开(公告)日：1986-12-30

申请号：US725470

申请日：1985-04-22

Applicant: Ronald W. Broadbent ,  Ellsworth A. Stockbower

Inventor： Ronald W. Broadbent ,  Ellsworth A. Stockbower

IPC: B05D7/14 ,  B05D1/18

CPC classification number: B05D7/142

Abstract: Continuous autodeposition from a bath having a low solids concentration and stable coating characteristics is achieved by close control of bath iron concentration, preferably by maintaining iron concentration below about 1.5 gm/l by controlled discard and replacement of bath volume.

Abstract translation: 通过密切控制浴铁浓度，优选通过控制丢弃和更换浴体积来维持铁浓度低于约1.5gm / l，从而实现了具有低固体浓度和稳定涂层特性的浴的连续自动沉积。

公开(公告)号：US6110977A

公开(公告)日：2000-08-29

申请号：US95677

申请日：1998-06-10

Applicant: Stephen F. Gross ,  Michael S. Wiggins ,  Ronald W. Broadbent ,  David I. Devore ,  Timothy C. Morris

Inventor： Stephen F. Gross ,  Michael S. Wiggins ,  Ronald W. Broadbent ,  David I. Devore ,  Timothy C. Morris

IPC: B01D19/04 ,  B01F17/56 ,  C08G65/24 ,  C08G65/26 ,  C08G65/337 ,  C11D1/825

CPC classification number: C08G65/24 ,  B01D19/04 ,  B01D19/0404 ,  B01D19/0431 ,  C08G65/2609 ,  C08G65/337

Abstract: Products of the reaction of epichlorohydrin and compounds having the formula IIR.sub.3 (EO).sub.n (PO).sub.m OH (II)wherein R.sub.3 is an alkyl, alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 10; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are extremely efficient defoamers for aqueous surfactant systems are effective as defoamers, viscosity reducers and crystallization preventives for aqueous surfactant solutions, particularly alkyl polyglycosides.

Abstract translation: 表氯醇与具有式IIR 3（EO）n（PO）mOH（II）的化合物的反应产物，其中R 3是具有4至22个碳原子的烷基，链烯基或异戊基; 具有4至22个碳原子的取代的烷基或烯基，其中： n为0〜50的数，m为0〜10的数。 其中表氯醇与（II）的摩尔比为约0.60 / 1至约2/1是用于水性表面活性剂体系的非常有效的消泡剂作为用于表面活性剂水溶液，特别是烷基多糖苷的消泡剂，降粘剂和结晶预防剂是有效的。

公开(公告)号：US6107394A

公开(公告)日：2000-08-22

申请号：US91064

申请日：1999-01-11

Applicant: Ronald W. Broadbent ,  Kenneth Breindel

Inventor： Ronald W. Broadbent ,  Kenneth Breindel

IPC: C08G65/329 ,  C08L71/02 ,  C08J3/00 ,  C08K3/20 ,  C08L51/00 ,  C08L75/00 ,  C08L77/00

CPC classification number: C08G65/329 ,  C08L71/02

Abstract: Latexes are thicknened by a blend of a urethane compound effective as an associative thickener and a non-urethane compound of the formula: R.sup.1 --(O--A).sub.a --B.sup.1 --R.sup.2 --(B.sup.2 --R.sup.3).sub.d --(B.sup.3 --(A'--O).sub.b-f --(A'--B.sup.4).sub.f --R.sup.4 --(B.sup.5 --R.sup.5).sub.e).sub.n --B.sup.6 --(A"O).sub.c --R.sup.6, wherein R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl; B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5 and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylated group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.4 --C(O)--O--, an amino group to form the amine linkage R.sup.2 --N(R)-- and/or R.sup.4 --N(R)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl), and an amido group (to form the amide linkage R.sup.2 --N(R)--C(O)-- and or R.sup.4 --N(R)--C(O)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl); each of a, b, c, d, e, f and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; and each of A, A' and A" is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.

Abstract translation: PCT No.PCT / US96 / 19136 Sec。 371日期1999年1月11日 102（e）1999年1月11日PCT PCT 1996年12月4日PCT公布。 出版物WO97 / 21743 日期：1997年6月19日通过作为缔合增稠剂和下式的非氨基甲酸酯化合物的共混物，将化合物加成：R1-（OA）a-B1-R2-（B2-R3）d-（B3 - （A'-O）bf-（A'-B4）f-R4-（B5-R5）e）n-B6-（A''O）c-R6，其中R1和R6是独立选择的一价疏水基团 由脂肪族基团，取代脂肪族基团，芳香族基团和取代芳香族基团组成的组; R2和R4独立地选自脂族，取代的脂族，芳族或取代的芳族基团，每个基团是二价或三价的; R3和R5独立地选自氢，低级烷基和低级芳烷基; B1，B2，B3，B4，B5和B6是独立地选自氧原子（形成醚键-O-）的连接基团，羧基（形成酯键R2-C（O） -O-和/或R 4 -C（O）-O-，形成胺键R2-N（R） - 和/或R4-N（R） - 的氨基，其中R是氢，低级烷基， 低级芳烷基或低级酰基）和酰氨基（形成酰胺键R2-N（R）-C（O） - 和/或R4-N（R）-C（O） - ，其中R是氢， 低级烷基，低级芳烷基或低级酰基）; a，b，c，d，e，f和n各自为整数，其中a和c各自独立地为大于20至约200的任何整数; b是大于20至约450的任何整数; d，e和f为零或1; n为1〜5的整数; 并且A，A'和A“各自独立地为乙烯，1,2-亚丙基，1,2-亚丁基单元或其组合。

公开(公告)号：US20100288644A1

公开(公告)日：2010-11-18

申请号：US12803263

申请日：2009-11-12

Applicant: David W. Brown ,  Kenneth Breindel ,  Michael S. Wiggins ,  Ronald W. Broadbent ,  Shailesh Shah

Inventor： David W. Brown ,  Kenneth Breindel ,  Michael S. Wiggins ,  Ronald W. Broadbent ,  Shailesh Shah

IPC: C25D3/02 ,  B21B45/02

CPC classification number: C25D3/02 ,  C10M159/12 ,  C10M173/00 ,  C10M2207/042 ,  C10M2207/046 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2209/105 ,  C10N2260/06

Abstract: Coatings for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, and latex compositions comprising a base-catalyzed reaction product of (a) at least one compound of formula I R1(X)3  (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (b) at least one compound having the formula II R2X(AO)nY  (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1-C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, or a C1-C6 alkylamino group, n is at least 1; wherein the mole ratio of component a) to b) is from 0.1:1 to 5:1; are described.

Abstract translation: 用于金属容器，金属加工润滑剂组合物，用于电镀和电解提取的组合物的涂料，以及包含（a）至少一种式I的化合物R1（X）3（I）的碱催化的反应产物的胶乳组合物，其中每个X基团为 卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1是含有3至10个碳的烷基三 原子 和（b）至少一种具有式II R2X（AO）nY（II）的化合物，其中R2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S-或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y为氢原子，Y为巯基或氨基或C1-C6烷基氨基而不是端基-OH，条件是当Y为巯基或氨基时，或为C1-C6烷基氨基 ，n至少为1; 其中组分a）至b）的摩尔比为0.1:1至5:1; 被描述。

公开(公告)号：US07169858B2

公开(公告)日：2007-01-30

申请号：US10788136

申请日：2004-02-26

Applicant: David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

Inventor： David W. Brown ,  Kenneth Breindel ,  Ronald W. Broadbent ,  Michael S. Wiggins

IPC: C08G65/22 ,  C08G65/24

CPC classification number: C07C41/03 ,  C07C43/11 ,  C08G65/2639 ,  C08G65/337 ,  C08L71/03 ,  C09D5/024 ,  C09D7/65 ,  Y10T428/25 ,  C07C43/23

Abstract: Reaction products prepared by processes which comprise reacting: A) at least one compound having the general formula I: R1(X)3  (I) wherein each X group independently represents a halogen atom or one X group represents a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group having from 3 to 10 carbon atoms; and B) at least one compound having the general formula II R2X(AO)nY  (II) wherein R2 represents a polyfluorinated organic group having from 1 to 36 carbon atoms and at least two fluorine atoms; X represents —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y represents hydrogen, a mercapto group, an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, with the proviso that when Y is a mercapto, amino, or a C1–C6 alkylamino group, n is at least 1; are described.

Abstract translation: 通过以下方法制备的反应产物：A）至少一种具有通式I的化合物：<？in-line-formula description =“In-line formula”end =“lead”→> R 1> （X）3（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中每个X基团独立地表示卤素原子或一个X 基团表示卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1 >是具有3至10个碳原子的烷基三胺基; 和B）至少一种具有通式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO） Y（II）<？在线公式描述=“在线式”end =“tail”？>其中R 2表示多氟化有机基团，其具有1至 36个碳原子和至少两个氟原子; X表示-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y表示氢，巯基，氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是当Y 是巯基，氨基或C 1 -C 6烷基氨基，n为至少1; 被描述。