公开(公告)号：US5728463A

公开(公告)日：1998-03-17

申请号：US626267

申请日：1996-04-01

申请人： Senya Inoue ,  Nobuyuki Otaki

发明人： Senya Inoue ,  Nobuyuki Otaki

IPC分类号： B32B5/16

CPC分类号： G01N30/482 ,  B01J2220/54 ,  Y10T428/2982 ,  Y10T428/2991

摘要： A material for use as a stationary phase for chromatography comprising a solid material the surface of which is coated with pyrophosphate and/or metaphosphate.

摘要翻译： 用作色谱固定相的材料，包括其表面涂覆有焦磷酸盐和/或偏磷酸盐的固体材料。

公开(公告)号：US4698317A

公开(公告)日：1987-10-06

申请号：US726325

申请日：1985-04-23

申请人： Senya Inoue ,  Akira Ono ,  Mikio Kobayashi ,  Hiroshi Yokoo

发明人： Senya Inoue ,  Akira Ono ,  Mikio Kobayashi ,  Hiroshi Yokoo

IPC分类号： B01J20/16 ,  B01J21/14 ,  C01B33/26 ,  C03B19/10 ,  C03C10/00 ,  C03C10/08 ,  C03C11/00 ,  C04B35/195 ,  C04B38/00 ,  C04B38/08 ,  G01N30/52 ,  C03C12/00 ,  C04B38/06

CPC分类号： B01J21/14 ,  B01J20/16 ,  C01B33/26 ,  C03B19/107 ,  C03B19/108 ,  C03C10/0045 ,  C03C11/00 ,  C03C11/002 ,  C04B35/195 ,  C04B38/009 ,  C04B38/08 ,  G01N2030/484 ,  G01N2030/528

摘要： New type porous cordierite ceramics having a new characteristic interconnecting open cellular structure and a hollow microspherical cordierite glass powder with a shell devoid of any pores or provided with a few or an abundance of open pores which is used as a starting material for the porous cordierite ceramics. The porous cordierite ceramics are produced by subjecting a starting solution containing an alkyl silicate, an aluminum salt and an magnesium salt optionally with other compounds in an organic or aqueous organic solvent to spray thermal decomposition to prepare the hollow microspherical cordierite glass powder, and then processing the cordierite glass powder to a shaped body after or before an optional heat treatment and firing the shaped body at a temperature below the melting point of cordierite. The porous cordierite ceramics are useful as a carrier for gas chromatography or various chemical reactions.

摘要翻译： 新型多孔堇青石陶瓷具有互连开孔型结构的新型特征和中空微球堇青石玻璃粉末，其空隙没有任何孔隙或具有少量或大量开孔，用作多孔堇青石陶瓷的起始材料 。 多孔堇青石陶瓷通过使含有烷基硅酸盐，铝盐和镁盐的任选与其它化合物的起始溶液在有机或含水有机溶剂中进行热分解来制备中空微珠堇青石玻璃粉末，然后加工 堇青石玻璃粉末在可选的热处理之后或之前成型体，在低于堇青石熔点的温度下焙烧成形体。 多孔堇青石陶瓷可用作气相色谱或各种化学反应的载体。

公开(公告)号：US4871693A

公开(公告)日：1989-10-03

申请号：US100998

申请日：1987-09-24

申请人： Senya Inoue ,  Akira Ono ,  Mikio Kobayashi ,  Hiroshi Yokoo

发明人： Senya Inoue ,  Akira Ono ,  Mikio Kobayashi ,  Hiroshi Yokoo

IPC分类号： B01J20/16 ,  B01J21/14 ,  C01B33/26 ,  C03B19/10 ,  C03C10/00 ,  C03C10/08 ,  C03C11/00 ,  C04B35/195 ,  C04B38/00 ,  C04B38/08 ,  G01N30/52

CPC分类号： B01J21/14 ,  B01J20/16 ,  C01B33/26 ,  C03B19/107 ,  C03B19/108 ,  C03C10/0045 ,  C03C11/00 ,  C03C11/002 ,  C04B35/195 ,  C04B38/009 ,  C04B38/08 ,  G01N2030/484 ,  G01N2030/528

摘要： New type porous cordierite ceramics having a new characteristic interconnecting open cellular structure and a hollow microspherical cordierite glass powder with a shell devoid of any pores or provided with a few or an abundance of open pores which is used as a starting material for the porous cordierite ceramics. The porous cordierite ceramics are produced by subjecting a starting solution containing an alkyl silicate, an aluminum salt and an magnesium salt optionally with other compounds in an organic or aqueous organic solvent to spray thermal decomposition to prepare the hollow microspherical cordierite glass powder, and then processing the cordierite glass powder to a shaped body after or before an optional heat treatment and firing the shaped body at a temperature below the melting point of cordierite. The porous cordierite ceramics are useful as a carrier for gas chromatography or various chemical reactions.

公开(公告)号：US4836994A

公开(公告)日：1989-06-06

申请号：US95222

申请日：1987-09-11

申请人： Senya Inoue ,  Akira Ono

发明人： Senya Inoue ,  Akira Ono

IPC分类号： B01J20/04 ,  C01B25/32 ,  C01B25/455

CPC分类号： B01J20/048 ,  B01J20/282 ,  C01B25/32 ,  C01B25/322 ,  C01B25/325 ,  C01B25/455 ,  B01J2220/54

摘要： The present invention relates to a process for preparing a calcium-phosphorus-apatite, essentially characterized by admixing a single solvent of water or an organic solvent compatible with water or a mixed solvent of water with an organic solvent compatible with water with calcium and phosphorus compounds soluble in said single or mixed solvent to prepare a raw material solution, and atomizing the raw material solution into a flame or a heating zone for effecting a thermal decomposition reaction thereof to form a calcium-phosphorus-apatite; a calcium-phosphorus-apatite obtained by the process and having novel characteristics; and the use of the calcium-phosphorus-apatite as a chromatographic packing material.

公开(公告)号：US5205928A

公开(公告)日：1993-04-27

申请号：US774512

申请日：1991-10-08

申请人： Senya Inoue ,  Akira Ono ,  Nobuyuki Otaki

发明人： Senya Inoue ,  Akira Ono ,  Nobuyuki Otaki

IPC分类号： B01J20/04 ,  C01B25/32

CPC分类号： C01B25/322 ,  B01J20/048 ,  B01J20/28011 ,  B01J20/28019 ,  B01J20/28054 ,  B01J20/28057 ,  B01J20/3078 ,  B01J20/3085

摘要： Microspherical sintered bodies of hydroxyapatite are prepared according to a new specific process wherein a suspension having hydroxyapatite microparticles dispersed in water or an organic solvent or a mixture of water and an organic solvent compatible therewith is atomized into a heating zone maintained above 500.degree. C. whereby spherical agglomerates of hydroxyapatite microparticles formed by drying and solidification of microdroplets of the suspension are sintered while the agglomerates are suspended in the heating zone. Microspherical sintered bodies of hydroxyapatite thus obtained, which may be modified by an optical heat treatment to adjust the surface area of the sintered body and growth of crystals therein, are useful in various fields of industry, for example, as a sorption agent in chromatographic separation.

摘要翻译： 根据新的具体方法制备羟基磷灰石的微球形烧结体，其中将分散在水或有机溶剂中的羟基磷灰石微粒的悬浮液或与其相容的水和有机溶剂的混合物雾化到保持在500℃以上的加热区中，由此 通过干燥和固化悬浮液的微滴形成的羟基磷灰石微粒的球形聚集体被烧结，而附聚物悬浮在加热区中。 由此得到的羟基磷灰石的微球状烧结体可以通过光学热处理改性以调节烧结体的表面积和其中的晶体生长，可用于各种工业领域，例如作为色谱分离中的吸附剂 。

公开(公告)号：US5108956A

公开(公告)日：1992-04-28

申请号：US704732

申请日：1991-05-20

申请人： Senya Inoue ,  Akira Ono ,  Nobuyuki Otaki

发明人： Senya Inoue ,  Akira Ono ,  Nobuyuki Otaki

IPC分类号： B01J20/281 ,  B01J20/04 ,  B01J20/20 ,  C01B25/32 ,  G01N30/88

CPC分类号： C01B25/322 ,  B01J20/048 ,  B01J20/28004 ,  B01J20/281 ,  C01B25/327 ,  B01J2220/58

摘要： Microspherical sintered bodies of hydroxyapatite are prepared according to a new specific process wherein a suspension having hydroxyapatite microparticles dispersed in water or an organic solvent or a mixture of water and an organic solvent compatible therewith is atomized into a heating zone maintained above 500.degree. C. whereby spherical agglomerates of hydroxyapatite microparticles formed by drying and solidification of microdroplets of the suspension are sintered while the agglomerates are suspended in the heating zone. Microspherical sintered bodies of hydroxyapatite thus obtained, which may be modified by an optical heat treatment to adjust the surface area of the sintered body and growth of crystals therein, are useful in various fields of industry, for example, as a sorption agent in chromatographic separation.

公开(公告)号：US4711769A

公开(公告)日：1987-12-08

申请号：US893324

申请日：1986-07-30

申请人： Senya Inoue ,  Akira Ono

发明人： Senya Inoue ,  Akira Ono

IPC分类号： B01J20/04 ,  C01B25/32 ,  C01B25/455 ,  C01B15/16 ,  C01B25/26

CPC分类号： B01J20/048 ,  B01J20/282 ,  C01B25/32 ,  C01B25/322 ,  C01B25/325 ,  C01B25/455 ,  B01J2220/54

摘要： The present invention relates to a process for preparing a calcium-phosphorus-apatite, essentially characterized by admixing a single solvent of water or an organic solvent compatible with water or a mixed solvent of water with an organic solvent compatible with water with calcium and phosphorus compounds soluble in said single or mixed solvent to prepare a raw material solution, and atomizing the raw material solution into a flame or a heating zone for effecting a thermal decomposition reaction thereof to form a calcium-phosphorus-apatite; a calcium-phosphorus-apatite obtained by the process and having novel characteristics; and the use of the calcium-phosphorus-apatite as a chromatographic packing material.

摘要翻译： PCT No.PCT / JP85 / 00693 Sec。 一九八六年七月三十日 102（e）日期1986年7月30日PCT 1985年12月18日PCT PCT。 出版物WO86 / 03733 日期：1986年7月3日。本发明涉及一种钙磷磷灰石的制备方法，其基本特征在于将水或与水或水的混合溶剂相容的有机溶剂与单质溶剂与有机溶剂相容 其中水与钙和磷化合物溶解在所述单一或混合溶剂中以制备原料溶液，并将原料溶液雾化成火焰或加热区，以进行其热分解反应以形成磷酸钙磷灰石; 通过该方法获得的具有新特征的磷酸钙磷灰石; 并使用钙磷磷灰石作为色谱包装材料。